☆ 4.7 Review

Metal organic frameworks as promising sensing tools for electrochemical detection of persistent heavy metal ions from water matrices: A concise review

CHEMOSPHERE (2023)

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Chemiluminescent Two-Dimensional Metal-Organic Framework with Multiple Metal Catalytic Centers and Its Peroxidase-like Activity for Sensing of Small Molecules

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Summary: In this study, a chemiluminescent 2D metal-organic framework (MOF) with dual functionality of a chemiluminescence reagent and noble metal nanoparticles was developed. The material exhibited strong and stable chemiluminescence properties and outstanding peroxidase-mimicking activity, making it suitable for the design of highly sensitive biosensors.

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Mixed-ligand-devised anionic MOF with divergent open Co(II)-nodes as chemo-resistant, bi-functional material for electrochemical water oxidation and mild-condition tandem CO2 fixation

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Summary: The MOF material CSMCRI-10 exhibits excellent bi-functional performance for efficient water oxidation and solvent-free CO2 conversion. With low overpotential and improved oxygen evolution reaction rate, the material maintains stability in consecutive cycles, achieving oxidative carboxylation of CO2 and styrene.

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Article Chemistry, Inorganic & Nuclear

A viologen-derived host-guest MOF material: Photochromism, photoswitchable luminescence, and inkless and erasable printing

Jian-Jun Liu et al.

Summary: The study focuses on encapsulating a simple methyl viologen guest into an anionic MOF framework to demonstrate reversible photochromic and photoswitchable luminescent properties under UV-Vis light irradiation. By controlling the UV-Vis light irradiation with a stencil, the host-guest MOF material can be deposited on filter paper and used as inkless print material.

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Article Multidisciplinary Sciences

Recent advances in chemically and biologically synthesized nanostructures for colorimetric detection of heavy metal

Tahir Rasheed et al.

Summary: This article reviews the recent advances in colorimetric detection based on chemically and biologically synthesized nanomaterials. These methods offer features such as visual detection, high selectivity and sensitivity, and easy synthesis, making them promising for the detection of target analytes such as heavy metal pollutants.

JOURNAL OF KING SAUD UNIVERSITY SCIENCE (2022)

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Article Engineering, Environmental

Controllable one step electrochemical synthesis of PANI encapsulating 3d-4f bimetal MOFs heterostructures as electrode materials for high-performance supercapacitors

Ping-Ping Sun et al.

Summary: Two new 3D 3d-4f bimetal organic frameworks (ZnCe-MOF and CuCe-MOF) were synthesized through hydrothermal method. These MOFs have monoclinic symmetry in the P2(1)/n space group and were coated with PANI using the electrodeposition method to improve electrical conductivity. The heterostructure of MOF coated with PANI shows promising applications in portable energy storage devices, with specific capacitance reaching up to 724.4F g(-1) and 713.2F g(-1) at 1 A g(-1).

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Biophysics

Metal-organic frameworks based hybrid nanocomposites as state-of-the-art analytical tools for electrochemical sensing applications

Tahir Rasheed et al.

Summary: This paper systematically summarizes recent breakthroughs in MOFs and their derivatives in enhanced electrochemical sensing applications. The overview part provides insights into the future prospects and directions of MOFs and their derivatives, aiming to overcome present limitations.

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MOF-derived magnetic-dielectric balanced Co@ZnO@N-doped carbon composite materials for strong microwave absorption

Ke Yang et al.

Summary: Using metal organic frameworks as precursors, this study successfully synthesized high performance absorbent materials with special morphology and balanced magnetic dielectric properties.

CARBON (2022)

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Article Environmental Sciences

Identification of heavy metal ions from aqueous environment through gold, Silver and Copper Nanoparticles: An excellent colorimetric approach

Ali Hyder et al.

Summary: Heavy metal pollution poses a serious threat to human health and the environment, prompting researchers to develop specific analytical methods for heavy metal ion determination and utilize metal nanoparticles for rapid detection. Research has focused on utilizing materials such as gold, silver, and copper nanoparticles for colorimetric sensing of toxic metal ions, with a focus on stability and functionalization of the nanoparticles. This review covers comprehensive work on colorimetric detection of heavy metals using metal nanoparticles from 2014 onwards.

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Review Environmental Sciences

Metal organic frameworks for electrochemical sensor applications: A review

Navdeep Kajal et al.

Summary: Metal-organic frameworks (MOFs) are porous coordination polymers synthesized by metal-based nodes and organic linkers, known for their versatile properties. This review discusses the use of MOFs as electrochemical sensors and how they enhance the selectivity and sensitivity of the sensors, particularly in detecting heavy metal ions and organic pollutants from groundwater and water bodies. Additionally, the review explores the detection of various compounds like antibiotics, phenolic compounds, and pesticides using MOFs, as well as the potential of metal nano-particles and metal-oxide based composites for sensing applications. It also highlights the challenges and future opportunities in the field of MOF-based electrochemical sensors.

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Article Energy & Fuels

Diffusion control and surface control mechanism in hierarchical nanostructured porous zinc-based MOF material for supercapattery

Syeda Ramsha Ali et al.

Summary: This paper reports the application of zinc-based metal-organic framework nanomaterials as a supercapattery device. The material was synthesized using the facile hydrothermal technique and characterized using various methods. The device shows excellent performance and cyclic stability, and stores energy through both diffusion-controlled and surface-controlled contributions.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2022)

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Article Chemistry, Physical

Fe-MOF Materials as Precursors for the Catalytic Dehydrogenationof Isobutane

Alberto Rodriguez-Gomez et al.

Summary: We investigated the use of iron-based metal-organic frameworks as precursors for isobutane dehydrogenation catalysts and characterized the materials to determine their properties and active phases. The stabilization of Fe2+ species is crucial for achieving stable and selective catalysts, and the addition of potassium and titanium can improve the catalytic performance.

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Review Green & Sustainable Science & Technology

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Summary: The development of new/novel methods in materials science has brought great potential for the synthesis of various nano-materials. This article focuses on the synthesis of metal oxide/sulfide-based nanocomposites and their applications in photocatalytic removal of organic dye molecules, energy storage, antimicrobial, and heavy metal ion-sensing. The article provides essential procedures for synthesis and highlights the importance of these nanocomposites in different applications.

MATERIALS TODAY SUSTAINABILITY (2022)

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Article Multidisciplinary Sciences

A europium metal-organic framework for dual Fe3+ ion and pH sensing

Linda Rozenberga et al.

Summary: The MOF originally reported as containing europium(III) and 2-hydroxyterephtalic acid was re-assessed and found to be composed of 2-methoxyterephthalate instead. The sensing properties towards Fe3+ ion concentrations and pH levels were altered, with a dynamic quenching mechanism for fluorescence turn-off response and a ligand protonation mechanism for the turn-on response discovered.

SCIENTIFIC REPORTS (2022)

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Article Chemistry, Physical

Metal-organic framework (MOF) composites as promising materials for energy storage applications

Yi Peng et al.

Summary: Metal-organic framework (MOF) composites are considered important energy storage materials due to their high porousness, multifunction, various structures, and controllable chemical compositions, but they still face challenges and difficulties in batteries and supercapacitors.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2022)

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Ayesha Rehman et al.

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Polyvinyl alcohol and aminated cellulose nanocrystal membranes with improved interfacial compatibility for environmental applications

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Shano M. Pirot et al.

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The Selective CO2 Adsorption and Photothermal Conversion Study of an Azo-Based Cobalt-MOF Material

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Hollow Carbon Nanofibers with Inside-outside Decoration of Bi-metallic MOF Derived Ni-Fe Phosphides as Electrode Materials for Asymmetric Supercapacitors

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Design and synthesis of phosphating bimetallic CeCo-MOF for substantially improved photocatalytic hydrogen evolution

Teng Li et al.

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Cellulose acetate based sustainable nanostructured membranes for environmental remediation

Ayesha Rehman et al.

Summary: Membrane-based gas separation has the potential to reduce environmentally hazardous CO2 gas. This study aimed to synthesize mixed matrix membranes (MMMs) with improved CO2 adsorption performance and stability. The effect of increasing filler concentration on CO2 adsorption was investigated. The results showed that increasing the filler concentration improved the adsorption performance, but beyond a certain concentration, aggregation occurred. The successful incorporation of MOF within the MMMs was confirmed through spectroscopy analysis.

CHEMOSPHERE (2022)

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Review Engineering, Environmental

MOF based engineered materials in water remediation: Recent trends

Richelle M. Rego et al.

Summary: With the increasing demand for freshwater, materials such as metal organic frameworks (MOFs) have gained attention for their ability to remove contaminants from water sources. However, the poor processability and fragility of MOFs limit their practical applications in water treatment, prompting efforts to improve their stability and processability for real-world use.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Review Materials Science, Multidisciplinary

MOF materials as therapeutic agents, drug carriers, imaging agents and biosensors in cancer biomedicine: Recent advances and perspectives

Adam Bieniek et al.

Summary: Recent advances have shown the significant potential of MOFs in cancer diagnostics and treatment, with a vast amount of literature and data requiring systematization. This study aims to consolidate and reflect the latest developments in MOFs applications in medicine, particularly in anticancer therapy, while discussing the potential, challenges, and emerging opportunities in using MOFs for cancer treatment.

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Design and optimization of electrochemical cell potential for hydrogen gas production

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Summary: This study focuses on optimizing the best working conditions in molten salt melt for hydrogen gas production, achieving high current efficiency of up to 90.5%. The research reveals that an increase in current is directly proportional to the flow rate of hydrogen gas, leading to an increase in hydrogen production.

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A nanoscale Nd-based metal-organic framework electrochemical sensor for rapid detection of Rhodamine B

Shaoxiong Feng et al.

Summary: A novel neodymium-based metal-organic framework (Nd-MOF) was synthesized and used to construct an efficient electrochemical sensor for the rapid and reliable detection of Rhodamine B (RhB). The Nd-MOF/GCE sensor exhibited strong accumulation ability and high electrocatalytic activity for RhB detection, with wide linear detection ranges and a low detection limit.

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Recent advances on preparation and environmental applications of MOF-derived carbons in catalysis

Mengjie Hao et al.

Summary: This review summarizes the synthesis strategies of MOF-derived carbons and their potential applications in catalysis, especially in organo-catalysis, photocatalysis, and electrocatalysis. The focus is on the properties of derived carbons and their roles in improving catalytic efficiency.

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Review Biotechnology & Applied Microbiology

Metal-Organic Framework (MOF)-Based Biomaterials for Tissue Engineering and Regenerative Medicine

Moldir Shyngys et al.

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Review Materials Science, Multidisciplinary

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Jie Yang et al.

Summary: Research on metal-organic frameworks (MOFs) in fluorescence sensors is still in the early stage but shows great potential. Recent advances in materials design, manufacturing strategies, and detection applications for various analytes have been systematically reviewed. The diversity of materials and adjustable structure of MOFs make them suitable for the design and construction of fluorescence sensors, enhancing sensitivity and selectivity.

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY (2021)

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Article Chemistry, Applied

A novel fluorescent metal-organic framework based on porphyrin and AIE for ultra-high sensitivity and selectivity detection of Pb2+ ions in aqueous solution

Qianyi Wang et al.

Summary: The synthesis of ZnTCPP-MOF allows for efficient detection of Pb2+ ions in water, demonstrating excellent selectivity and sensitivity. The fluorescent properties of ZnTCPP-MOF were prominent in the experiment, enabling rapid detection of Pb2+ ions even at low concentrations. The study highlights the ability of ZnTCPP-MOF to detect Pb2+ ions in water, with a low limit of detection of 4.99 x 10-8 M, which outperforms other MOFs.

DYES AND PIGMENTS (2021)

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Fluorescein Hydrazide-Appended Metal-Organic Framework as a Chromogenic and Fluorogenic Chemosensor for Mercury Ions

Aasif Helal et al.

Summary: In this study, a FH@Ni(MOF) composite was developed for highly selective and sensitive detection of Hg2+ ions. The composite exhibited significant optical signal changes upon binding with Hg2+ ions and was suitable for practical water sample detection.

MOLECULES (2021)

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Article Chemistry, Inorganic & Nuclear

Multifunctional MOF-based probes for efficient detection and discrimination of Pb2+, Fe3+ and Cr2O72-/CrO42-

Fengqin Wang et al.

Summary: In this study, metal-organic framework-based fluorescent probes were developed for efficient detection of polluting ions in groundwater, showing high sensitivity and good anti-interference ability. Additionally, Eu3+-incorporated samples with dual-emission were fabricated, acting as multi-target probes for selectively detecting specific ions. The recognition mechanism may be attributed to the competitive energy absorption between MOFs or Eu3+@MOFs and the analytes.

DALTON TRANSACTIONS (2021)

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Wei Shi et al.

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ACS APPLIED NANO MATERIALS (2021)

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Recent progresses in luminescent metal-organic frameworks (LMOFs) as sensors for the detection of anions and cations in aqueous solution

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Summary: Luminescent metal-organic frameworks (LMOFs) serve as fluorescent probes to rapidly and effectively detect excessive metal ions and anions in water, showing great potential for application. The luminescence properties of LMOFs are influenced by the selection of metal ions, the structure of organic ligands, the pore size, and the interaction of guest molecules, requiring further research and development.

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Metal-Organic-Framework-Based Materials as Platforms for Renewable Energy and Environmental Applications

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JOULE (2017)

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Recent developments on optical and electrochemical sensing of copper(II) ion based on transition metal complexes

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Multi-Responsive Luminescent Sensors Based on Two-Dimensional Lanthanide-Metal Organic Frameworks for Highly Selective and Sensitive Detection of Cr(III) and Cr(VI) Ions and Benzaldehyde

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CRYSTAL GROWTH & DESIGN (2017)

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Metal-organic frameworks: functional luminescent and photonic materials for sensing applications

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Synthesis of multifunctional upconversion NMOFs for targeted antitumor drug delivery and imaging in triple negative breast cancer cells

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A luminescent metal organic framework with high sensitivity for detecting and removing copper ions from simulated biological fluids

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Stable Zr(IV)-Based Metal-Organic Frameworks with Predesigned Functionalized Ligands for Highly Selective Detection of Fe(III) Ions in Water

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Dendrite-Free Nanocrystalline Zinc Electrodeposition from an Ionic Liquid Containing Nickel Triflate for Rechargeable Zn-Based Batteries

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Porphyrinic Metal-Organic Framework Catalyzed Heck-Reaction: Fluorescence Turn-On Sensing of Cu(II) Ion

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CHEMISTRY OF MATERIALS (2016)

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Adsorption, separation, and catalytic properties of densified metal-organic frameworks

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Fluorescent Aromatic Tag-Functionalized MOFs for Highly Selective Sensing of Metal Ions and Small Organic Molecules

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A Water-Stable Metal-Organic Framework for Highly Sensitive and Selective Sensing of Fe3+ Ion

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Lanthanide coordination polymers for multi-color luminescence and sensing of Fe3+

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Metal-organic frameworks: structure, properties, methods of synthesis and characterization

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A novel photofunctional hybrid material of pyrene functionalized metal-organic framework with conformation change for fluorescence sensing of Cu2+

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A turn on fluorescent sensor based on lanthanide coordination polymer nanoparticles for the detection of mercury(II) in biological fluids

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Fast, Sensitive, and Selective Ion-Triggered Disassembly and Release Based on Tris(bipyridine)ruthenium(II)-Functionalized Metal-Organic Frameworks

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Surface assembly of nano-metal organic framework on amine functionalized indium tin oxide substrate for impedimetric sensing of parathion

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Pre-concentration and energy transfer enable the efficient luminescence sensing of transition metal ions by metal-organic frameworks

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Supercapacitors of Nanocrystalline Metal-Organic Frameworks

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Encapsulation of Strongly Fluorescent Carbon Quantum Dots in Metal- Organic Frameworks for Enhancing Chemical Sensing

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High gas storage capacities and stepwise adsorption in a UiO type metal-organic framework incorporating Lewis basic bipyridyl sites

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Surfactant assisted nano-composite cation exchanger: Development, characterization and applications for the removal of toxic Pb2+ from aqueous medium

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Water Stability and Adsorption in Metal-Organic Frameworks

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MOF-based electronic and optoelectronic devices

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Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications

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Simultaneous detection of Cd(II) and Pb(II) by differential pulse anodic stripping voltammetry at a nitrogen-doped microporous carbon/Nafion/bismuth-film electrode

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ELECTROCHIMICA ACTA (2014)

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TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2014)

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Non-conductive nanomaterial enhanced electrochemical response in stripping voltammetry: The use of nanostructured magnesium silicate hollow spheres for heavy metal ions detection

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A Noble-Metal-Free Porous Coordination Framework with Exceptional Sensing Efficiency for Oxygen

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Polyamine-Functionalized Carbon Quantum Dots as Fluorescent Probes for Selective and Sensitive Detection of Copper Ions

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Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites

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Luminescent Microporous Metal-Organic Framework with Functional Lewis Basic Sites on the Pore Surface: Specific Sensing and Removal of Metal Ions

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Conductive metal-organic frameworks and networks: fact or fantasy?

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Liquid-Phase Epitaxy of Multicomponent Layer-Based Porous Coordination Polymer Thin Films of [M(L)(P)0.5] Type: Importance of Deposition Sequence on the Oriented Growth

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Atomic spectrometry update. Elemental speciation

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Solvatochromic Behavior of a Nanotubular Metal-Organic Framework for Sensing Small Molecules

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Zinc(II) and Cadmium(II) Metal Complexes with Bis(tetrazole) Ligands: Synthesis and Crystal Structures

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Engineering Metal Organic Frameworks for Heterogeneous Catalysis

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The first transition-metal metal-organic framework showing cation exchange for highly selectively sensing of aqueous Cu(II) ions

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Colloidal Route for Preparing Optical Thin Films of Nanoporous Metal-Organic Frameworks

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Elaboration and properties of hierarchically structured optical thin films of MIL-101(Cr)

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Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework

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Interaction of an extended series of N-substituted di(2-picolyl)amine derivatives with copper(II). Synthetic, structural, magnetic and solution studies

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CO2 Adsorption-Based Separation by Metal Organic Framework (Cu-BTC) versus Zeolite (13X)

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Accessing Postsynthetic Modification in a Series of Metal-Organic Frameworks and the Influence of Framework Topology on Reactivity

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Multiplexed Imaging of Therapeutic Cells with Multispectrally Encoded Magnetofluorescent Nanocomposite Emulsions

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Co-adsorption and Separation of CO2-CH4 Mixtures in the Highly Flexible MIL-53(Cr) MOF

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Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine

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Zeolite-like Metal-Organic Frameworks (ZMOFs) as Hydrogen Storage Platform: Lithium and Magnesium Ion-Exchange and H2-(rho-ZMOF) Interaction Studies

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Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature

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High-throughput screening of synthesis parameters in the formation of the metal-organic frameworks MOF-5 and HKUST-1

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MICROPOROUS AND MESOPOROUS MATERIALS (2009)

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Facile synthesis of nanocrystals of a microporous metal-organic framework by an ultrasonic method and selective sensing of organoamines

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Syntheses, Structures, and Properties of Copper(II) Complexes of Bis(2-pyridylmethyl) Derivatives of o-, m-, and p-Phenylenediamine and Aniline

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Article Chemistry, Organic

Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0

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Tunable luminescent lanthanide coordination polymers based on reversible solid-state ion-exchange monitored by ion-dependent photoinduced emission spectra

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An explanation for the very large breathing effect of a metal-organic framework during CO2 adsorption

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Review Chemistry, Analytical

Electrochemical nanobiosensors

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Role of solvent-host interactions that lead to very large swelling of hybrid frameworks

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Solvent effect in a solvent free reaction

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CRYSTENGCOMM (2007)

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Metal-organic frameworks -: prospective industrial applications

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JOURNAL OF MATERIALS CHEMISTRY (2006)

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Solvent-free synthesis of a microporous metal-organic framework

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CRYSTENGCOMM (2006)

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Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature

AR Millward et al.

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Attachment of electron-withdrawing 2,4-dinitrobenzene groups to a cryptand-based receptor for Cu(II)/H+-specific exciplex and monomer emissions

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High affinity DNAzyme-based ligands for transition metal cations -: a prototype sensor for Hg2+

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Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues

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NATURE (2004)

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Development of fluorescent film sensors for the detection of divalent copper

Y Zheng et al.

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Synthesis, morphology control, and properties of porous metal-organic coordination polymers

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MICROPOROUS AND MESOPOROUS MATERIALS (2003)

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