期刊
CHEMSUSCHEM
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202300549
关键词
reaction mechanisms; lignin; NMR spectroscopy; integrated biorefinery; lignin-carbohydrate complexes
Our AqSO process has potential as a parameter-controlled biorefinery, allowing for tailored lignin products. We characterized the structure of AqSO lignins using NMR and investigated the effects of process severity and liquid-to-solid ratio. Lower severity and L/S=1 led to less degraded lignin with higher β-O-4 content, while harsher conditions yielded more condensed lignins. We identified and quantified new lignin moieties and hypothesized the formation of lignin carbohydrate complexes at low severity and L/S.
Our recently reported AquaSolv Omni (AqSO) process shows great potential as a parameter-controlled type of biorefinery, which allows tuning of structure and properties of the products towards their optimal use in high-value applications. Herein, a comprehensive NMR (quantitative C-13, P-31, and 2D heteronuclear single-quantum coherence) structural characterization of AqSO lignins is reported. The effect of the process severity (P-factor) and liquid-to-solid ratio (L/S) on the structure of the extracted lignins has been investigated and discussed. Low severity (P-factor in the range 400-600) and L/S=1 led to the isolation of less degraded lignin with a higher & beta;-O-4 content up to 34/100 Ar. Harsher processing conditions (P-factor=1000-2500) yielded more condensed lignins with a high degree of condensation up to 66 at P-factor=2000. New types of lignin moieties, such as alkyl-aryl and alkyl-alkyl chemical bonds together with novel furan oxygenated structures have been identified and quantified for the first time. In addition, the formation of lignin carbohydrate complexes bonds has been hypothesized at low severity and L/S. Based on the obtained data we were able to formulate a possible outlook of the occurring reactions during the hydrothermal treatment. Overall, such detailed structural information bridges the gap from process engineering to sustainable product development.
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