Helical Self-Assembly and Fe3+ Detection of V-Shaped AIE-Active Chiral Tetraphenylbutadiene-Based Polyamides

Chiral aggregation-induced emission (AIE) molecules have drawn attention for their helical self-assembly and special optical properties. The helical self-assembly of AIE-active chiral non-linear main-chain polymers can produce some desired optical features. In this work, a series of V-shaped chiral AIE-active polyamides P1-C3, P1-C6, P1-C12 and linear P2-C3, P2-C6, bearing n-propyl/hexyl/dodecyl side-chains, based on tetraphenylbutadiene (TPB), were prepared. All target main-chain polymers exhibit distinct AIE characteristics. The polymer P1-C6 with moderate length alkyl chains shows better AIE properties. The V-shaped main-chains and the chiral induction of (1R,2R)-(+)-1,2-cyclohexanediamine in each repeating unit promote the polymer chains display helical conformation, and multiple helical polymer chains induce nano-fibers helicity when the polymer chains aggregate and self-assemble in THF/H2O mixtures. Simultaneously, the helical conformation polymer chains and helical nano-fibers cause P1-C6 produce strong circular dichroism (CD) signals with positive Cotton effect. Moreover, P1-C6 could also occur fluorescence quenching response to Fe3+ selectively with a low detection limit of 3.48 & mu;mol/L.

Automated summary

In this study, a series of V-shaped chiral polyamides with aggregation-induced emission (AIE) properties were synthesized. The polymer P1-C6 with moderate alkyl chain length demonstrated superior AIE performance. It exhibited strong circular dichroism (CD) signals with positive Cotton effect and fluorescence quenching response specifically to Fe3+.