期刊
CHINESE JOURNAL OF CHEMISTRY
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.202300274
关键词
Friedel-Crafts gridization; A-type nanogrids; OFET; Chirality; Nanostructures; Organic chemistry
A novel type of A-type nanogrids (AGs) with axial and central chirality was synthesized via Friedel-Crafts gridization of thiophenes and difluorenyl biaromatic derivatives, yielding 9%-30%. Additionally, the effect of stereoisomers of 1,1'-binaphthyl difluorenols (BINDFOH) was investigated to demonstrate that R/S-BINDFOH is more advantageous for the synthesis of AGs than Mix-BINDFOH. Furthermore, tests on OFET memory devices showed that AGs have a larger storage window, indicating potential for data storage applications.
A novel type of A-type nanogrids (AGs) with axial and central chirality was synthesized via Friedel-Crafts gridization of thiophenes and difluorenyl biaromatic derivatives, yielding 9%-30%. Additionally, the effect of stereoisomers of 1,1'-binaphthyl difluorenols (BINDFOH) was investigated to demonstrate that R/S-BINDFOH is more advantageous for the synthesis of AGs than Mix-BINDFOH. Furthermore, tests on OFET memory devices showed that AGs have a larger storage window, indicating potential for data storage applications.
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