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Covalent Organic Framework-Semiconductor-Based Heterostructures for Photocatalytic Applications

CHEMSUSCHEM (2023)

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Article Chemistry, Physical

Two-Dimensional Benzobisthiazole-Vinylene-Linked Covalent Organic Frameworks Outperform One-Dimensional Counterparts in Photocatalysis

Shengxu Li et al.

Summary: In this work, a stable vinylene/olefin-linked two-dimensional covalent organic framework (v-2D-COF) was synthesized via a benzothiazole-mediated aldol-type polycondensation. The resultant v-2D-COF showed high chemical stability and desirable optoelectronic properties for photocatalytic hydrogen evolution. It exhibited a narrow band gap and an excellent photocurrent, making it a promising material for photocatalytic reactions.

ACS CATALYSIS (2023)

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Article Engineering, Environmental

A core-shell 2D-MoS2@MOF heterostructure for rapid therapy of bacteria-infected wounds by enhanced photocatalysis

Zhenxing Yang et al.

Summary: By constructing a core-shell interface electric field and enhancing oxygen adsorption ability, MoS2@PBMOF can generate high temperature and abundant ROS under light irradiation to kill bacteria, while promoting the healing of damaged tissues.

CHEMICAL ENGINEERING JOURNAL (2023)

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Article Nanoscience & Nanotechnology

Dynamic Interface with Enhanced Visible-Light Absorption and Electron Transfer for Direct Photoreduction of Flue Gas to Syngas

Jie Zhou et al.

Summary: This study reports the photoreduction of CO2 from simulated industrial exhaust using TEOA and a metal-free COF1-g-C3N4 composite. The enhanced light absorption and electron transfer effects of the dynamic interface lead to a high photosynthetic yield of syngas, ranking among the highest of known metal-free catalysts in diluted CO2.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Chemistry, Physical

Defective g-C3N4/covalent organic framework van der Waals heterojunction toward highly efficient S-scheme CO2 photoreduction

Jiangpeng Wang et al.

Summary: This study introduces a novel vdW heterojunction composite of g-C3N4 with nitrogen vacancies and Tp-Tta COF, showing effective interface contact area and improved photocatalytic CO2 reduction performance. The presence of nitrogen vacancies widens the Fermi level gap between g-C3N4 and Tp-Tta COF, leading to enhanced carrier recombination and higher photocatalytic activity and stability. The efficient electron transfer and CO2 affinity of Tp-Tta contribute to the enhanced CO selectivity in the S-scheme heterojunction photocatalyst design for CO2 reduction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Engineering, Environmental

Facet-dependent activity of TiO2/covalent organic framework S-scheme heterostructures for CO2 photoreduction

Xiaoqiang An et al.

Summary: Covalent organic frameworks (COFs) have great potential in constructing S-Scheme junctions with spatial separation and strong redox ability. Engineering the interfacial structure between COF and semiconductor photocatalysts is crucial for high-efficiency CO2 photoreduction. This study focuses on the contribution of material facets to the S-scheme photocatalysis of TiO2/COF heterojunctions, revealing that facet engineering is a versatile approach to improve the efficiency of S-scheme heterostructures for artificial photosynthesis.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Chemistry, Multidisciplinary

MOF-COF Composite Photocatalysts: Design, Synthesis, Mechanism

Guangsong Yuan et al.

Summary: This paper provides a detailed discussion on the design, synthesis, and mechanistic analysis of MOF-COF photocatalysts. It covers the improvement of photocatalytic properties through MOF-COF heterojunction structures, the synthesis of MOF-COF photocatalysts with different core-shell and non-core-shell structures, and the analysis of photocatalytic mechanisms for hydrogen evolution and photodegradation. The challenges and opportunities of MOF-COF photocatalysts are also discussed.

CRYSTAL GROWTH & DESIGN (2022)

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Article Chemistry, Physical

Self-assembly hybridization of COFs and g-C3N4: Decipher the charge transfer channel for enhanced photocatalytic activity

Han Wang et al.

Summary: Organic semiconductors are recognized as a new generation of photocatalysts for pollutants degradation and energy production. In this study, a TpMa/CN heterojunction was fabricated via a controllable self-assembly approach, showing enhanced visible-light absorption and improved photocatalytic activities.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Article Chemistry, Physical

Hierarchical Core-Shell ACOF-1@BiOBr as an Efficient Photocatalyst for the Degradation of Emerging Organic Contaminants

Ahmed E. ElMetwally et al.

Summary: A hierarchical coreshell structure of nanostructured ACOF-1@BiOBr was prepared and its performance in the degradation of organic contaminants under light irradiation was demonstrated. The enhanced photocatalytic activity of the ACOF-1@BiOBr system can be attributed to the synergy between ACOF-1 and BiOBr, which form a Type-II heterostructure that reduces the recombination rate of photogenerated charge carriers. The ACOF-1@BiOBr system also exhibited enhanced generation of superoxide radicals.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

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Article Chemistry, Applied

Construction of TiO2-covalent organic framework Z-Scheme hybrid through coordination bond for photocatalytic CO2 conversion

Lei Wang et al.

Summary: In this study, a covalent organic framework (COF) was constructed with CuTAPP and p-benzaldehyde, integrated with TiO2 to form a Z-scheme hybrid system. The framework showed enhanced photocatalytic performance in CO2 conversion, attributed to the photosensitizer effect of the porphyrin block and the establishment of a Z-scheme system for carrier separation.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Physical

Rational preparation of cocoon-like g-C3N4/COF hybrids: Accelerated intramolecular charge delivery for photocatalytic hydrogen evolution

Lei Wang et al.

Summary: By covalently modifying metal-free graphic carbon nitride with a 2D Schiff-base covalent organic framework, the photoelectrical characteristics and photocatalytic water-splitting efficiency were significantly improved. This modulation strategy at the molecular level provides a new opportunity for constructing carbon nitride based hybrids and regulating their photoelectric behaviors.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Chemistry, Physical

Rational design of 2D/2D covalent-organic framework/TiO2 nanosheet heterojunction with boosted photocatalytic H2 evolution

Hongqiang Shen et al.

Summary: The study introduces a 2D/2D hybrid photosensitive system by integrating 2D Schiff-base covalent-organic frameworks material with 2D TiO2 nanosheets, achieving enhanced photocatalytic performance. Efficient charge flow supply and full solar-energy utilization significantly improve the yield of the heterogeneous composite under visible light irradiation.

APPLIED SURFACE SCIENCE (2022)

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Article Engineering, Environmental

Covalent organic framework based WO3@COF/rGO for efficient visible-light-driven H2 evolution by two-step separation mode

Han Yan et al.

Summary: A core-shell COF-based Z-scheme heterojunction was synthesized, and by constructing a Z-scheme charge transfer pathway and using rGO as a carrier, the photocatalytic activity of COF was enhanced.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Chemical

Photocatalytic detoxification of hazardous pymetrozine pesticide over two-dimensional covalent-organic frameworks coupling with Ag3PO4 nanospheres

Jisheng Liu et al.

Summary: A Z-scheme Ag3PO4/TpPa-1-COF heterojunction was constructed by coupling 2D pi-pi stacking covalent organic framework with Ag3PO4 nanospheres. The heterojunction exhibited excellent photocatalytic activity on the degradation of pesticide and dye under simulated solar irradiation. The structure of the heterojunction contributed to the enhanced photocatalytic performance.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

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Article Chemistry, Physical

Photoelectron Transfer Mediated by the Interfacial Electron Effects for Boosting Visible-Light-Driven CO2 Reduction

Lei Zou et al.

Summary: In this study, a CdS@COF core-shell structure was successfully synthesized through a structural and electronic engineering strategy, which significantly improved the efficiency of photocatalytic CO2 reduction. The integration of CdS as an electron transfer channel enables photoelectron transfer and subsequent CO2 reduction from Zn-porphyrin to Co-bipyridyl units.

ACS CATALYSIS (2022)

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Review Chemistry, Inorganic & Nuclear

Porphyrin and phthalocyanine based covalent organic frameworks for electrocatalysis

Shengsheng Huang et al.

Summary: Covalent organic frameworks (COFs) are a rapidly growing class of crystalline porous polymers that have a wide range of applications due to their unique features. By incorporating porphyrin (Por-) and phthalocyanine (Pc-) building units into COFs, they acquire unique structural characteristics and excellent optical and electrical properties. Recent progress has been made in the rational design and construction of Por- and Pc-based COFs for electrocatalytic water splitting, CO2 reduction, and oxygen reduction. This article provides a summary of the synthetic strategies of Por- and Pc-based COFs, an overview of their applications in electrocatalytic reactions, and discusses the current challenges and directions for further development.

COORDINATION CHEMISTRY REVIEWS (2022)

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Article Chemistry, Multidisciplinary

Direct Construction of Isomeric Benzobisoxazole-Vinylene-Linked Covalent Organic Frameworks with Distinct Photocatalytic Properties

Shengxu Li et al.

Summary: Vinylene/olefin-linked two-dimensional covalent organic frameworks (v-2D-COFs) have been successfully synthesized via solid-state benzobisoxazole-mediated aldol polycondensation, resulting in two isomeric benzobisoxazole-bridged v-2D-COFs with distinct optoelectronic and electrochemical properties.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Multidisciplinary

Piezo-Photocatalytic Synergy in BiFeO3@COF Z-Scheme Heterostructures for High-Efficiency Overall Water Splitting

Mei-Ling Xu et al.

Summary: This study presents a novel approach for solar-driven overall water splitting by combining covalent organic frameworks (COFs) and piezoelectric material to form a Z-scheme core@shell heterostructure. The synergistic effect between the polarized electric field and photo-generated charges, along with the precise adjustment of shell thickness, greatly enhances carrier separation and utilization efficiency. The optimized BiFeO3@TpPa-1-COF photocatalyst exhibits the highest hydrogen and oxygen production rates among various piezo- and COF-based photocatalysts, providing new possibilities for the practical application of highly efficient photocatalytic overall water splitting.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Physical

Enhanced visible-light-driven photocatalytic activity of bi-phase titanium dioxide @ covalent organic framework Z-scheme system for photocatalytic removal of Cr (VI)

Yi Wen et al.

Summary: In this study, a series of catalysts were successfully synthesized and their photocatalytic activity towards the model pollutant Cr(VI) was evaluated. Among them, TiO2@COF-4 showed high efficiency in removing Cr(VI) within 30 minutes and remained stable in consecutive cycles. The morphology and structure of the catalysts were observed using various techniques, and the reasons for the enhancement in photocatalytic performance were analyzed. The experimental results suggested that the photocatalytic system of TiO2@COF-4 may follow a typical direct Z-scheme mechanism. These findings provide an effective solution for water treatment of heavy metal pollution.

APPLIED SURFACE SCIENCE (2022)

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Article Materials Science, Multidisciplinary

Construction of highly active WO3/TpPa-1-COF S-scheme heterojunction toward photocatalytic H2 generation

Long Sun et al.

Summary: By decorating WO3 on covalent organic frameworks, the photocatalytic performance is significantly improved, with higher H-2 evolution rate and apparent quantum efficiency. XPS characterization confirms the formation of internal electric field between WO3 and TpPa-1-COF, which promotes charge separation.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

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Article Chemistry, Physical

Constructing an all zero-dimensional CsPbBr3/CdSe heterojunction for highly efficient photocatalytic CO2 reduction

Guilin Yin et al.

Summary: In this study, an efficient 0D/0D heterojunction consisting of CdSe QDs grown on CsPbBr3 QDs was reported for high-performance photocatalytic CO2 reduction using water as the electron donor. The heterojunction facilitates fast electron transfer and enables efficient CO2 conversion into CO.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Applied

Fabricating covalent organic framework/CdS S-scheme heterojunctions for improved solar hydrogen generation

Long Sun et al.

Summary: In this study, an imine-based porous covalent organic framework (COF-LZU1) was integrated with controllably fabricated CdS hollow cubes to form an S-scheme heterojunction. The COF/CdS heterostructure exhibited enhanced photocatalytic hydrogen generation performance, including a higher hydrogen generation rate and apparent quantum efficiency.

CHINESE JOURNAL OF CATALYSIS (2022)

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Article Energy & Fuels

Advances in 2D/2D Z-Scheme Heterojunctions for Photocatalytic Applications

Xiaolei Liu et al.

Summary: Semiconductor-based photocatalysis technology has attracted attention for its potential in utilizing solar energy to address energy and environmental issues. 2D/2D Z-scheme heterojunctions demonstrate superior performance in photocatalysis due to their rapid charge transfer and effective separation of charge carriers, showing promise in hydrogen production, CO2 reduction, and pollutant degradation.

SOLAR RRL (2021)

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Article Chemistry, Physical

Porphyrin Conjugated Polymer Grafted onto BiVO4 Nanosheets for Efficient Z-Scheme Overall Water Splitting via Cascade Charge Transfer and Single-Atom Catalytic Sites

Jinming Wang et al.

Summary: This work demonstrates a highly efficient overall water photosplitting through the combination of heterometallic Zn-/Pt-porphyrin conjugated polymer and BiVO4 nanosheets. The Z-scheme charge transfer mechanism facilitated by Zn-O-V bridging bonds enables dual functionality in the catalyst and cascade charge transfer with Pt centers.

ADVANCED ENERGY MATERIALS (2021)

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Article Engineering, Chemical

A direct Z-scheme BiOBr/TzDa COF heterojunction photocatalyst with enhanced performance on visible-light driven removal of organic dye and Cr(VI)

Yan Zhang et al.

Summary: Efficient Z-scheme heterojunction photocatalyst BTDC was successfully synthesized by modifying 2D BiOBr with 2D TzDa COF, showing excellent performance in degrading RhB and reducing Cr(VI) under visible light. The enhanced efficiency of BTDC was attributed to accelerated charge carriers separation and transport, enhanced visible light absorption, and increased specific surface area.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Engineering, Chemical

In-situ growth of COF on BiOBr 2D material with excellent visible-light-responsive activity for U(VI) photocatalytic reduction

Xin Zhong et al.

Summary: The study investigated the photocatalytic performance of covalent organic frameworks and heterostructure BiOBr@TpPa-1 for uranium, revealing TpPa-1's enhancements in visible light capture and carrier recombination reduction. BiOBr@TpPa-1 efficiently reduced pre-enriched U(VI) within a short time under visible light irradiation. The results suggest a sustainable alternative for visible-light-driven conversion of high valent radionuclide ions in wastewater.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Multidisciplinary Sciences

Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution

Rufan Chen et al.

Summary: Covalent organic frameworks show promise in photocatalytic hydrogen generation from water, with the incorporation of different transition metals allowing for tuning of the hydrogen evolution rate.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

An Inorganic/Organic S-Scheme Heterojunction H2-Production Photocatalyst and its Charge Transfer Mechanism

Chang Cheng et al.

Summary: This study introduces a strategy for preparing high-efficiency photocatalysts by growing inorganic semiconductors on organic semiconductors, leading to the successful synthesis of an S-scheme heterojunction photocatalyst. Through optimization, the composite material exhibits high hydrogen evolution rate and quantum efficiency.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

2D-2D SnS2/Covalent Organic Framework Heterojunction Photocatalysts for Highly Enhanced Solar-Driven Hydrogen Evolution without Cocatalysts

Dandan Shang et al.

Summary: The preparation of 2D-2D SnS2/TpPa-1-COF heterojunction photocatalyst can accelerate the separation of photogenerated charge carriers, broaden the response range to visible light, and enhance the efficiency of photocatalytic H-2 production.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Multidisciplinary

Photocatalytic Hydrogen Evolution from Water Splitting Using Core-Shell Structured Cu/ZnS/COF Composites

Wenmin Wang et al.

Summary: Hydrogen is a sustainable and clean fuel that has attracted attention as an alternative to fossil fuels for alleviating global warming. The novel Cu/ZnS/COF composite photocatalyst demonstrated efficient hydrogen production due to its unique core-shell structure and abundant active sites.

NANOMATERIALS (2021)

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Article Materials Science, Multidisciplinary

Strategies to enhance photocatalytic activity of graphite carbon nitride-based photocatalysts

Runda Huang et al.

Summary: With the rapid development of the photocatalysis field, graphite carbon nitride (g-C3N4) has been widely used as a visible-light-responsive photocatalyst due to its rich sources and simple preparation. Various strategies to optimize the photocatalytic properties of g-C3N4 include constructing heterojunctions, morphological controlling, metal deposition, ion doping, dye sensitization, etc.

MATERIALS & DESIGN (2021)

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Article Chemistry, Physical

The interfacial charge transfer in triphenylphosphine-based COF/PCN heterojunctions and its promotional effects on photocatalytic hydrogen evolution

Jie Tang et al.

Summary: The novel triphenylphosphine-based covalent organic frameworks (P-COF-1) were introduced into polymeric carbon nitride (PCN) to fabricate P-COF-1/PCN heterojunctions for improved photocatalytic activity in hydrogen evolution. The well-matched band structure between P-COF-1 and PCN facilitates electron migration and enhances photo-generated carriers separation, resulting in enhanced photocatalytic hydrogen evolution efficiency.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Review Chemistry, Physical

Review on hydrogen production photocatalytically using carbon quantum dots: Future fuel

Yogeshwari Vyas et al.

Summary: Carbon quantum dots (CQDs) are zero-dimensional nanoparticles that have gained attention for their potential applications in water splitting for hydrogen production. They exhibit excellent optical and electronic properties, high stability, low toxicity, and can be used for catalytic hydrogen gas production from water under sunlight.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Engineering, Chemical

Facile sonochemical synthesis of CdS/COF heterostructured nanocomposites and their enhanced photocatalytic degradation of Bisphenol-A

Chen Sun et al.

Summary: In this study, new CdS/COF heterostructured nanocomposites were synthesized using a facile sonochemical irradiation method and were found to have enhanced photocatalytic degradation performance towards BPA with the addition of COF. Among the prepared materials, 0.5 wt% CdS/COF exhibited the highest photocatalytic activity, with h(+) and center dot O-2(-) identified as the main active radicals in the photocatalytic reaction for BPA degradation. Additionally, 0.5 wt% CdS/COF showed photocatalytic stability and reusability in degrading BPA.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

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Article Chemistry, Physical

Covalent Organic Frameworks as Emerging Platforms for CO2 Photoreduction

Ha L. Nguyen et al.

Summary: Covalent organic frameworks (COFs) are a new class of porous crystalline materials with semiconductor properties, showing promising performance in CO2 photoreduction catalysis. Principles of design and recent advancements in using COFs for CO2 photoreduction can serve as a reference for developing CO2 reduction catalysts.

ACS CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

Design of well-defined shell-core covalent organic frameworks/metal sulfide as an efficient Z-scheme heterojunction for photocatalytic water splitting

Yan Wang et al.

Summary: The development of a covalent-organic framework (COF)-based Z-scheme heterostructure for solar energy driven water splitting shows promise, with a direct Z-scheme heterostructure COF-metal sulfide hybrid being successfully fabricated in this study. The tight interface formed by chemical bonding between T-COF and CdS, along with proper band alignment and strong interfacial interactions, enable efficient charge separation and transfer, leading to improved efficiency in photocatalytic water splitting.

CHEMICAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Construction of LZU1@WO3 heterojunction photocatalysts: enhanced photocatalytic performance and mechanism insight

Simin Shang et al.

Summary: A new nano-LZU1@WO3 composite photocatalyst was successfully synthesized through a hydrothermal method, exhibiting higher photocatalytic activity than pure WO3 and LZU1 in degrading dye BBR. The improved performance of the composite material is mainly attributed to effective photo-generated charge separation and Z-type heterojunction transfer.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Construction of a novel 2D-2D heterojunction by coupling a covalent organic framework and In2S3 for photocatalytic removal of organic pollutants with high efficiency

Luqiu Li et al.

Summary: This study successfully coupled TpPa-1 COF with In2S3 to form a 2D-2D heterojunction, which effectively accelerated charge transfer, prevented charge carrier recombination, and improved light absorption and specific surface area. The constructed 2D-2D layered structure increased contact area with intimate interface contact, facilitating charge mobility and transfer in the interface. The photocatalytic degradation rates of TC and RhB with the 2D-2D heterojunction were significantly higher compared to pure COF and In2S3.

NEW JOURNAL OF CHEMISTRY (2021)

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Construction of a polymeric cobalt phthalocyanine@mesoporous graphitic carbon nitride composite for efficient photocatalytic CO2 reduction

Hongwei Li et al.

Summary: By polymerizing cobalt phthalocyanine on mesoporous g-C3N4, a hybrid organic/inorganic photocatalyst was prepared for efficient CO2 reduction to CO under visible light irradiation in organic solvents. The photocatalyst exhibited high activity and long-term stability, offering a versatile strategy for synthesizing active composite materials for photocatalysis.

CHEMICAL COMMUNICATIONS (2021)

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Review Materials Science, Multidisciplinary

Nanostructured metal nitrides for photocatalysts

Tingke Rao et al.

Summary: Metal nitrides have attracted attention as catalytic materials for energy transformations, with their morphology, size, defects, and nanostructured construction being critical factors in their efficiency. Research is focused on developing new synthetic methods, cocatalysts, and structural design to enhance activity, selectivity, and stability. Studies are summarized on recent progress in light-induced overall water splitting and CO2 reduction using metal nitride photocatalysts.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Chemistry, Inorganic & Nuclear

Fabrication of 2D/2D COF/SnNb2O6 nanosheets and their enhanced solar hydrogen production

Jianlin Ren et al.

Summary: This study demonstrates the fabrication of 2D/2D heterojunction nanosheets using COF/SnNb2O6 for enhanced solar hydrogen production efficiency. The improved photocatalytic performance is attributed to the formation of a good energy band position and effective charge separation between the two materials. This smart integration of organic and inorganic materials proves to be an effective tactic for developing efficient photocatalysts.

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Article Nanoscience & Nanotechnology

Cu2O Cubes Decorated with Azine-Based Covalent Organic Framework Spheres and Pd Nanoparticles as Tandem Photocatalyst for Light-Driven Degradation of Chlorinated Biphenyls

Ahmed E. ElMetwally et al.

Summary: By loading azine-based COF spheres onto Cu2O cubes and decorating them with palladium nanoparticles, an efficient photocatalytic hybrid material was developed for the degradation of chlorinated biphenyls. The congener with a para chlorine atom was found to be more vulnerable to degradation due to increased conjugation between the phenyl rings induced by the electron-donating effect of the chlorine atom, leading to enhanced planarity and easier removal of the chlorine atom. The data also showed that nucleophilic substitution at the para position had the lowest Gibbs free energy, while substitution at the ortho position had the highest Gibbs free energy.

ACS APPLIED NANO MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Construction of a Z-scheme heterojunction for high-efficiency visible-light-driven photocatalytic CO2 reduction

Guoqiang Zhang et al.

Summary: The article introduces the research progress and advantages of using Z-scheme heterojunction photocatalysts to convert CO2, pointing out its great potential in improving efficiency, stability, and light responsiveness.

NANOSCALE (2021)

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Hetero-nanostructured metal oxide-based hybrid photocatalysts for enhanced photoelectrochemical water splitting - A review

Ch Venkata Reddy et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Covalently integrated core-shell MOF@COF hybrids as efficient visible-light-driven photocatalysts for selective oxidation of alcohols

Guilong Lu et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

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Core-Shell Type Semiconducting Heterostructures for Visible Light Photocatalysis

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CHEMICAL RECORD (2020)

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Highly efficient charge transfer in CdS-covalent organic framework nanocomposites for stable photocatalytic hydrogen evolution under visible light

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SCIENCE BULLETIN (2020)

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Wenhao Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Semiconductor/Covalent-Organic-Framework Z-Scheme Heterojunctions for Artificial Photosynthesis

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Two novel MOFs@COFs hybrid-based photocatalytic platforms coupling with sulfate radical-involved advanced oxidation processes for enhanced degradation of bisphenol A

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Defects Engineering Leads to Enhanced Photocatalytic H2 Evolution on Graphitic Carbon Nitride-Covalent Organic Framework Nanosheet Composite

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LANGMUIR (2020)

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Supercritical CO2 produces the visible-light-responsive TiO2/COF heterojunction with enhanced electron-hole separation for high-performance hydrogen evolution

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Rational combination of covalent-organic framework and nano TiO2 by covalent bonds to realize dramatically enhanced photocatalytic activity

Chang-Cheng Li et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Review Chemistry, Physical

Recent advances in semiconductor metal oxides with enhanced methods for solar photocatalytic applications

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Metal-free 2D/2D heterojunction of covalent triazine-based frameworks/graphitic carbon nitride with enhanced interfacial charge separation for highly efficient photocatalytic elimination of antibiotic pollutants

Shihai Cao et al.

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Article Materials Science, Multidisciplinary

Two-dimensional semiconducting covalent organic frameworks for photocatalytic solar fuel production

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MATERIALS TODAY (2020)

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Article Chemistry, Inorganic & Nuclear

Highly Selective and Active Electrochemical Reduction of CO2 to CO on a Polymeric Co(II) Phthalocyanine@Graphitic Carbon Nitride Nanosheet-Carbon Nanotube Composite

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INORGANIC CHEMISTRY (2020)

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Review Materials Science, Multidisciplinary

Nanostructured CdS for efficient photocatalytic H2evolution: A review

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SCIENCE CHINA-MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Covalent-Organic-Framework-Based Composite Materials

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CHEM (2020)

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Review Chemistry, Physical

A review on graphitic carbon nitride (g-C3N4) based nanocomposites: Synthesis, categories, and their application in photocatalysis

Mohammed Ismael

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

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Article Nanoscience & Nanotechnology

Construction of the 1D Covalent Organic Framework/2D g-C3N4 Heterojunction with High Apparent Quantum Efficiency at 500 nm

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ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Physical

Micro-scale spatial location engineering of COF-TiO2 heterojunctions for visible light driven photocatalytic alcohol oxidation

He Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

A stable covalent organic framework for photocatalytic carbon dioxide reduction

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CHEMICAL SCIENCE (2020)

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Review Chemistry, Physical

Charge steering in ultrathin 2D nanomaterials for photocatalysis

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JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Chemistry, Physical

Covalent organic frameworks: emerging high-performance platforms for efficient photocatalytic applications

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JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Chemistry, Multidisciplinary

Covalent organic framework photocatalysts: structures and applications

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CHEMICAL SOCIETY REVIEWS (2020)

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Article Chemistry, Physical

Covalent-organic framework based Z-scheme heterostructured noble-metal-free photocatalysts for visible-light-driven hydrogen evolution

Yang-Peng Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Chemistry, Multidisciplinary

Recent development of covalent organic frameworks (COFs): synthesis and catalytic (organic-electro-photo) applications

Rakesh Kumar Sharma et al.

MATERIALS HORIZONS (2020)

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Review Chemistry, Multidisciplinary

From Solar Energy to Fuels: Recent Advances in Light-Driven C1 Chemistry

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Agriculture, Multidisciplinary

Isolation and Characterization of the Pymetrozine-Degrading Strain Pseudomonas sp. BYT-1

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JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2019)

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Review Chemistry, Multidisciplinary

Critical Aspects and Recent Advances in Structural Engineering of Photocatalysts for Sunlight-Driven Photocatalytic Reduction of CO2 into Fuels

Nhu-Nang Vu et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Engineering, Environmental

Ball milling synthesis of covalent organic framework as a highly active photocatalyst for degradation of organic contaminants

Hongzhou Lv et al.

JOURNAL OF HAZARDOUS MATERIALS (2019)

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Article Chemistry, Multidisciplinary

A Covalent Organic Framework Bearing Single Ni Sites as a Synergistic Photocatalyst for Selective Photoreduction of CO2 to CO

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Review Nanoscience & Nanotechnology

Photocatalytic Applications of Heterostructure Graphitic Carbon Nitride: Pollutant Degradation, Hydrogen Gas Production (water splitting), and CO2 Reduction

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NANOSCALE RESEARCH LETTERS (2019)

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Article Chemistry, Multidisciplinary

Semiconducting 2D Triazine-Cored Covalent Organic Frameworks with Unsubstituted Olefin Linkages

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Review Energy & Fuels

Current understanding and challenges of solar-driven hydrogen generation using polymeric photocatalysts

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NATURE ENERGY (2019)

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Review Chemistry, Physical

Adsorptive removal and photocatalytic degradation of organic pollutants using metal oxides and their composites: A comprehensive review

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ADVANCES IN COLLOID AND INTERFACE SCIENCE (2019)

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Article Chemistry, Physical

Construction of covalently integrated core-shell TiO2 nanobelts@COF hybrids for highly selective oxidation of alcohols under visible light

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APPLIED SURFACE SCIENCE (2019)

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Article Chemistry, Physical

Metal-free catalysts of graphitic carbon nitride–covalent organic frameworks for efficient pollutant destruction in water

Yunjin Yao et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

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Article Chemistry, Multidisciplinary

In Situ Irradiated X-Ray Photoelectron Spectroscopy Investigation on a Direct Z-Scheme TiO2/CdS Composite Film Photocatalyst

Jingxiang Low et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

A general strategy via chemically covalent combination for constructing heterostructured catalysts with enhanced photocatalytic hydroge evolution

Gang Zhou et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

A composite of single-crystalline Bi2WO6 and polycrystalline BiOCl with a high percentage of exposed (00l) facets for highly efficient photocatalytic degradation of organic pollutants

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CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Boosting photocatalytic H2 evolution on g-C3N4 by modifying covalent organic frameworks (COFs)

Maolan Luo et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Constructing a novel family of halogen-doped covalent triazine-based frameworks as efficient metal-free photocatalysts for hydrogen production

Zhi Cheng et al.

NANOSCALE ADVANCES (2019)

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Review Chemistry, Multidisciplinary

Recent developments in heterogeneous photocatalysts for solar-driven overall water splitting

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CHEMICAL SOCIETY REVIEWS (2019)

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Article Chemistry, Inorganic & Nuclear

A hybrid of g-C3N4 and porphyrin-based covalent organic frameworks via liquid-assisted grinding for enhanced visible-light-driven photoactivity

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DALTON TRANSACTIONS (2019)

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Review Chemistry, Multidisciplinary

Nanostructured materials for photocatalysis

Chunping Xu et al.

CHEMICAL SOCIETY REVIEWS (2019)

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Article Chemistry, Physical

Covalent organic framework-supported Fe-TiO2 nanoparticles as ambient-light-active photocatalysts

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JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Review Chemistry, Physical

g-C3N4-Based Heterostructured Photocatalysts

Junwei Fu et al.

ADVANCED ENERGY MATERIALS (2018)

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Review Chemistry, Physical

Three-dimensional graphene supported catalysts for organic dyes degradation

Kai He et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Review Chemistry, Physical

Semiconductor/boron nitride composites: Synthesis, properties, and photocatalysis applications

Chengyun Zhou et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Multidisciplinary

Highly photoluminescent two-dimensional imine-based covalent organic frameworks for chemical sensing

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CHEMICAL COMMUNICATIONS (2018)

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Article Chemistry, Multidisciplinary

Embedding Carbon Nitride into a Covalent Organic Framework with Enhanced Photocatalysis Performance

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CHEMISTRY-AN ASIAN JOURNAL (2018)

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Article Chemistry, Multidisciplinary

MoS2 Quantum Dots-Modified Covalent Triazine-Based Frameworks for Enhanced Photocatalytic Hydrogen Evolution

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CHEMSUSCHEM (2018)

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Review Chemistry, Multidisciplinary

CdS-Based photocatalysts

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ENERGY & ENVIRONMENTAL SCIENCE (2018)

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Review Green & Sustainable Science & Technology

A review of ZnO nanoparticles as solar photocatalysts: Synthesis, mechanisms and applications

Chin Boon Ong et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2018)

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Article Chemistry, Physical

Visible-Light-Driven Photoreduction of CO2 to CH4 over N,O,P-Containing Covalent Organic Polymer Submicrospheres

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ACS Catalysis (2018)

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Article Chemistry, Physical

Rhenium-modified porous covalent triazine framework for highly efficient photocatalytic carbon dioxide reduction in a solid-gas system

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CATALYSIS SCIENCE & TECHNOLOGY (2018)

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Review Chemistry, Physical

Cadmium sulfide-based nanomaterials for photocatalytic hydrogen production

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JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Article Chemistry, Physical

H2 Evolution with Covalent Organic Framework Photocatalysts

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ACS ENERGY LETTERS (2018)

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Article Chemistry, Multidisciplinary

Covalent Organic Frameworks Linked by Amine Bonding for Concerted Electrochemical Reduction of CO2

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CHEM (2018)

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Review Chemistry, Multidisciplinary

Core-shell structured titanium dioxide nanomaterials for solar energy utilization

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CHEMICAL SOCIETY REVIEWS (2018)

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Article Chemistry, Multidisciplinary

Size-controlled synthesis of CdS nanoparticles confined on covalent triazine-based frameworks for durable photocatalytic hydrogen evolution under visible light

Dengke Wang et al.

NANOSCALE (2018)

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Review Chemistry, Multidisciplinary

Two-dimensional polymeric carbon nitride: structural engineering for optimizing photocatalysis

Wenjun Jiang et al.

SCIENCE CHINA-CHEMISTRY (2018)

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Article Chemistry, Physical

Photocatalysis: Tailor-Made Photoconductive Pyrene-Based Covalent Organic Frameworks for Visible-Light Driven Hydrogen Generation (Adv. Energy Mater. 24/2018)

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Advanced Energy Materials (2018)

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Article Chemistry, Multidisciplinary

2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO2 Reduction

Sizhuo Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Multidisciplinary Sciences

Understanding structure-activity relationships in linear polymer photocatalysts for hydrogen evolution

Michael Sachs et al.

NATURE COMMUNICATIONS (2018)

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Article Chemistry, Multidisciplinary

Covalent Triazine Framework Modified BiOBr Nanoflake with Enhanced Photocatalytic Activity for Antibiotic Removal

Shuai-Ru Zhu et al.

CRYSTAL GROWTH & DESIGN (2018)

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Article Chemistry, Multidisciplinary

Encapsulating [Mo3S13](2-) clusters in cationic covalent organic frameworks: enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

Yuan-Jie Cheng et al.

CHEMICAL COMMUNICATIONS (2018)

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Article Chemistry, Multidisciplinary

Hybridization of MOFs and COFs: A New Strategy for Construction of MOF@COF Core-Shell Hybrid Materials

Yongwu Peng et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Physical

A Particulate Photocatalyst Water-Splitting Panel for Large-Scale Solar Hydrogen Generation

Yosuke Goto et al.

JOULE (2018)

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Article Chemistry, Inorganic & Nuclear

The Controllable Synthesis of Octadecahedral BiVO4 with Exposed {111} Facets

Yifeng Zhang et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

Salicylideneanilines-Based Covalent Organic Frameworks as Chemoselective Molecular Sieves

Guo-Hong Ning et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Multidisciplinary

Salen-Based Covalent Organic Framework

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Multidisciplinary

Single-Site Photocatalytic H2 Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts

Tanmay Banerjee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Review Chemistry, Multidisciplinary

Graphene/graphitic carbon nitride hybrids for catalysis

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MATERIALS HORIZONS (2017)

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Review Chemistry, Applied

A review on TiO2-based Z-scheme photocatalysts

Kezhen Qi et al.

CHINESE JOURNAL OF CATALYSIS (2017)

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Article Chemistry, Multidisciplinary

Conjugated Microporous Polymer Nanosheets for Overall Water Splitting Using Visible Light

Lei Wang et al.

ADVANCED MATERIALS (2017)

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Article Chemistry, Multidisciplinary

Isoreticular covalent organic frameworks for hydrocarbon uptake and separation: the important role of monomer planarity

Jinqiao Dong et al.

CRYSTENGCOMM (2017)

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Article Chemistry, Multidisciplinary

A quaternary-ammonium-functionalized covalent organic framework for anion conduction

Hongxia Guo et al.

CRYSTENGCOMM (2017)

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Article Engineering, Chemical

Covalent organic polymer modified TiO2 nanosheets as highly efficient photocatalysts for hydrogen generation

Qingqing Yang et al.

CHEMICAL ENGINEERING SCIENCE (2017)

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Article Chemistry, Multidisciplinary

Visible-Light-Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts

Reiner Sebastian Sprick et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Review Chemistry, Multidisciplinary

Multinary I-III-VI2 and I2-II-IV-VI4 Semiconductor Nanostructures for Photocatalytic Applications

Michelle D. Regulacio et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

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Article Chemistry, Multidisciplinary

Crystalline fibres of a covalent organic framework through bottom-up microfluidic synthesis

David Rodriguez-San-Miguel et al.

CHEMICAL COMMUNICATIONS (2016)

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Article Chemistry, Multidisciplinary

Light-induced spatial separation of charges toward different crystal facets of square-like WO3

Huihua Gong et al.

CHEMICAL COMMUNICATIONS (2016)

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Article Multidisciplinary Sciences

Covalently bonded single-molecule junctions with stable and reversible photoswitched conductivity

Chuancheng Jia et al.

SCIENCE (2016)

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Review Engineering, Environmental

Recent developments of zinc oxide based photocatalyst in water treatment technology: A review

Kian Mun Lee et al.

WATER RESEARCH (2016)

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Article Chemistry, Multidisciplinary

Visible light-driven water oxidation using a covalently-linked molecular catalyst-sensitizer dyad assembled on a TiO2 electrode

Masanori Yamamoto et al.

CHEMICAL SCIENCE (2016)

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Article Energy & Fuels

Path dependence in energy systems and economic development

Roger Fouquet

NATURE ENERGY (2016)

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Review Chemistry, Multidisciplinary

Polymeric Photocatalysts Based on Graphitic Carbon Nitride

Shaowen Cao et al.

ADVANCED MATERIALS (2015)

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Review Plant Sciences

The Structure of Photosystem II and the Mechanism of Water Oxidation in Photosynthesis

Jian-Ren Shen

ANNUAL REVIEW OF PLANT BIOLOGY, VOL 66 (2015)

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Review Chemistry, Physical

Review of material design and reactor engineering on TiO2 photocatalysis for CO2 reduction

Oluwafunmilola Ola et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS (2015)

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Article Chemistry, Multidisciplinary

Tunable Organic Photocatalysts for Visible-Light-Driven Hydrogen Evolution

Reiner Sebastian Sprick et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Article Multidisciplinary Sciences

Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway

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SCIENCE (2015)

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Article Chemistry, Multidisciplinary

Chemical sensing in two dimensional porous covalent organic nanosheets

Gobinda Das et al.

CHEMICAL SCIENCE (2015)

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Review Chemistry, Physical

CdS/Graphene Nanocomposite Photocatalysts

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ADVANCED ENERGY MATERIALS (2015)

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Article Chemistry, Applied

Fabrication of a β-Bi2O3/BiOI heterojunction and its efficient photocatalysis for organic dye removal

Suiqi Han et al.

CHINESE JOURNAL OF CATALYSIS (2015)

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Article Chemistry, Multidisciplinary

Highly stable covalent organic framework-Au nanoparticles hybrids for enhanced activity for nitrophenol reduction

Pradip Pachfule et al.

CHEMICAL COMMUNICATIONS (2014)

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Review Chemistry, Multidisciplinary

Understanding TiO2 Photocatalysis: Mechanisms and Materials

Jenny Schneider et al.

CHEMICAL REVIEWS (2014)

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Article Chemistry, Multidisciplinary

A Covalent Organic Framework-Cadmium Sulfide Hybrid as a Prototype Photocatalyst for Visible-Light-Driven Hydrogen Production

Jayshri Thote et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

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Article Chemistry, Physical

g-C3N4-Based Photocatalysts for Hydrogen Generation

Shaowen Cao et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2014)

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Article Chemistry, Multidisciplinary

A hydrazone-based covalent organic framework for photocatalytic hydrogen production

Linus Stegbauer et al.

CHEMICAL SCIENCE (2014)

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Article Chemistry, Physical

Green, scalable and morphology controlled synthesis of nanofibrous covalent organic frameworks and their nanohybrids through a vapor-assisted solid-state approach

Yi Jiang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Review Chemistry, Multidisciplinary

Hybrid Artificial Photosynthetic Systems Comprising Semiconductors as Light Harvesters and Biomimetic Complexes as Molecular Cocatalysts

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ACCOUNTS OF CHEMICAL RESEARCH (2013)

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Article Nanoscience & Nanotechnology

Solvothermal Synthesis of Microporous, Crystalline Covalent Organic Framework Nanofibers and Their Colorimetric Nanohybrid Structures

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ACS APPLIED MATERIALS & INTERFACES (2013)

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Editorial Material Multidisciplinary Sciences

Chemical approaches to artificial photosynthesis

Javier J. Concepcion et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2012)

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Article Chemistry, Multidisciplinary

Photocatalytic hydrogen evolution through fully conjugated poly(azomethine) networks

Matthias Georg Schwab et al.

CHEMICAL COMMUNICATIONS (2010)

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Article Chemistry, Physical

Photocatalytic Water Splitting: Recent Progress and Future Challenges

Kazuhiko Maeda et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2010)

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Review Chemistry, Multidisciplinary

Photosynthetic energy conversion: natural and artificial

James Barber

CHEMICAL SOCIETY REVIEWS (2009)

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Article Chemistry, Multidisciplinary

ATR-SEIRAS Investigation of the Fermi Level of Pt Cocatalyst on a GaN Photocatalyst for Hydrogen Evolution under Irradiation

Masaaki Yoshida et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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Article Chemistry, Multidisciplinary

Polymer Semiconductors for Artificial Photosynthesis: Hydrogen Evolution by Mesoporous Graphitic Carbon Nitride with Visible Light

Xinchen Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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Article Chemistry, Physical

A metal-free polymeric photocatalyst for hydrogen production from water under visible light

Xinchen Wang et al.

NATURE MATERIALS (2009)

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Article Chemistry, Physical

Direct splitting of H2S into H2 and S on CdS-based photocatalyst under visible light irradiation

Guijun Ma et al.

JOURNAL OF CATALYSIS (2008)

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Article Chemistry, Multidisciplinary

Enhancement of photocatalytic H2 evolution on CdS by loading MOS2 as cocatalyst under visible light irradiation

Xu Zong et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

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Article Chemistry, Multidisciplinary

Mass production and high photocatalytic activity of ZnS nanoporous nanoparticles

JS Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

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Article Multidisciplinary Sciences

Sustainable hydrogen production

JA Turner

SCIENCE (2004)

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