期刊
CERAMICS INTERNATIONAL
卷 41, 期 9, 页码 10766-10774出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2015.05.012
关键词
Powders: solid state reaction; X-ray methods; Batteries; LiVPO4F; In-situ observation
资金
- Ningbo Key Innovation Team [2014B81005]
- Ningbo Natural Science Foundation [2014A610042]
- K.C. Wong Magna Fund in Ningbo University
In this work, a novel lithium storage material LiVPO4F is synthesized and reported for advanced lithium-ion batteries. By using the carbothermal reduction method, LiVPO4F is prepared with VPO4 as the intermediate precursor. The as-prepared LiVPO4F particles reveal an average particle size of 400 nm and are surrounded by conductive carbon black particles with size of 30-50 nm. Over-discharge tests show that LiVPO4F has good reversibility with the discharge/charge capacities of 556.0/391.4 mAh g(-1) in the potential range of 0.0-4.7 V. In-situ and ex-situ observations prove that the structural evolution of VPO4F during an over-discharge process to 0.0 V is associated with the phase transformation of VPO4F-->LiVPO4F-->Li2VPO4F-->Li3VPO4F. The corresponding recharge process is a quasi-reversible reaction, which is related to the delithiation process of Li3VPO4F-->Li2VPO4F-->LiVPO4F-->LixVPO4F-->VPO4F. All these results indicate that LiVPO4F has good over-discharge resistant ability as cathode material for lithium-ion batteries. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
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