H2 and CH4 outgassing rates in the Samail ophiolite, Oman: Implications for low-temperature, continental serpentinization rates

Reduced (H2- and CH4-rich) and hyperalkaline fluids are products of subsurface reactions accompanying serpentinization of ultramafic rocks. H2 and CH4 produced during serpentinization can fuel microorgan-isms and support habitable subsurface environments. CH4 is also a potent greenhouse gas and can offset negative greenhouse emissions arising from active CO2 removal accompanying carbon mineralization in ultramafic rocks. However, the rate at which reduced volatiles are delivered to the surface and the rate of reactions that generate these volatiles at low-temperature conditions are poorly known. In this work, we measured H-2 and CH4 outgassing rates in several hyperalkaline spring sites in the Samail ophiolite, Oman. H-2 and CH4 outgassing in these sites are variable and range up to 70,000 and 7,000 mol yr(1), respectively. CH4 outgassing in spring sites are unlikely to offset negative carbon emissions estimated from active car-bon mineralization reactions in the Samail ophiolite. However, diffused CH4 outgassing from peridotite outcrops remain unconstrained. Compositional and isotopic constraints show that volatiles are likely derived from active serpentinization, fluid inclusion decrepitation, or a combination of both. Calculated active serpentinization rates of up to 8 x 10-14 sec(-1) account for measured outgassing rates and these are consistent with slow rates expected at low temperatures. In calculations of serpentinization rates, this work uses reaction-path models to account incorporation of both ferrous and ferric iron in the resulting alteration assemblages, which yields similar to 0.3 mol H-2 kg(-1) of ultramafic rock altered, lower than simulations based on iron oxidation to magnetite only. Contribution from decrepitation of H2- and CH(4-)bearing fluid inclusions is possible but would require much more mass of ultramafic rocks to account for observed out -gassing. Further studies can help quantify extents of each source on active outgassing in Oman. Overall, this work shows that low-temperature serpentinization on geologically short timescales can account for observed flux of reduced volatiles in hyperalkaline environments.(c) 2023 Elsevier Ltd. All rights reserved.

Automated summary

Reduced and hyperalkaline fluids produced during serpentinization of ultramafic rocks can support subsurface habitats and offset greenhouse emissions. However, the rates of fluid delivery to the surface and generation of reduced volatiles at low-temperature conditions are poorly understood.