In situ study of chiral symmetry breaking in sodium chlorate solutions by Mueller matrix polarimetry

This work presents a novel approach for investigating symmetry-breaking processes during crystallization using Mueller matrix polarimetry. By applying this method to the cooling process of NaClO3 solutions, we demonstrate its ability to capture not only the initial and final stages of crystallization but also the intermediate steps and dynamics of the process. This technique provides more comprehensive information and insights into the symmetry-breaking mechanisms involved in crystal formation. Overall, this study highlights the potential of Mueller matrix polarimetry for in situ statistical measurements of the optical rotation and for monitoring the evolution of enantiomeric excesses.

Automated summary

This study presents a new approach using Mueller matrix polarimetry to investigate symmetry-breaking processes during crystallization. By applying this method to cooling NaClO3 solutions, the researchers demonstrate its capability to capture the entire process, including the initial and final stages as well as the intermediate steps and dynamics. This technique provides more comprehensive information and insights into the symmetry-breaking mechanisms involved in crystal formation. Overall, this study highlights the potential of Mueller matrix polarimetry for in situ statistical measurements of optical rotation and monitoring the evolution of enantiomeric excesses.