期刊
CERAMICS INTERNATIONAL
卷 41, 期 1, 页码 1087-1092出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2014.09.033
关键词
Aurivillius phase; Multiferroic; Bi4NdTi3FeO15; Ni-doping
资金
- National Nature Science Foundations of China [51002047, 11274101]
- Department of Education of Hubei Province [Q20081005]
Ceramics of Ni-doped Bi4NdTi3Fe1-xNixO15 (x=0.1, 0.3, 0.5 and 0.7) (Ni-x) were synthesized by a multicalcination procedure. The substitution of Ni for Fe does not change the layered perovskite structure of Bi4NdTi3FeO15 (BNTF) except that a small amount of Ni2O3 appears in the Ni-0.7 sample. Plate-like morphology of the grains which is characteristic for layer-structure Aurivillius compounds was clearly observed for all the Ni-x samples. The epsilon(r), 2P(r) and 2M(r) values are not proportional to the Ni doping concentration but increase firstly and then decrease. Taking into account ferroelectric and magnetic properties together the optimum room temperature (RT) multiferroic property was acquired in the Ni-0.3 sample within the range of experiment, which is preliminarily discussed from the radius difference of magnetic ions, their ratio and the location of different magnetic ions. The present work is meaningful for compositional design of RT multiferroic materials based on four-layer structured Aurivillius compounds. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
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