期刊
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
卷 64, 期 2, 页码 124-132出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.201600241
关键词
Carbodicarbene; Bent allene; Carbone; N-Heterocyclic carbenes; N-Hetereocyclic olefin
资金
- Ministry of Science & Technology, Taiwan [MOST 104-2628-M-001-005-MY4]
- Academia Sinica Career Development Award
The pursuit of unusual bonding environments of carbon species with non-octet electronic configurations has been quite active in fundamental organic and theoretical chemistry for many decades. In this respect, a distinct carbone species has been successfully isolated recently and defined as carbodicarbene or bent allene. This neutral two-coordinated central carbon atom possesses two electron lone pairs, while its octet deficiency is overcome by sigma donation of N-heterocyclic carbenes (NHCs) bound to the central carbon. The present review is focused on the rich chemistry of carbodicarbenes in the aspects of synthesis, characterization, and ligand science of metal complex as well as their intrinsic reactivities.
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