☆ 4.7 Article

Dinitrogen Binding and Functionalization from a Low-Coordinate Alkynyliron Complex

INORGANIC CHEMISTRY (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Multidisciplinary

Mechanism of Nitrogen-Carbon Bond Formation from Iron(IV) Disilylhydrazido Intermediates during N2 Reduction

Samuel M. Bhutto et al.

Summary: This study reports a reaction sequence that activates C-H bonds in simple arenes and N-N triple bond in N2, allowing the formation of a new N-C bond and conversion of abundant feedstocks into N-containing organic compounds. The key step involves partial silylation of N2, followed by sequential silyl radical and silyl cation addition to form a kinetically competent iron(IV)-NN(SiMe3)2 intermediate that can be isolated at low temperature. This new pathway offers a method for functionalizing N2 using organometallic chemistry.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Recent progress in functional atom-precise coinage metal clusters protected by alkynyl ligands

Miao-Miao Zhang et al.

Summary: This review summarizes the development and functional properties of alkynyl-protected coinage metal clusters, and discusses the prospects and opportunities for future development.

COORDINATION CHEMISTRY REVIEWS (2022)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Multiphoton absorption at metal alkynyl complexes

Ling Zhang et al.

Summary: Materials exhibiting multi-photon absorption (MPA), such as metal alkynyl complexes, have significant potential applications in microfabrication, bio-imaging and sensing, and photodynamic therapy. The collinear structure of metal and alkynyl ligand in these complexes promotes strong electron delocalization and intra-molecular charge transfer, leading to outstanding MPA behavior.

COORDINATION CHEMISTRY REVIEWS (2022)

添加到收藏夹

Review Chemistry, Applied

Transition-Metal-Catalyzed Selective Alkynylation of C-H Bonds

Anjana Suseelan Sarala et al.

Summary: Alkynylation reactions are highly sought-after in synthetic methodologies due to their versatility in C-C triple bond diversifications. Transition-metal-catalyzed C-H alkynylation has emerged as an alternative method to Sonogashira coupling, allowing for site-selective alkynylations under moderate reaction conditions.

ADVANCED SYNTHESIS & CATALYSIS (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Iron-Catalyzed Alkyne Carboamination via an Isolable Iron Imide Complex

Corey A. Richards et al.

Summary: Transition metal imide-mediated C-N bond formation is a powerful strategy for introducing nitrogen into organic compounds. Stoichiometric experiments revealed a catalyst deactivation pathway, which was suppressed in the presence of a coordinating additive. These insights were instrumental in identifying reaction conditions that allow for turnover of the iron catalyst.

ORGANOMETALLICS (2021)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Electronic Properties of Poly-Yne Carbon Chains and Derivatives with Transition Metal End-Groups

Frederic Gendron et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2020)

添加到收藏夹

Article Multidisciplinary Sciences

Coupling dinitrogen and hydrocarbons through aryl migration

Sean F. McWilliams et al.

NATURE (2020)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

σ-Acetylide complexes for biomedical applications: Features, challenges and future directions

Ashanul Haque et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

The Myth of d8 Copper(III)

Ida M. DiMucci et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Development and Evolution of Mechanistic Understanding in Iron-Catalyzed Cross-Coupling

Michael L. Neidig et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Alkynyl Coinage Metal Clusters and Complexes-Syntheses, Structures, and Strategies

Arvind Kumar Gupta et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Iron versus Ruthenium: Clarifying the Electronic Differences between Prototypical Mixed-Valence Organometallic Butadiyndiyl Bridged Molecular Wires

Simon Gueckel et al.

ORGANOMETALLICS (2018)

添加到收藏夹

Article Chemistry, Physical

Iron(II) Bis(acetylide) Complexes as Key Intermediates in the Catalytic Hydrofunctionalization of Terminal Alkynes

Nikolaus Gorgas et al.

ACS CATALYSIS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Fe-Catalyzed Conversion of N-2 to N(SiMe3)(3) via an Fe-Hydrazido Resting State

Adam D. Piascik et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Intermediates and Reactivity in Iron-Catalyzed Cross-Couplings of Alkynyl Grignards with Alkyl Halides

Jared L. Kneebone et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Markovnikov versus anti-Markovnikov Hydrophosphination: Divergent Reactivity Using an Iron (II) β-Diketiminate Pre-Catalyst

Andrew K. King et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Iron-Catalyzed gem-Specific Dimerization of Terminal Alkynes

Qiuming Liang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Iron Alkynyl Helicenes: Redox-Triggered Chiroptical Tuning in the IR and Near-IR Spectral Regions and Suitable for Telecommunications Applications

Chengshuo Shen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

From Widely Accepted Concepts in Coordination Chemistry to Inverted Ligand Fields

Roald Hoffmann et al.

CHEMICAL REVIEWS (2016)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Iron and Ruthenium Alkynyl Complexes with 2-Fluorenyl Groups: Some Linear and Nonlinear Optical Absorption Properties

Floriane Malvolti et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride

Nicholas A. Arnet et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

High-Spin Iron(II) Alkynyl Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Reactivity Study

Xiaojie Wang et al.

ORGANOMETALLICS (2015)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Group 8 metal alkynyl complexes for nonlinear optics

Guillaume Grelaud et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and energetics of Tp′Rh[P(OMe)3](R)H: a systematic investigation of ligand effects on C-H activation at rhodium

Yunzhe Jiao et al.

CHEMICAL SCIENCE (2014)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Dinitrogen Activation at Iron and Cobalt Metallalumatranes

P. Alex Rudd et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2013)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Catalytic and Stoichiometric Cumulene Formation within Dimeric Group 2 Acetylides

Merle Arrowsmith et al.

ORGANOMETALLICS (2013)

添加到收藏夹

Review Chemistry, Multidisciplinary

Transition metal-catalyzed decarboxylative coupling reactions of alkynyl carboxylic acids

Kyungho Park et al.

RSC ADVANCES (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes

Gereon M. Yee et al.

CHEMICAL COMMUNICATIONS (2011)

添加到收藏夹

Review Chemistry, Multidisciplinary

Transition-metal catalyzed oxidative cross-coupling reactions to form C-C bonds involving organometallic reagents as nucleophiles

Wei Shi et al.

CHEMICAL SOCIETY REVIEWS (2011)

添加到收藏夹

Review Chemistry, Multidisciplinary

Applications of gold(I) alkynyl systems: a growing field to explore

Joao Carlos Lima et al.

CHEMICAL SOCIETY REVIEWS (2011)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Metal alkynyl complexes as switchable NLO systems

Katy A. Green et al.

COORDINATION CHEMISTRY REVIEWS (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

N2 Functionalization at Iron Metallaboratranes

Marc-Etienne Moret et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

添加到收藏夹

Review Chemistry, Multidisciplinary

Copper-catalyzed azide-alkyne cycloaddition (CuAAC) and beyond: new reactivity of copper(I) acetylides

Jason E. Hein et al.

CHEMICAL SOCIETY REVIEWS (2010)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Unusual Electronic Effects Imparted by Bridging Dinitrogen: an Experimental and Theoretical Investigation

Wesley A. Hoffert et al.

INORGANIC CHEMISTRY (2010)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Transition Metal Acetylide Rearrangement and Coupling Induced by Coordinative Unsaturation

Chengbao Ni et al.

ORGANOMETALLICS (2009)

添加到收藏夹

Review Chemistry, Multidisciplinary

Cu-catalyzed azide-alkyne cycloaddition

Morten Meldal et al.

CHEMICAL REVIEWS (2008)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Dinitrogen and acetylide complexes of low-valent chromium

Louise A. Berben et al.

INORGANIC CHEMISTRY (2008)

添加到收藏夹

Review Chemistry, Multidisciplinary

Multinuclear silver ethynide supramolecular synthons for the construction of coordination networks

Thomas C. W. Mak et al.

CHEMISTRY-AN ASIAN JOURNAL (2007)

添加到收藏夹

Review Chemistry, Multidisciplinary

Synthesis and reactivity of low-coordinate iron(II) fluoride complexes and their use in the catalytic hydrodefluorination of fluorocarbons

J Vela et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Low-coordinate iron(II) amido complexes of β-diketiminates:: Synthesis, structure, and reactivity

NA Eckert et al.

INORGANIC CHEMISTRY (2004)

添加到收藏夹

Review Chemistry, Multidisciplinary

Metal alkynyl sigma complexes: Synthesis and materials

NJ Long et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Bi- and oligometallic early and late transition metal complexes based on alkynyl-titanocenes and related species spanned by carbon rich π-systems

H Lang et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2002)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.