☆ 4.7 Article

Synthesis, Structure, and Magnetic Properties of Homometallic Mono-, Penta-, and Hexanuclear Dysprosium Complexes

CRYSTAL GROWTH & DESIGN (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Applied

Structures and magnetic properties of two series of Schiff base binuclear lanthanide complexes

Ying Lu et al.

Summary: The relationship between the structure and magnetic properties of two series of binuclear Ln complexes was investigated. One of the complexes exhibited field-induced single-molecule magnet behavior, while the other did not. In addition, the magnetocaloric effect of two complexes was studied.

APPLIED ORGANOMETALLIC CHEMISTRY (2023)

添加到收藏夹

Article Chemistry, Physical

Symmetrical Pd(II) and Ni(II) Schiff base complexes: Synthesis, crystal structure determination, spectral characterization, and theoretical studies

Mehdi Fallah-Mehrjardi et al.

Summary: New palladium(II) and nickel(II) complexes of symmetrical Schiff base ligand derived from 4,5-dimethyl-o-phenylenediamine were prepared and their molecular structures were investigated using elemental analysis and spectroscopic methods. The crystal structure analysis revealed that the coordination environment of nickel in the NiL complex is tetra-coordinate with slightly distorted square planar geometry. Hirshfeld surface investigation provided further understanding of the intermolecular interactions, and theoretical calculations supported the experimental findings.

JOURNAL OF MOLECULAR STRUCTURE (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Effects of Counterions, Coordination Anions, and Coordination Solvent Molecules on Single-Molecule Magnetic Behaviors and Nonlinear Optical Properties of Chiral Zn2Dy Schiff Base Complexes

Cai-Ming Liu et al.

Summary: In this study, the influence of changing counterions and coordination anions on the structures and performances of Zn2Dy chiral single-molecule magnets was investigated. The results showed that these factors have significant effects on the magnetic and nonlinear optical properties of the complexes.

INORGANIC CHEMISTRY (2022)

添加到收藏夹

Editorial Material Multidisciplinary Sciences

Lanthanide single-molecule magnets with high anisotropy barrier: where to from here?

Zhenhua Zhu et al.

NATIONAL SCIENCE REVIEW (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Subcomponent self-assembly of circular helical Dy6(L)6 and bipyramid Dy12 (L)8 architectures directed via second-order template effects

Xiao-Lei Li et al.

Summary: In situ metal-templated (hydrazone) condensation of 4,6-dihydrazino-pyrimidine, o-vanillin, and dysprosium ions resulted in the formation of discrete hexa- or dodecanuclear metallosupramolecular Dy-6(L)(6) or Dy-12(L)(8) aggregates. The structures exhibited unique circular helical or tetragonal bipyramid architectures, and the coordination mode of the bis(hydrazone) ligand L varied depending on the complex. The formation of the aggregates could be controlled by adjusting the reaction conditions. Dy-6(L)(6) showed a significant spin-relaxation energy barrier of 435 K, making it a promising candidate for lanthanide single-molecular magnets.

CHEMICAL SCIENCE (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Slow magnetic relaxation in a Dy3 triangle and a bistriangular Dy6 cluster

Wen Wang et al.

Summary: In this study, two lanthanide single-molecule magnets were synthesized and characterized structurally and magnetically. Both compounds exhibited strong magnetic relaxation behavior, but with different magnetic properties. Ab initio calculations revealed the nature of their distinct magnetic properties.

DALTON TRANSACTIONS (2022)

添加到收藏夹

Review Materials Science, Multidisciplinary

Emerging Trends on Designing High-Performance Dysprosium(III) Single-Molecule Magnets

Tesfay G. Ashebr et al.

Summary: This Review discusses the recent trends in key synthetic strategies for achieving exotic magnetic properties and provides representative seminal reports. Special emphasis is given to monomeric high-performance Dy(III)-SMMs realized through crystal field, predominant bond, and organometallic approaches, as well as stimulating reports on endometallofullerenes and radical-bridged systems with strong magnetic coupling. The role of spin-vibration coupling in magnetic relaxation is also highlighted. More demanding theoretical studies are anticipated to predict promising molecules with magnetization blocking at practical temperatures.

ACS MATERIALS LETTERS (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Shining New Light on Multifunctional Lanthanide Single-Molecule Magnets

Riccardo Marin et al.

Summary: Single-molecule magnets play a crucial role in quantum information processing and spintronics. The harmonious combination of magnetism and luminescence within single molecules provides insights for emerging next-generation spintronics devices.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

High-Coordinate Mononuclear Ln(III) Complexes: Synthetic Strategies and Magnetic Properties

Joydev Acharya et al.

Summary: Research on single-molecule magnets involving monometallic 4f complexes has been conducted extensively in the past two decades, with the aim of understanding the factors governing slow magnetization relaxation and establishing a magneto-structural correlation. The main goal is to suppress the temperature independent quantum tunneling of magnetization effect by fine-tuning the coordination geometry. Investigating complexes containing high coordination number around Ln(III) has been relatively sparse, but various synthetic strategies have been used for assembling 10- and 12-coordinated Ln(III) complexes.

MAGNETOCHEMISTRY (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Mononuclear Dysprosium Alkoxide and Aryloxide Single-Molecule Magnets

Vijay S. Parmar et al.

Summary: Recent studies have shown that mononuclear lanthanide (Ln) complexes can be high-performing single-molecule magnets (SMMs). The focus is on mononuclear Dy-III alkoxide and aryloxide SMMs with coordination numbers up to eight, covering synthesis, solid-state structures and magnetic attributes. Brief overviews are also provided of mononuclear Tb-III, Ho-III, Er-III and Yb-III alkoxide and aryloxide SMMs.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

Andoni Zabala-Lekuona et al.

Summary: The discovery of Single-Molecule Magnets in 1993 revolutionized the field of information storage by shrinking the size of bits to molecular levels. Despite initially operating at temperatures near absolute zero, collaboration between chemists and physicists have led to the development of materials that can operate above liquid nitrogen temperatures. The evolution of SMMs has involved the study of various routes towards high performance materials, with each route essential for understanding the quantum dynamics behind these molecules.

COORDINATION CHEMISTRY REVIEWS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Air-Stable Chiral Single-Molecule Magnets with Record Anisotropy Barrier Exceeding 1800 K

Zhenhua Zhu et al.

Summary: By introducing fluorinated substituents on the ligands, two chiral Dy(III) macrocyclic complexes with high anisotropy barrier and relaxation time were obtained, providing a new avenue for improving air-stable SMMs and depositing SMMs on surfaces.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Syntheses, structural modulation, and slow magnetic relaxation of three dysprosium(III) complexes with mononuclear, dinuclear, and one-dimensional structures

Hua-Jian Ye et al.

Summary: Three novel dysprosium complexes based on 3-azotriazolyl-2,6-dihydroxybenzoic acid were synthesized and structurally characterized by X-ray crystallography, showing mononuclear, dinuclear, and one-dimensional structures. Magnetic measurements revealed diverse magnetic behaviors in the complexes, including slow magnetic relaxation and energy barriers. Ab initio calculations were also conducted to investigate the magnetic behavior of the complexes.

DALTON TRANSACTIONS (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

pH manipulates the assembly of a series of dysprosium clusters with subtle differences

Hai-Ling Wang et al.

Summary: Changing the pH of the reaction solution led to different coordination environments of the metal center Dy5 in the structures of pentanuclear dysprosium clusters, demonstrating the importance of pH in fine-tuning the structure of lanthanide clusters with the same shape.

INORGANIC CHEMISTRY FRONTIERS (2021)

添加到收藏夹

Article Materials Science, Multidisciplinary

Acid and alkali-resistant Dy4 coordination clusters: synthesis, structure and slow magnetic relaxation behaviors

Shui Yu et al.

Summary: Two newly synthesized coordination clusters based on [Dy-4] structures exhibit excellent magnetic properties and stability in water and common organic solvents. This breakthrough in the stability of 0D coordination compounds could potentially lead to the development of chemically stable single-molecule magnets for applications in moist and acidic/alkaline media.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Development of Single-Molecule Magnets†

Dong Shao et al.

CHINESE JOURNAL OF CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Substituent Effects on Exchange Coupling and Magnetic Relaxation in 2,2′-Bipyrimidine Radical-Bridged Dilanthanide Complexes

Colin A. Gould et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Blocking like it's hot: a synthetic chemists' path to high-temperature lanthanide single molecule magnets

Conrad A. P. Goodwin

DALTON TRANSACTIONS (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Concomitant emergence of circularly polarized luminescence and single-molecule magnet behavior in chiral-at-metal Dy complex

Bahjat El Rez et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Trinuclear and Hexanuclear Lanthanide(III) Complexes of the Chiral 3+3 Macrocycle: X-ray Crystal Structures and Magnetic Properties

Tomasz Bereta et al.

INORGANIC CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Air-Stable Hexagonal Bipyramidal Dysprosium(III) Single-Ion Magnets with Nearly Perfect D6h Local Symmetry

Zi-Han Li et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Molecular magnetism of lanthanide: Advances and perspectives

Zhenhua Zhu et al.

COORDINATION CHEMISTRY REVIEWS (2019)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Two Dy(III) Single-Molecule Magnets with Their Performance Tuned by Schiff Base Ligands

Shui Yu et al.

INORGANIC CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Physical

Double and triple pyridine-N-oxide bridged dinuclear Dysprosium(III) dimers and single-molecule magnetic properties

Ling Zhang et al.

JOURNAL OF MOLECULAR STRUCTURE (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Symmetry strategies for high performance lanthanide-based single-molecule magnets

Jun-Liang Liu et al.

CHEMICAL SOCIETY REVIEWS (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Assembly of Lanthanide(III) Cubanes and Dimers with Single-Molecule Magnetism and Photoluminescence

Ho-Yin Wong et al.

INORGANIC CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Cyano-Bridged Fe(II)-Cr(III) Single-Chain Magnet Based on Pentagonal Bipyramid Units: On the Added Value of Aligned Axial Anisotropy

Celine Pichon et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Structure and magnetism of two chair-shaped hexanuclear dysprosium(III) complexes exhibiting slow magnetic relaxation

Zi-Yuan Liu et al.

RSC ADVANCES (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

The slow magnetic relaxation regulated by the coordination, configuration and intermolecular dipolar field in two mononuclear Dy-III single-molecule magnets (SMMs)

Sheng Zhang et al.

DALTON TRANSACTIONS (2018)

添加到收藏夹

Article Multidisciplinary Sciences

Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

Fu-Sheng Guo et al.

SCIENCE (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

A New {Dy5} Single-Molecule Magnet Bearing the Schiff Base Ligand N-Naphthalidene-2-amino-5-chlorophenol

Dimitris I. Alexandropoulos et al.

MAGNETOCHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Molecular Cobalt Catalysts for O2 Reduction: Low-Overpotential Production of H2O2 and Comparison with Iron-Based Catalysts

Yu-Heng Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Multidisciplinary Sciences

Molecular magnetic hysteresis at 60 kelvin in dysprosocenium

Conrad A. P. Goodwin et al.

NATURE (2017)

添加到收藏夹

Editorial Material Chemistry, Physical

SPINTRONICS The molecular way

Andrea Cornia et al.

NATURE MATERIALS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Homometallic DyIII Complexes of Varying Nuclearity from 2 to 21: Synthesis, Structure, and Magnetism

Sourav Biswas et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Two {Dy2} single-molecule magnets formed via an in situ reaction by capturing CO2 from atmosphere under ambient conditions

Kun Zhang et al.

DALTON TRANSACTIONS (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Understanding the Magnetic Anisotropy toward Single-Ion Magnets

Yin-Shan Meng et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet

You-Song Ding et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

A planar triangular Dy3 + Dy3 single-molecule magnet with a toroidal magnetic moment

Xiao-Lei Li et al.

CHEMICAL COMMUNICATIONS (2016)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Syntheses, structures and magnetic properties of two Dy6 clusters based on polydentate ligands with a new topological motif

Jia-Ping Tong et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(III) Single-Ion Magnets

Yan-Cong Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Stable Pentagonal Bipyramidal Dy(III) Single-Ion Magnet with a Record Magnetization Reversal Barrier over 1000 K

Jiang Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

High symmetry or low symmetry, that is the question - high performance Dy(III) single-ion magnets by electrostatic potential design

Wen-Bin Sun et al.

CHEMICAL SCIENCE (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

An air-stable Dy(III) single-ion magnet with high anisotropy barrier and blocking temperature

Sandeep K. Gupta et al.

CHEMICAL SCIENCE (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

Nicholas F. Chilton et al.

CHEMICAL COMMUNICATIONS (2015)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing only one lanthanide ion

Humphrey L. C. Feltham et al.

COORDINATION CHEMISTRY REVIEWS (2014)

添加到收藏夹

Article Multidisciplinary Sciences

Electrically driven nuclear spin resonance in single-molecule magnets

Stefan Thiele et al.

SCIENCE (2014)

添加到收藏夹

Review Chemistry, Multidisciplinary

Lanthanide Single-Molecule Magnets

Daniel N. Woodruff et al.

CHEMICAL REVIEWS (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Coexistence of Distinct Single-Ion and Exchange-Based Mechanisms for Blocking of Magnetization in a CoII2DyIII2 Single-Molecule Magnet

Kartik Chandra Mondal et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enhancing Anisotropy Barriers of Dysprosium(III) Single-Ion Magnets

Gong-Jun Chen et al.

CHEMISTRY-A EUROPEAN JOURNAL (2012)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Molecular Assembly and Magnetic Dynamics of Two Novel Dy6 and Dy8 Aggregates

Yun-Nan Guo et al.

INORGANIC CHEMISTRY (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Net Toroidal Magnetic Moment in the Ground State of a {Dy6}-Triethanolamine Ring

Liviu Ungur et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

添加到收藏夹

Article Multidisciplinary Sciences

Electronic read-out of a single nuclear spin using a molecular spin transistor

Romain Vincent et al.

NATURE (2012)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

A Dy6 Cluster Displays Slow Magnetic Relaxation with an Edge-to-Edge Arrangement of Two Dy3 Triangles

Hongshan Ke et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Coupling Dy-3 Triangles Enhances Their Slow Magnetic Relaxation

Ian J. Hewitt et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ab initio investigation of the non-collinear magnetic structure and the lowest magnetic excitations in dysprosium triangles

Liviu Ungur et al.

NEW JOURNAL OF CHEMISTRY (2009)

添加到收藏夹

Article Physics, Multidisciplinary

Spin chirality in a molecular dysprosium triangle: The archetype of the noncollinear ising model

Javier Luzon et al.

PHYSICAL REVIEW LETTERS (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dysprosium triangles showing single-molecule magnet behavior of thermally excited spin states

JK Tang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

添加到收藏夹

Article Chemistry, Multidisciplinary

Lanthanide double-decker complexes functioning as magnets at the single-molecular level

N Ishikawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.