☆ 4.5 Review

Recent advances in non-p-conjugated nonlinear optical sulfates with deep-UV absorption edge

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Review Chemistry, Inorganic & Nuclear

A review of structures and physical properties of rare earth chalcophosphates

Zi-Xia Chen et al.

Summary: Metal chalcophosphates exhibit chemical and structural diversity due to the different ways phosphorus-sulfur/selenium anionic groups connect. Rare earth metals, known for their unique magneto-optical properties, have attracted great interest and have been widely studied. Recent research progress on rare earth chalcophosphates, focusing on their structures and physical properties, is summarized in this review. It is believed that rare earth chalcophosphates have the potential to be multifunctional materials, and this summary aims to provide insights for the development of new rare earth chalcophosphates.

COORDINATION CHEMISTRY REVIEWS (2023)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials

Wenfeng Zhou et al.

Summary: This paper summarizes a class of important infrared nonlinear optical crystals - silver-based chalcogenides, which have outstanding properties. These crystals play an important role in extending laser wavelengths and frequency conversion technology, and have been used in various fields such as civil industry, medicine, and military affairs. By classifying and analyzing their chemical composition and molecular structure, the characteristics of silver-based chalcogenides are summarized, and the research direction and development prospects as infrared nonlinear optical candidate materials are discussed.

COORDINATION CHEMISTRY REVIEWS (2023)

添加到收藏夹

Review Chemistry, Physical

Recent Development of Non-π-Conjugated Deep Ultraviolet Nonlinear Optical Materials

Weiqi Huang et al.

Summary: This article introduces the research progress of deep-UV non-linear optical (NLO) materials, including the properties and structure relationship of p-conjugated and non-pi-conjugated deep-UV NLO crystals, as well as new functional groups. It is found that non-pi-conjugated deep-UV NLO materials are divided into six categories, which are important for balancing performance.

CHEMISTRY OF MATERIALS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nonpolar Na10Cd(NO3)4(SO3S)4 Exhibits a Large Second-Harmonic Generation

Youchao Liu et al.

Summary: Conventional wisdom suggests that nonpolar structures do not favor strong second-harmonic generation responses. However, we report a nonpolar thiosulfate with a stronger SHG response than polar sulfates. This enhancement is mainly attributed to the flexibility of the S=S bond.

CCS CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Physical

A2BeS2O8(A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear OpticalCrystals

Yingshuang Sun et al.

Summary: A series of new noncentrosymmetric beryllium sulfates were designed and synthesized based on the parent borophosphates. They showed high thermodynamic stabilities and enhanced second harmonic generation (SHG) responses. They also exhibited moderate birefringence and transparency in the deep ultraviolet (DUV) region.

CHEMISTRY OF MATERIALS (2022)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Advances in second-order nonlinear optical sulfates

Yaoguo Shen et al.

Summary: This review provides a comprehensive overview of NLO sulfates, including classification, synthesis methods, crystal structure features, optical performances, and structure-property relationships. The key structure-property relationships are summarized to assist new researchers in designing superior sulfate NLO materials.

COORDINATION CHEMISTRY REVIEWS (2022)

添加到收藏夹

Article Materials Science, Multidisciplinary

An Optimized KBe2BO3F2-Like Structure: The Unity of Deep-Ultraviolet Transparency, Nonlinear Optical Property, and Ferroelectricity

Hongyuan Sha et al.

Summary: This study proposes a new design strategy to optimize the KBBF structure and successfully design a new ferroelectric material, Li2KRb(SO4)2. This material exhibits high optical effects and ferroelectricity, and eliminates the layered structure, showing potential applications.

ADVANCED OPTICAL MATERIALS (2022)

添加到收藏夹

Article Nanoscience & Nanotechnology

Alkali metal sulfate: A new non-n-conjugated deep-ultraviolet quasi-phase matching crystal

Hongyuan Sha et al.

Summary: A ferroelectric alkali metal sulfate crystal, LiKSO4, is found to combine a short absorption cutoff edge, a large second harmonic generation response, and the typical ferroelectric polarization reversal into a single structure. It possesses an optimized structure with effective layer connections, offering new possibilities for the development of deep-ultraviolet nonlinear optical materials.

SCRIPTA MATERIALIA (2022)

添加到收藏夹

Review Optics

Deep-ultraviolet nonlinear optical crystals: concept development and materials discovery

Lei Kang et al.

Summary: This article reviews the recent progress in experimental and theoretical research on deep-ultraviolet (DUV) nonlinear optical (NLO) crystals. It discusses the core concepts and stringent criteria for identifying qualified DUV phase-matched second-harmonic generation crystals. The article also explores the development of DUV NLO structure-property correlations from first principles and potential future directions for research.

LIGHT-SCIENCE & APPLICATIONS (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials

Yanqiang Li et al.

Summary: Second-order nonlinear optical (NLO) materials have significant applications in various fields, and the rational assembly of high-performance second-order NLO materials remains a challenge. In this study, a local polarity-induced assembly strategy is proposed, which involves using specific cations, self-condensation of weakly polarizable units, and introduction of strongly polarizable units to facilitate the assembly of second-order NLO materials. Using this strategy, a variety of excellent second-order NLO materials have been successfully assembled, expanding the sources of such materials.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Pushing KTiOPO4-like Nonlinear Optical Sulfates into the Deep-Ultraviolet Spectral Region

Yang Zhou et al.

Summary: This study successfully designed and synthesized two new deep-ultraviolet nonlinear optical crystals by using a bandgap-directed computer-aided material design approach. The transmittance spectrum of one of the crystals, KZnSO4F, showed a significant blue-shifted transparency window to <190 nm, which was explained by first-principles calculations. This work pushes the transparency windows of KTP-like NLO sulfates into the deep-UV spectral region for the first time and will pave a prospective way to the accurate design and synthesis of new deep-UV NLO materials.

INORGANIC CHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A General Principle for DUV NLO Materials: π-Conjugated Confinement Enlarges Band Gap

Lin Xiong et al.

Summary: The paper proposes a general principle, pi-conjugated confinement, to partially decouple the interunit pi-conjugated interactions by separating non-pi-conjugated units, aiming to enlarge the band gap and gain a large optical anisotropy. This principle suggests that carbonophosphates could be a promising new DUV candidate system.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Physical

Non-π-Conjugated Deep-Ultraviolet Nonlinear Optical Crystal K2Zn3(SO4)(HSO4)2F4

Yang Zhou et al.

Summary: A new non-pi-conjugated deep-UV NLO material, K2Zn3(SO4)(HSO4)(2)F-4, has been successfully obtained by the hydrothermal method. It shows good phase matching properties and lower absorption edge, with a birefringence of 0.0126.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Fluorine-Driven Enhancement of Birefringence in the Fluorooxosulfate: A Deep Evaluation from a Joint Experimental and Computational Study

Wenqi Jin et al.

Summary: The study identifies the fluorooxosulfate group as a new functional module for enhancing birefringence, with a birefringence magnitude 4.8-15.5 times higher than sulfates with the same metal cations. Experimental measurements confirm the birefringence enhancement of fluorooxosulfates, while theoretical studies reveal the role of fluorine in inducing anisotropic electronic distribution within the fluorooxo-tetrahedral group.

ADVANCED SCIENCE (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs2Ca2(SO4)3

Yaoguo Shen et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

[ABa2Cl][Ga4S8] (A = Rb, Cs): Wide-Spectrum Nonlinear Optical Materials Obtained by Polycation-Substitution-Induced Nonlinear Optical (NLO)-Functional Motif Ordering

Bin-Wen Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis, characterizations and theoretical analysis of a noncentrosymmetric sulfate

Yaoguo Shen et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates

Yanqiang Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Uniform Alignment of Non-π-Conjugated Species Enhances Deep Ultraviolet Optical Nonlinearity

Jing Lu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical response

Meng Wang et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2019)

添加到收藏夹

Article Chemistry, Physical

Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates

Bingbing Zhang et al.

CHEMISTRY OF MATERIALS (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

CaB5O7F3: A Beryllium-Free Alkaline-Earth Fluorooxoborate Exhibiting Excellent Nonlinear Optical Performances

Zhizhong Zhang et al.

INORGANIC CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Non-Centrosymmetric RbNaMgP2O7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation

Sangen Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

M2B10O14F6 (M = Ca, Sr): Two Noncentrosymmetric Alkaline Earth Fluorooxoborates as Promising Next-Generation Deep-Ultraviolet Nonlinear Optical Materials

Min Luo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Materials Science, Multidisciplinary

A beryllium-free deep-UV nonlinear optical material CsNaMgP2O7 with honeycomb-like topological layers

Sangen Zhao et al.

JOURNAL OF MATERIALS CHEMISTRY C (2018)

添加到收藏夹

Editorial Material Multidisciplinary Sciences

The must-have and nice-to-have experimental and computational requirements for functional frequency doubling deep-UV crystals

P. Shiv Halasyamani et al.

NATURE COMMUNICATIONS (2018)

添加到收藏夹

Article Chemistry, Physical

Monofluorophosphates: A New Source of Deep-Ultraviolet Nonlinear Optical Materials

Lin Xiong et al.

CHEMISTRY OF MATERIALS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ba2NaCIP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure

Jie Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials

T. Thao Tran et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Finding the Next Deep-Ultraviolet Nonlinear Optical Material: NH4B4O6F

Guoqiang Shi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Beryllium-Free β-Rb2Al2B2O7 as a Possible Deep-Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F2

T. Thao Tran et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Chemistry, Physical

M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications

Hongwei Yu et al.

CHEMISTRY OF MATERIALS (2017)

添加到收藏夹

Article Chemistry, Physical

Deep-Ultraviolet Transparent Cs2LiPO4 Exhibits an Unprecedented Second Harmonic Generation

Yaoguo Shen et al.

CHEMISTRY OF MATERIALS (2016)

添加到收藏夹

Review Chemistry, Physical

Deep Ultraviolet Nonlinear Optical Materials

T. Thao Tran et al.

CHEMISTRY OF MATERIALS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response

Lin Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem

Sangen Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba3(ZnB5O10)PO4

Hongwei Yu et al.

ADVANCED MATERIALS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge

Sangen Zhao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material

T. Thao Tran et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)

Peng Yu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Deep-Ultraviolet Transparent Phosphates RbBa2(PO3)5 and Rb2Ba3(P2O7)2 Show Nonlinear Optical Activity from Condensation of [PO4]3- Units

Sangen Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Multidisciplinary Sciences

Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications

Sangen Zhao et al.

NATURE COMMUNICATIONS (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Alkaline-Alkaline Earth Fluoride Carbonate Crystals ABCO3F (A = K, Rb, Cs; B = Ca, Sr, Ba) as Nonlinear Optical Materials

Guohong Zou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

添加到收藏夹

Editorial Material Multidisciplinary Sciences

Materials science: China's crystal cache

David Cyranoski

NATURE (2009)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.