Impact of Structural Flexibility of Amine Moieties as Bridges for Redox-Active Sites on Secondary Battery Performance

Article Multidisciplinary Sciences

Phase-engineered cathode for super-stable potassium storage

Lichen Wu et al.

Summary: The authors demonstrate that phase-engineered amorphous vanadium oxide can alleviate large volume variation and improve electrochemical behavior in potassium-ion batteries, leading to superior K storage ability and improved performance.

NATURE COMMUNICATIONS (2023)

添加到收藏夹

Review Chemistry, Multidisciplinary

Emerging Lithiated Organic Cathode Materials for Lithium-Ion Full Batteries

Yong Lu et al.

Summary: Organic electrode materials have great potential in lithium batteries, especially lithiated organic cathode materials that can match with Li-free anodes, showing promising practical full-battery applications. Future research should focus on new redox chemistries and the construction of full batteries under practical conditions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Bond modulation of MoSe2+x driving combined intercalation and conversion reactions for high-performance K cathodes

Ting Lei et al.

Summary: The introduction of Se atoms between MoSe2 layers through bond modulation produces a high-performance cathode for potassium-ion batteries. This cathode, MoSe2+x-rGO, exhibits an ultrahigh capacity, long cycle life, and extraordinary rate performance. The study on bond modulation driving combined intercalation and conversion reactions provides new insights into the design of high-performance K cathodes.

CHEMICAL SCIENCE (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

In situ formed uniform and elastic SEI for high-performance batteries

Mingyuan Gu et al.

Summary: The solid electrolyte interphase (SEI) serves a crucial role in battery performance, and a uniform and elastic SEI was constructed using in situ electro-polymerization (ISEP-SEI) of ionic liquid electrolytes. ISEP-SEI exhibited excellent uniformity, effectively passivating the electrode surface, and maintained structural integrity during cycling due to its superior elasticity. This technology enabled stable cycling of potassium metal symmetric batteries for 5000 hours and improved the performance and stability of other battery components.

ENERGY & ENVIRONMENTAL SCIENCE (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Soluble Organic Cathodes Enable Long Cycle Life, High Rate, and Wide-Temperature Lithium-Ion Batteries

Mengjie Li et al.

Summary: The use of gel polymer electrolytes (GPE) and Nafion-coated separators eliminates the shuttle reaction of organic electrodes, maintaining their electrochemical performance and improving cycle life and rate capability of batteries. Additionally, the shielding capability of GPE can be customized for organic electrodes with different molecular sizes, providing a universal solution to the shuttle effect.

ADVANCED MATERIALS (2022)

添加到收藏夹

Article Chemistry, Physical

Hierarchical yolk-shell structured Li-rich cathode boosting cycling and voltage stabled LIBs

Yanchen Liu et al.

Summary: The hierarchical yolk-shell structured Li1.2Mn0.54Ni0.13Co0.13O2 cathode shows an initial coulombic efficiency of 85.8% and outstanding capacity retention rates of 89.1% after cycling at 2.0 C for 200 cycles. After cycling at 10.0 C for 500 cycles, the capacity retention rate is 93.8%, and for 1,000 cycles, it is 85.2%.

NANO RESEARCH (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Are Redox-Active Organic Small Molecules Applicable for High-Voltage (>4 V) Lithium-Ion Battery Cathodes?

Yuto Katsuyama et al.

Summary: The study investigates the potential use of croconic acid (CA) as a cathode material for high-energy-density lithium-ion batteries. It demonstrates that CA exhibits high voltage and theoretical energy density, making it a promising candidate for future organic batteries.

ADVANCED SCIENCE (2022)

添加到收藏夹

Article Chemistry, Physical

Inorganic cathode materials for potassium ion batteries

Yating Meng et al.

Summary: Potassium ion batteries have gained attention in large-scale electrochemical energy storage due to their abundant resources, low cost, performance safety, and environmental non-toxicity. However, challenges such as the large atomic weight and radius of potassium ion and short cycle life limit their practical use. Inorganic cathode materials play a crucial role in the development of high-performance potassium ion batteries, and this review focuses on their current development and the relationship between material composition, structure, and electrochemical performance.

MATERIALS TODAY ENERGY (2022)

添加到收藏夹

Article Chemistry, Physical

Challenges and prospects of nickel-rich layered oxide cathode material

Sidra Jamil et al.

Summary: This review article provides a comprehensive overview of the advantages and challenges of Ni-rich layered oxide cathode materials in terms of high energy density and high operating voltage, and summarizes the latest improvement methods. In addition, it explores the compatibility and interface challenges of Ni-rich cathodes with solid-state electrolytes, as well as the practical application prospects in the field of electromobility.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

添加到收藏夹

Article Chemistry, Physical

A furan-based organic cathode material for high-performance sodium ion batteries

Jingwei Zhang et al.

Summary: Organic materials have the potential to be electrode materials for sodium ion batteries due to their tunable molecular structures and low costs. However, their dissolution in electrolyte leads to poor performance. In this study, a furan-based QFQ compound is developed, which is almost insoluble in organic electrolytes and exhibits stable electrochemical performance. This is the first report of furan unit working as additional anion storage site, which could be useful for future design of efficient organic cathode materials.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

添加到收藏夹

Article Chemistry, Physical

Toward coupling of electrochemical redox properties with electrostatic potential surfaces tailored by dopant architectures for pyrenetetrone

Chae Young Go et al.

Summary: This study systematically explored the electrochemical characteristics of pyrenetetrone derivatives using computational methods, revealing the key factors influencing their redox properties. It was found that dopant electronegativity, electrostatic potential, and interatomic electronic flow are crucial in determining the redox behavior of these compounds. During the discharging process, dopant electronegativity becomes dominant, with boron-doped compounds showing potential for high-performance cathodes.

ENERGY STORAGE MATERIALS (2021)

添加到收藏夹

Article Chemistry, Physical

Unraveling the role of ion-solvent chemistry in stabilizing small-molecule organic cathode for potassium-ion batteries

Dandan Yu et al.

Summary: This study investigates the effects of salt concentrations and solvents on the performance of potassium-organic batteries using methylene blue (MB) as the cathode material. High-concentration potassium bis(fluorosulfonyl)amide-based ether electrolyte is found to be versatile in achieving long lifespan, while enhancing interactions between K'-ether and anion-participated ion-ether complexes help mitigate shuttle effects and inhibit K dendrite growth. As a result, MB cathode shows high capacity and long-term cycling stability, demonstrating the feasibility of MB as a cathode material in potassium-ion batteries.

ENERGY STORAGE MATERIALS (2021)

添加到收藏夹

Article Chemistry, Physical

Particle Size and Particle-Size Distribution Effects on Li+ Extraction/Insertion Kinetics for Li-Rich Mn-Based Oxides

Zhitang Fang et al.

Summary: A series of Li-rich Mn-based layered materials with different particle sizes and distributions were successfully synthesized, showing enhanced electrochemical performance due to the unique particle size and PSD, especially at high current rates. The material displayed excellent lithium storage properties at high temperatures and full cells using this material as the cathode showed improved electrochemical performance.

ACS APPLIED ENERGY MATERIALS (2021)

添加到收藏夹

Article Chemistry, Physical

Effect of Li Excess on Electrochemical Performance of Ni-Rich LiNi0.9Co0.05Mn0.05O2 Cathode Materials for Li-Ion Batteries

Eyob Belew Abebe et al.

Summary: In this study, nickel-rich layered oxide cathode materials were modified by adding a specific amount of lithium excess, resulting in improved electrochemical performance such as enhanced discharge capacity retention and rate capability. The optimal lithium excess in the NCM90 cathode materials showed potential for use in next-generation lithium-ion batteries.

ACS APPLIED ENERGY MATERIALS (2021)

添加到收藏夹

Editorial Material Chemistry, Physical

Towards practical organic batteries

Jing Xie et al.

Summary: Conjugated sulfonamides, as cathodes, have high redox potentials and exceptional atmospheric stability, providing a sustainable alternative to traditional inorganic materials used in commercial lithium-ion batteries.

NATURE MATERIALS (2021)

添加到收藏夹

Article Nanoscience & Nanotechnology

Tailored Design of Electrochemically Degradable Anthraquinone Functionality toward Organic Cathodes

Chae Young Go et al.

Summary: In the study, it was found that the Li-triggered structural collapse observed in the early stage of discharging of anthraquinone with halogenated nitrogen-based functionalities can be attributed to the strong Lewis acid-base interaction of N-Li-X. Furthermore, replacing N and/or X with electron-deficient atoms such as B and/or H can alleviate the repulsive force on the N-X bond, improving the theoretical performance and showing that key parameters cooperatively contribute to the electrochemical redox potential.

ACS APPLIED MATERIALS & INTERFACES (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Unraveling Three-Stage Discharging Behaviors of Bio-Inspired Organic Cathode Materials

Ku Hyun Jung et al.

Summary: This study systematically designs a large number of DNA/RNA-inspired derivatives and explores their electrochemical redox properties to understand the structure-potential-performance relationship. Four key conclusions are drawn, including the importance of charging energy for determining redox potentials, the cooperative contributions of charging and reorganization energies to discharging potentials, the cathodic inactivity of compounds at the end of discharging, and the critical dependence of charge/energy-storage capability on Li binding mechanism. These findings will contribute to the development of bio-inspired cathode materials for high-performance Li-ion batteries.

ADVANCED FUNCTIONAL MATERIALS (2021)

添加到收藏夹

Review Electrochemistry

Recent Insights into Rate Performance Limitations of Li-ion Batteries

Christian Heubner et al.

Summary: Improving the fast charging capabilities and driving range of electric vehicles is a major goal in Li-ion battery research. Fundamental understanding of performance limiting factors at the electrode level is crucial for optimizing materials, electrode design, and cell architectures. Analytical and semi-empirical models are emphasized for understanding specific performance limiting factors of electrodes and discussing promising improvement strategies for liquid electrolyte-based Li-ion batteries.

BATTERIES & SUPERCAPS (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Electrode Degradation in Lithium-Ion Batteries

Joshua P. Pender et al.

ACS NANO (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Molecular Design Strategy for High-Redox-Potential and Poorly Soluble n-Type Phenazine Derivatives as Cathode Materials for Lithium Batteries

Licheng Miao et al.

CHEMSUSCHEM (2020)

添加到收藏夹

Article Chemistry, Physical

Integrating Multiredox Centers into One Framework for High-Performance Organic Li-Ion Battery Cathodes

Chunyu Cui et al.

ACS ENERGY LETTERS (2020)

添加到收藏夹

Review Multidisciplinary Sciences

A reflection on lithium-ion battery cathode chemistry

Arumugam Manthiram

NATURE COMMUNICATIONS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

New Redox Strategies in Organic Synthesis by Means of Electrochemistry and Photochemistry

Jinjian Liu et al.

ACS CENTRAL SCIENCE (2020)

添加到收藏夹

Article Chemistry, Physical

Crucial role of cyanides for high-potential electrochemical reduction reaction

Gyeong Seok Jeong et al.

ENERGY STORAGE MATERIALS (2020)

添加到收藏夹

Article Nanoscience & Nanotechnology

Synthesis and Mechanism of High Structural Stability of Nickel-Rich Cathode Materials by Adjusting Li-Excess

Zhenlu Yu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

添加到收藏夹

Article Chemistry, Physical

Conjugacy of organic cathode materials for high-potential lithium-ion batteries: Carbonitriles versus quinones

Ku Hyun Jung et al.

ENERGY STORAGE MATERIALS (2020)

添加到收藏夹

Review Materials Science, Multidisciplinary

On battery materials and methods

R. Borah et al.

MATERIALS TODAY ADVANCES (2020)

添加到收藏夹

Review Geosciences, Multidisciplinary

Rare earth elements: A review of applications, occurrence, exploration, analysis, recycling, and environmental impact

V. Balaram

GEOSCIENCE FRONTIERS (2019)

添加到收藏夹

Editorial Material Chemistry, Physical

What Limits the Capacity of Layered Oxide Cathodes in Lithium Batteries?

Hui Zhou et al.

ACS ENERGY LETTERS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Improving the Understanding of the Redox Properties of Fluoranil Derivatives for Cathodes in Sodium-Ion Batteries

Ku Hyun Jung et al.

CHEMSUSCHEM (2019)

添加到收藏夹

Review Chemistry, Physical

Lithium-ion batteries: outlook on present, future, and hybridized technologies

Taehoon Kim et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

添加到收藏夹

Article Chemistry, Physical

Unveiled correlations between electron affinity and solvation in redox potential of quinone-based sodium-ion batteries

Ki Chul Kim et al.

ENERGY STORAGE MATERIALS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Pushing the limit of layered transition metal oxide cathodes for high-energy density rechargeable Li ion batteries

U. -H. Kim et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

添加到收藏夹

Article Multidisciplinary Sciences

High energy-density and reversibility of iron fluoride cathode enabled via an intercalation-extrusion reaction

Xiulin Fan et al.

NATURE COMMUNICATIONS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Performance optimization of freestanding MWCNT-LiFePO4 sheets as cathodes for improved specific capacity of lithium-ion batteries

Rahmat Agung Susantyoko et al.

RSC ADVANCES (2018)

添加到收藏夹

Article Chemistry, Physical

Boron-doped coronenes with high redox potential for organic positive electrodes in lithium-ion batteries: a first-principles density functional theory modeling study

Yuntong Zhu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

添加到收藏夹

Article Chemistry, Physical

Boosting the performance of organic cathodes through structure tuning

Jian Xie et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

添加到收藏夹

Article Chemistry, Physical

Impact of Cathode Material Particle Size on the Capacity of Bulk-Type All-Solid-State Batteries

Florian Strauss et al.

ACS ENERGY LETTERS (2018)

添加到收藏夹

Article Multidisciplinary Sciences

Electrochemical surface passivation of LiCoO2 particles at ultrahigh voltage and its applications in lithium-based batteries

Jiawei Qian et al.

NATURE COMMUNICATIONS (2018)

添加到收藏夹

Review Engineering, Chemical

Design Strategies for Promising Organic Positive Electrodes in Lithium-Ion Batteries: Quinones and Carbon Materials

Ki Chul Kim

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Redox-Active Macrocycles for Organic Rechargeable Batteries

Dong Jun Kim et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Review Green & Sustainable Science & Technology

Emerging renewable and sustainable energy technologies: State of the art

Akhtar Hussain et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2017)

添加到收藏夹

Review Green & Sustainable Science & Technology

Recent approaches of unit commitment in the presence of intermittent renewable energy resources: A review

Saleh Y. Abujarad et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2017)

添加到收藏夹

Article Chemistry, Physical

Quinone Electrode Materials for Rechargeable Lithium/Sodium Ion Batteries

Yiwen Wu et al.

ADVANCED ENERGY MATERIALS (2017)

添加到收藏夹

Article Chemistry, Physical

Designing strategies to tune reduction potential of organic molecules for sustainable high capacity battery application

Rafael B. Araujo et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Sulfur Heterocyclic Quinone Cathode and a Multifunctional Binder for a High-Performance Rechargeable Lithium-Ion Battery

Ting Ma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

First-Principles Density Functional Theory Modeling of Li Binding: Thermodynamics and Redox Properties of Quinone Derivatives for Lithium-Ion Batteries

Ki Chul Kim et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Materials Science, Ceramics

Enhanced lithium ionic conductivity and study of the relaxation and giant dielectric properties of spark plasma sintered Li5La3Nb2O12 nanomaterials

Mohamad M. Ahmad

CERAMICS INTERNATIONAL (2015)

添加到收藏夹

Article Chemistry, Physical

High-Density Lithium-Ion Energy Storage Utilizing the Surface Redox Reactions in Folded Graphene Films

Tianyuan Liu et al.

CHEMISTRY OF MATERIALS (2015)

添加到收藏夹

Article Materials Science, Multidisciplinary

Li-ion battery materials: present and future

Naoki Nitta et al.

MATERIALS TODAY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Poly(benzoquinonyl sulfide) as a High-Energy Organic Cathode for Rechargeable Li and Na Batteries

Zhiping Song et al.

ADVANCED SCIENCE (2015)

添加到收藏夹

Article Chemistry, Physical

Investigation of the Redox Chemistry of Anthraquinone Derivatives Using Density Functional Theory

Jonathan E. Bachman et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2014)

添加到收藏夹

Article Chemistry, Physical

Jaguar: A high-performance quantum chemistry software program with strengths in life and materials sciences

Art D. Bochevarov et al.

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY (2013)

添加到收藏夹

Article Green & Sustainable Science & Technology

Grid vs. storage in a 100% renewable Europe

Florian Steinke et al.

RENEWABLE ENERGY (2013)

添加到收藏夹

Article Multidisciplinary Sciences

Graphene-modified LiFePO4 cathode for lithium ion battery beyond theoretical capacity

Lung-Hao Hu et al.

NATURE COMMUNICATIONS (2013)

添加到收藏夹

Article Chemistry, Physical

Polyaniline/Vanadium Pentoxide Layer-by-Layer Electrodes for Energy Storage

Lin Shao et al.

CHEMISTRY OF MATERIALS (2012)

添加到收藏夹

Article Chemistry, Physical

Lithium-Polymer battery based on polybithiophene as cathode material

J. Chen et al.

JOURNAL OF POWER SOURCES (2006)

添加到收藏夹

Article Chemistry, Physical

Computation of equilibrium oxidation and reduction potentials for reversible and dissociative electron-transfer reactions in solution

P Winget et al.

THEORETICAL CHEMISTRY ACCOUNTS (2004)

添加到收藏夹

Article Biochemistry & Molecular Biology

Redox potential of quinones in both electron transfer branches of photosystem I

H Ishikita et al.

JOURNAL OF BIOLOGICAL CHEMISTRY (2003)

添加到收藏夹

Article Electrochemistry

Preparation and electrochemical characterization of a polymer Li1.03Mn1.97O4/pEDOT composite electrode

C Arbizzani et al.

ELECTROCHEMISTRY COMMUNICATIONS (2002)

添加到收藏夹

Article Electrochemistry

Optimized LiFePO4 for lithium battery cathodes

A Yamada et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2001)

添加到收藏夹

Article Chemistry, Physical

Computational electrochemistry: aqueous one-electron oxidation potentials for substituted anilines

P Winget et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2000)

添加到收藏夹

Impact of Structural Flexibility of Amine Moieties as Bridges for Redox-Active Sites on Secondary Battery Performance

相关参考文献

导出引文

分享论文