期刊
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
卷 27, 期 12, 页码 2216-2225出版社
SOC BRASILEIRA QUIMICA
DOI: 10.5935/0103-5053.20160114
关键词
voltammetric determination; carboxyl; multiwalled carbon nanotubes; sulfamethazine; sulfamethoxazole
资金
- National Natural Science Foundation of China [61301037]
- Foundation of Henan Educational Committee [13A550194]
- Key Project of Zhengzhou [20120663]
- Plan for Scientific Innovation Talent of Henan University of Technology [2012CXRC02]
- Fundamental Research Funds for the Henan Provincial Colleges and Universities [2014YWQQ05]
- Youth Backbone Teacher Training Program of Henan University of Technology
- Master's Degree Thesis Cultivation Project of Henan University of Technology [PY201504]
New glassy carbon electrode (GCE) modified with carboxyl multiwalled carbon nanotubes (MWCNTs) and treated with ultrasonic dispersing in N, N-dimethylfomamide (DMF) media, namely DMF/carboxyl/MWCNTs/GCE, was prepared for electrochemical determination of sulfonamides (SAs). Electrochemical behavior of SAs based on DMF/carboxyl/MWCNTs/GCE was investigated by cyclic voltammetry and impedance spectroscopy. The effects of various experimental parameters on the response of electrode such as pH of buffer, scan rate and the amount of modification were optimized. Under the optimal conditions, the obtained sensor presented linear response to SAs in the range of 5.0 x 10(-7) to 1.1 x 10(-4) mol L-1 of sulfonamide (R = 0.999), sulfamethazine (R = 0.990), sulfadiazine (R = 0.997), sulfamethoxazole (R = 0.996) and the limits of detection of 1.65 x 10(-8), 3.19 x 10(-8), 6.76 x 10(-8) and 9.41 x 10(-8) mol L-1, respectively. The recoveries were in the range of ca. 85-103% with relative standard deviation (RSD) < 5%. The sensor was tested by cyclic voltammetry with repeatability and stability of more than 90% of its original activity. The proposed method might offer feasibility and applicability of the sensor for further complex sulfonamides compounds.
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