Palladium-Catalyzed Cross-Coupling of Tertiary Cyclopropyl Carbagermatranes with Acyl Chlorides

A simple method for the synthesis of cyclopropane compounds via cross-coupling reaction between tertiary cyclopropyl carbagermatranes and acyl chlorides was reported. Derivatives of acryloyl chloride and aliphatic acyl chloride also performed to be suitable substrates. This process can be used to introduce a wide range of functionalized cyclopropane groups and acyl groups directly.

Automated summary

A simple method for the synthesis of cyclopropane compounds through the cross-coupling reaction between tertiary cyclopropyl carbagermatranes and acyl chlorides was reported. Derivatives of acryloyl chloride and aliphatic acyl chloride were also found to be suitable substrates. This method allows for the direct introduction of a wide range of functionalized cyclopropane and acyl groups.