Comparing the Cubic and Tetragonal Phases of MAPbI3 at Room Temperature

Stability and maintenance of the crystal structure are the main drawbacks of the application of organic-inorganic perovskites in photovoltaic devices. The Delta T = 62 K robust shift of the structural phase transition observed here allows us to conduct a comprehensive study at room temperature of the tetragonal versus cubic phase on MAPbI3. The absence of the shift in the cubic transition for all-inorganic CsPbI3 samples confirms the importance of both orientation and dynamics of the organic cations. Our results provide a unique opportunity to evaluate the physical properties of both cubic and tetragonal phases of MAPbI3 at the same temperature, eliminating different phonon effects as possible causes for different properties. Besides higher electrical resistivity, the perovskite cubic phase presents a faster charge carrier lifetime than the tetragonal phase and partial PL quenching, pointing toward increased trap-assisted nonradiative recombination. The light absorption coefficient in the cubic phase is larger than the absorption in the tetragonal phase in the green region.

Automated summary

The stability and maintenance of the crystal structure are the main concerns in using organic-inorganic perovskites in photovoltaic devices. This study explores the tetragonal and cubic phases of MAPbI3 at room temperature, revealing the importance of organic cations in the structural phase transition. The perovskite cubic phase exhibits higher electrical resistivity, faster charge carrier lifetime, and greater light absorption in the green region compared to the tetragonal phase.