期刊
ELECTROCHIMICA ACTA
卷 447, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2023.142157
关键词
Spinel-structure high entropy oxide; Sodium ion battery; Entropy stabilization effect; Oxygen vacancy; In situ XRD
By introducing the concept of high entropy into conventional transition metal oxides, spinel high-entropy oxide [(FeCoNiMn)(1-x)Nax](3)O-4 was successfully prepared, showing impressive stability in sodium ion batteries. The high entropy stabilization effect, along with the precise adjustment of oxygen vacancy, enables improved cycling performance, reversible capacity, coulombic efficiency, and rate performance.
Rapid capacity decay is a crucial issue for conversion reaction anodes of sodium ion batteries (SIBs). Here, we introduced the concept of high entropy into the conventional transition metal oxides, successfully preparing spinel high-entropy oxide [(FeCoNiMn)(1-x)Nax](3)O-4 (x = 0.05, 0.08, 0.12) (named after HEO 0.12, HEO 0.08, HEO 0.05) by spray pyrolysis. Due to the entropy stabilization effect, an electrode material exhibits respectable stability. Simultaneously, the precise adjustment of oxygen vacancy accomplished by ion substitution demon-strates that oxygen vacancy naturally in HEO not only provides additional active sites for Na+ accommodation and lowers the sodiation energy barrier enabling reversible Na+ intercalation, but also effectively propels charge transfer. As a result, the cooperation of the entropy stabilization effect and oxygen vacancy makes HEO 0.12 competitive in terms of cycling performance (average capacity decay of 0.069% cycle(-1) at 1000 mA g(+1)), reversible specific capacity, coulombic efficiency and rate performance compared to those of counterparts. Significantly, the evolution of composition and structure during cycling suggests that the key inducing factors for the satisfactory cycling stability of HEO are the excellent reaction reversibility and structure durability, exca-vating the nature of the entropy stabilization effect. This work sheds novel insights into the development of anodes for SIBs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据