Effect of Poly(vinyl alcohol) on Catalytic Performance of Al-Pillared Clay in Alkylation of Aromatic Hydrocarbons with Olefins

It is vital to design and synthesize efficient catalysts for removing olefins from aromatics and prolonging reaction time. The catalytic properties of pillared clay for olefin removal from aromatic compounds can be enhanced noticeably by grafting organic polymer molecules due to modification of the clay porosity in the pillaring reaction. In the present work, a series of catalysts are prepared by pillaring raw bentonite and acid-treated bentonite with aluminum and poly(vinyl alcohol) (PVA) intercalation. Prepared samples are evaluated in the olefin removal process and characterized by X-ray diffraction patterns (XRD), temperature-programmed desorption (TPD) of NH3, and nitrogen adsorption- desorption isotherms. The BET results reveal that the pillaring reaction in an aqueous solution of PVA increases the clay's surface area to greater than 200 m2.g-1. The pore volume of alumina-pillared acid-activated clay (Al-PAAC) is enhanced from 0.278 to 0.321 and 0.416 cm3.g-1 at the PVA concentrations of 30 and 50 wt %, respectively. The samples modified with PVA, as a precursor in the pillaring reaction, show an enhanced catalytic activity compared to the other samples due to a higher number of active sites. The olefin conversion of the pillared sample remains above 50% in the presence of 50 wt % PVA for more than 26 h. Furthermore, PVA could facilitate the reactant's access to the active acid sites in the interlayer of the pillared clay. The adsorption of aromatic compounds and olefins by the pillared samples follows the intraparticle diffusion kinetic model. In addition, the Langmuir model fits the adsorption isotherm data well.

Automated summary

In this study, the catalytic properties of pillared clay for olefin removal from aromatic compounds were improved by modifying the clay porosity with organic polymer molecules. The surface area of acid-activated clay treated with calcium ion (Al-PAAC) was increased from 0.278 to 0.321 and 0.416 cm3.g-1 at PVA concentrations of 30% and 50%, respectively. The PVA-modified samples showed higher catalytic activity compared to other samples due to more active sites. The olefin conversion of the pillared sample remained above 50% in the presence of 50% PVA for more than 26 hours.