☆ 4.5 Review

Current Status and Future Trends of In Situ Catalytic Upgrading of Extra Heavy Oil

ENERGIES (2023)

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Summary: This paper studies the effect of NiCrWC catalyst surface pre-oxidation on the composition of heavy oil catalytic cracking products and proposes a hypothetical mechanism for the cracking of heavy oil components over pre-oxidized catalysts.

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Summary: In this study, a new ligand was synthesized using sunflower oil as the source material to prepare Fe, Ni, Co and Cu-based oil soluble catalysts. Computational study showed that Cu-based catalyst had the strongest bond energy with the ligand. Experimental results demonstrated the efficiency of the catalysts on heavy oil oxidation process and achieved a maximum temperature shift in the high-temperature oxidation zone.

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Trialkylmethylammonium molybdate ionic liquids as novel oil-soluble precursors of dispersed metal catalysts for slurry-phase hydrocracking of heavy oils

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Experimental study on viscosity reduction of heavy oil with water content by synergistic effect of microwave and nano-catalyst

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Oxidation of heavy crude oils under reservoir conditions: Influence of catalysts and the gas phase

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Experimental Investigation of Metal-Based Calixarenes as Dispersed Catalyst Precursors for Heavy Oil Hydrocracking

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Summary: Using metal-based TBC[6] organic compounds as dispersed catalyst precursors can enhance the upgrading of vacuum gas oil by improving catalytic hydrogenation reactions.

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Tatyana Valeryevna Kukharova et al.

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Iron oxide nanoparticles impact on improving reservoir rock minerals catalytic effect on heavy oil aquathermolysis

Sergey A. Sitnov et al.

Summary: According to the results of this study, the addition of iron oxide nanoparticles at higher temperatures can significantly promote the catalytic activity of aquathermolysis, reducing the content of resins and asphaltenes, and increasing the content of saturates, leading to a decrease in viscosity and an increase in gas proportion of the extracted oil. The data obtained at 250 degrees Celsius confirm the synergistic effect of iron oxide nanoparticles, which can facilitate the decomposition and conversion of heavy oil under hydrothermal conditions.

FUEL (2022)

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Mechanistic and kinetic insight into catalytic oxidation process of heavy oil in in-situ combustion process using copper (II) stearate as oil soluble catalyst

Chengdong Yuan et al.

Summary: In this study, copper (II) stearate was introduced as an oil-soluble catalyst for heavy oil oxidation in in-situ combustion process, leading to a significant reduction in activation energy and improved formation rate and quality of coke-like residues, thereby enhancing the efficiency of heavy oil recovery in in-situ combustion process.

FUEL (2021)

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Oxidation of Heavy Oil Using Oil-Dispersed Transition Metal Acetylacetonate Catalysts for Enhanced Oil Recovery

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Summary: The study focused on transition metal-based acetylacetonates as catalysts for heavy oil oxidation. Cu(acac)(2) showed the most significant catalytic effect, reducing activation energy and improving oxidation efficiency.

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Effect of copper stearate as catalysts on the performance of in-situ combustion process for heavy oil recovery and upgrading

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Summary: Using copper stearate as catalysts can significantly accelerate the combustion of heavy oil, promote fuel deposition and combustion, and make them occur more easily at lower temperatures. In combustion processes, copper stearate can lower the ignition temperature, increase the air/fuel ratio, enhance oil recovery, and achieve a higher level of in-situ oil upgrading.

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Catalytic effects of Al2O3 nano-particles on thermal cracking of heavy oil during in-situ combustion process

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Summary: Bimetallic oxide CoFe2O4 nanoparticles were synthesized and coated with oleic acid to form oil-dispersed catalyst for accelerated heavy oil oxidation. The catalytic activity of CoFe2O4@oleic acid nanoparticles was higher than CoFe2O4, promoting the heavy oil oxidation process.

FUEL (2021)

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Oil-Dispersed α-Fe2O3 Nanoparticles as a Catalyst for Improving Heavy Oil Oxidation

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