4.6 Review

Periodic Mesoporous Organosilica Nanomaterials with Unconventional Structures and Properties

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Dual-Modal Lateral Flow Test Strip Assisted by Near-Infrared- Powered Nanomotors for Direct Quantitative Detection of Circulating MicroRNA Biomarkers from Serum

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Summary: This study presents a method for direct, amplification-free, and quantitative detection of miRNA-21 in serum and cell medium using near-infrared-powered Janus nanomotors as swimming probes in a lateral flow test strip (LFTS). The active movement of the nanomotors significantly improved the capture efficiency of miRNA-21 targets, enabling direct quantitative detection on the LFTS assay with both visual and thermal signals. The constructed LFTS assay achieved a limit-of-detection of 18 fmol/L for miRNA-21, which was 12.22-fold compared to that of LFTS assay with static probes. This method holds great potential for early diagnosis and treatment of miRNA-related diseases.

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Summary: Janus nanomaterials composed of two compartments with dissimilar compositions and/or functionalities have attracted considerable attention in recent years. Janus polymer/inorganic nanocomposites, combining properties of polymers and inorganic substances, exhibit appealing properties and potential applications. Various synthetic routes allow for the creation of Janus materials with tunable composition, morphology, and microstructures.

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Multiphase Microreactors Based on Liquid-Liquid and Gas-Liquid Dispersions Stabilized by Colloidal Catalytic Particles

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Xiquan Cheng et al.

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Pickering Emulsion Catalysis: Interfacial Chemistry, Catalyst Design, Challenges, and Perspectives

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Preparation and application of Janus nanoparticles: Recent development and prospects

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Periodic mesoporous organosilicas (PMOs): From synthesis strategies to applications

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Shedding Light on Luminescent Janus Nanoparticles: From Synthesis to Photoluminescence and Applications

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Summary: This article reviews the design, preparation, optical properties, and applications of luminescent Janus nanoparticles. The introduction of luminescence has expanded the functionalities and applications of Janus nanoparticles. The opportunities and challenges in developing next-generation luminescent Janus nanoparticles are also discussed.
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Janus phenol-formaldehyde resin and periodic mesoporous organic silica nanoadsorbent for the removal of heavy metal ions and organic dyes from polluted water

Yangying Si et al.

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ADVANCED COMPOSITES AND HYBRID MATERIALS (2022)

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Task-Specific Janus Materials in Heterogeneous Catalysis

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Summary: This review systematically covers recent and significant achievements in the application of task-specific Janus nanomaterials as heterogeneous catalysts in various types of chemical reactions, and provides an outlook on possible future applications.

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A Chemotactic Colloidal Motor

Chang Zhou et al.

Summary: Chemotactic colloidal motors have promising applications in the biomedical field, requiring submicrometer scale, strong chemotactic ability, and clear chemotactic mechanism.

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Influence of Surface Chemistry on the Surfactant Organization and Interfacial Structure of Mesoporous Silica and Organosilica

Gyehyun Park et al.

Summary: The influence of surface chemistry on interfacial interactions and assembly structures of mesoporous silica (SiO2) and periodic mesoporous organosilica (PMO) with different bridging groups is studied. The results show that the different organic bridging groups lead to different adsorption behaviors of surfactants and affect the assembly structures. The findings provide guidance for the design of molecular machines, absorbents, and enzyme immobilization materials.

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NIR Light-Propelled Janus-Based Nanoplatform for Cytosolic-Fueled microRNA Imaging

Fan Lin et al.

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Dual-Propelled Lanbiotic Based Janus Micromotors for Selective Inactivation of Bacterial Biofilms

Kaisong Yuan et al.

Summary: A graphene oxide/PtNPs/Fe2O3 dual-propelled catalytic and fuel-free rotary actuated magnetic Janus micromotors modified with Nisin are designed for highly selective capture/inactivation of gram-positive bacteria and biofilms. The micromotors show a 2-fold increase in capture/killing ability compared to free peptide and static counterparts, due to the specific interaction of Nisin with Staphylococcus Aureus bacteria Lipid II unit. High stability of Nisin and high towing force allow for efficient operation in untreated media and in blood, illustrating the high selectivity and potential for tailored lanbiotics in various applications.

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Janus bifunctional periodic mesoporous organosilica

Majid Vafaeezadeh et al.

Summary: A new method for synthesizing a Janus periodic mesoporous organosilica material (JPMO) is introduced, where the material is capable of forming stable Pickering emulsions. This bifunctional material may find widespread applications in various fields related to material science and catalysis.

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Amine-promoted Ru1/Fe3O4 encapsulated in hollow periodic mesoporousorganosilica sphere as a highly selective and stable catalyst for aqueous levulinic acid hydrogenation

Ying Yang et al.

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Fast and Selective Aqueous-Phase Oxidation of Styrene to Acetophenone Using a Mesoporous Janus-Type Palladium Catalyst

Majid Vafaeezadeh et al.

Summary: By selectively modifying the surface of hollow mesoporous silica material, a heterogeneous Janus-type palladium interphase catalyst was obtained, showing exceptional activity for the aqueous-phase oxidation of styrene to acetophenone. The catalyst demonstrated an 88% yield of acetophenone after 60 minutes of reaction.

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Plugged bifunctional periodic mesoporous organosilica as a high-performance solid phase microextraction coating for improving extraction efficiency of chlorophenols in different matrices

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Electrochemically-Matched and Nonflammable Janus Solid Electrolyte for Lithium-Metal Batteries

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