Efficacious selective separation of U(VI) over Mo(VI) using novel 2,9-diamide-1,10-phenanthroline ligands: Liquid-liquid extraction and coordination chemistry

Uranium and molybdenum are important strategic elements. The production of Mo-99 and the hydrometallurgical process of uranium ore face difficult problems of separation of uranium and molybdenum. In this study, the four phenanthroline diamide ligands were synthesized, and extraction and stripping experiments were performed under different conditions to evaluate the potential application of these ligands for separation of U(VI) over Mo(VI). With the growth of alkyl chain, the solubility of ligands could be greatly improved, and the separation effect of U(VI) over Mo(VI) gradually increased. The SFU/Mo were around 10,000 at 4 mol/L HNO3. Three stripping agents were tested with the stripping efficiency of Na2CO3 (5%) > H2O > HNO3 (0.01 mol/L). The stripping percentages of the three stripping agents were all close to unity, indicating that the ligands had the potential to be recycled. The chemical stoichiometry of U(VI) complexes with ligands was evaluated as 1:1 using electrospray ionization mass spectrometry, ultraviolet visible spectroscopy and single-crystal X-ray diffraction. The consistency between theoretical calculation and experimental results further explains the coordination mechanism. (c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences

Automated summary

In this study, four phenanthroline diamide ligands were synthesized and evaluated for the separation of U(VI) from Mo(VI) through extraction and stripping experiments under different conditions. The results showed that the solubility of the ligands and the separation effect of U(VI) over Mo(VI) increased with the growth of alkyl chain. The chemical stoichiometry of U(VI) complexes with ligands was determined as 1:1.