期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 163, 期 8, 页码 A1672-A1677出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0821608jes
关键词
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资金
- Joint Center for Energy Storage Research, an Energy Innovation Hub - U.S. Department of Energy, Office of Science, Basic Energy Sciences
- [DE-AC02-06CH11357]
The effect of MgCl2 on a series of chloride containing magnesium electrolytes was investigated. In the presence of extra MgCl2, the electrochemical properties of Grignard reagents (RMgCl, R = Ph, Et, iPr) were significantly improved, and the advantage of MgCl2 was further demonstrated in Mg-Mo6S8 rechargeable batteries with improved capacities and much smaller over-potentials. MgCl2 was then further proven to be a powerful reagent to improve the performance of well-established strong Lewis acid derived magnesium electrolytes including the all-phenyl complex (APC) and alkoxide-based magnesium electrolytes. The results suggest that MgCl2 salt is a very important species to benefit all chloride containing electrolytes for rechargeable magnesium-ion batteries. (C) 2016 The Electrochemical Society. All rights reserved.
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