Low-Temperature Selective Catalytic Reduction of NO with NH3 over a Biochar-Supported Perovskite Oxide Catalyst

Maintaining high denitration efficiency for the selective catalytic reduction with ammonia (NH3-SCR) at low temperatures is challenging. In this work, a modified biochar-supported perovskite oxide catalyst was synthesized and implemented to NO conversion in the low temperature range of 100-250 degrees C. Different modification methods were compared, where the combination of nitric acid and air oxidation treatment endowed biochar with abundant acidic surface oxygen-containing groups and a higher specific surface area as a support. The perovskite oxide (LaMnO3) and the LaMnO3/biochar catalysts were prepared to investigate the interactions between the catalyst and the support. The LaMnO3/biochar catalyst exhibited excellent denitration efficiency and good N2 selectivity, achieving over 80% NO conversion within the entire temperature range of 100-250 degrees C (SN2 > 90%), and the highest NO conversion reached 95.8% at 225 degrees C (SN2 = 95.4%). This catalyst provided synergistic adsorption capacity for NH3 as a result of the acidic function of perovskite oxide and acidic oxygen-containing functional groups of the modified biochar support. Additionally, LaMnO3 showed an eminent redox capability for NO conversion due to the high content of Mn4+ and chemically adsorbed oxygen species. Finally, NH3-SCR reaction mechanisms were proposed on the basis of transient response experiments and in situ diffuse reflectance infrared Fourier transform spectra (DRIFTS) characterization.

Automated summary

In this study, a modified biochar-supported perovskite oxide catalyst was synthesized to achieve high denitration efficiency for selective catalytic reduction with ammonia (NH3-SCR) at low temperatures. Different modification methods were compared, and it was found that the combination of nitric acid and air oxidation treatment provided a biochar support with abundant acidic surface oxygen-containing groups and a higher specific surface area. The LaMnO3/biochar catalyst exhibited excellent denitration efficiency and good N2 selectivity, achieving over 80% NO conversion within the entire temperature range of 100-250 degrees C. The catalyst provided synergistic adsorption capacity for NH3 through the acidic function of perovskite oxide and modified biochar support, and LaMnO3 showed a strong redox capability for NO conversion due to the high content of Mn4+ and chemically adsorbed oxygen species. The NH3-SCR reaction mechanisms were proposed based on transient response experiments and in situ diffuse reflectance infrared Fourier transform spectra (DRIFTS) characterization.