Design, synthesis, and application of thermally responsive draw solutes for sustainable forward osmosis desalination: A review

Forward osmosis (FO) is an emerging sustainable desalination technology; however, it is not a stand-alone process and requires an additional step to recover the water or regenerate the draw solute (DS), making it energy extensive. Therefore, incorporating inexpensive energy sources for DS regeneration is a viable solution to compete with reverse osmosis desalination technology. Hence, selecting suitable DS and its regeneration became a crucial research focus in FO desalination. Among various DSs reported, thermally responsive DSs (TRDS) provide an opportunity to integrate low-grade energy sources for DS regeneration. Utilizing such inexpensive energy will reduce fossil fuel energy demand, lower the cost of desalination, and minimize the carbon footprint. Hence, this review explores the TRDS for FO-based desalination with its design, synthesis, and applications. The manuscript has discussed the classification and selection criteria for the DSs, and how traditional and newgeneration TRDSs are designed and synthesized from cationic and anionic moieties of ionic liquids, hydrogels, and other chemicals. The manuscript has also given importance to design criteria such as osmotic strength, viscosity, toxicity, and thermal stability for TRDSs. Furthermore, a detailed discussion on the FO performance, energy, and economic aspects of TRDSs has been reviewed, along with a discussion on the possible low-grade energy sources for the recovery of TRDS. Finally, the challenges and future directions for TRDSs have been discussed to drive FO toward sustainable desalination technology.

Automated summary

Forward osmosis (FO) is a promising desalination technology, but it requires an additional step for water recovery or draw solute (DS) regeneration, making it energy intensive. Incorporating inexpensive energy sources for DS regeneration is a viable solution to compete with reverse osmosis desalination technology. This review explores thermally responsive DSs (TRDS) for FO-based desalination, discussing their design, synthesis, applications, and potential low-grade energy sources for recovery.