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Anisotropic Heavy-Metal-Free Semiconductor Nanocrystals: Synthesis, Properties, and Applications

CHEMICAL REVIEWS (2023)

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Article Chemistry, Multidisciplinary

ZnSe Nanorods-CsSnCl3 Perovskite Heterojunction Composite for Photocatalytic CO2 Reduction

Nuoya Li et al.

Summary: Utilizing sunlight to convert CO2 into chemical fuels can address the greenhouse effect and fossil fuel crisis. This study designed and prepared a composite material based on ZnSe and CsSnCl3, which can enhance the photocatalytic activity for CO2 reduction and contribute to the development of metal halide perovskite photocatalysts.

ACS NANO (2022)

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Review Chemistry, Multidisciplinary

Application of Perovskite Quantum Dots as an Absorber in Perovskite Solar Cells

Weiguang Chi et al.

Summary: This Review analyzes the issues and advantages of perovskite quantum dots (QDs) in terms of purification, device fabrication, light absorption, charge transport, and stability. Promising strategies to enhance perovskite QDs and QD-based solar cells are elucidated based on exchange chemistry, passivation engineering, and structure engineering, paving the way for further development in this area.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Review Engineering, Environmental

Looping Mercury Cycle in Global Environmental-Economic System Modeling

Yumeng Li et al.

Summary: The Minamata Convention on Mercury aims to protect the environment and human beings from the adverse impacts of mercury pollution. Current studies show that mercury emissions can have negative effects on human health and ecosystems, but the feedback of mercury-related environmental impacts to the economic system is not fully understood. This lack of understanding impedes the development of comprehensive mercury control actions, highlighting the need for further research and modeling to loop the mercury cycle in the global environmental-economic system.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2022)

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Article Chemistry, Multidisciplinary

Germanium Halides Serving as Ideal Precursors: Designing a More Effective and Less Toxic Route to High-Optoelectronic-Quality Metal Halide Perovskite Nanocrystals

Xiaochen Wang et al.

Summary: The study introduces all-inorganic germanium salts, GeX4, as robust and less hazardous alternatives for improving the material properties of both Pb-based and Pb-free PNCs. GeX4 does not introduce the Ge element into the final nanocrystals, resulting in significantly improved photoluminescence quantum yield and phase stability. Theoretical calculations suggest that Ge halide precursors provide favorable conditions for the formation of defect-suppressed nanoparticles.

NANO LETTERS (2022)

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Article Chemistry, Physical

Frustrated Lewis Pair Sites Boosting CO2 Photoreduction on Cs2CuBr4 Perovskite Quantum Dots

Jianping Sheng et al.

Summary: This study reports alternative Cs2CuBr4 PQDs for photocatalytic CO2 reduction, demonstrating their high efficiency and unique adsorption and activation mechanism, with potential practical applications.

ACS CATALYSIS (2022)

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Review Materials Science, Multidisciplinary

Anisotropic Low-Dimensional Materials for Polarization-Sensitive Photodetectors: From Materials to Devices

Jing Wang et al.

Summary: This review provides an overview of the recent developments in polarization-sensitive photodetectors based on anisotropic systems. It presents the classification and anisotropic properties of low-dimensional materials, analyzes the anisotropic characteristics of different material systems from the perspective of crystallography, and discusses the working mechanism of polarization-sensitive photodetectors. Furthermore, it reviews the recent advances of polarization-sensitive photodetectors based on low-dimensional materials and addresses some breakthroughs for future development in this field.

ADVANCED OPTICAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Reductive Carbon-Carbon Coupling on Metal Sites Regulates Photocatalytic CO2 Reduction in Water Using ZnSe Quantum Dots

Zhi-Kun Xin et al.

Summary: Colloidal quantum dots made of precious-metal-free elements have attractive potential for solar-driven CO2 reduction. However, inhibiting the production of hydrogen remains a challenge. This study presents a carbon-carbon coupling reaction as a solution to block the competing hydrogen evolution in photocatalytic CO2 reduction, using zinc selenide quantum dots as catalysts. Introducing furfural significantly suppresses the evolution of hydrogen and enhances the production of CO.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Materials Science, Ceramics

Efficient and stable TiO2 nanorod array structured perovskite solar cells in air: Co-passivation and synergistic mechanism

Zhipeng Wang et al.

Summary: This study investigates the effects of octyl ammonium iodide (OAI) and choline chloride (Ch) on the performance and stability of titanium dioxide nanorod arrays (TNRAs)-based perovskite solar cells (PSCs). The results show that OAI enhances the structural stability of the perovskite layer, while Ch passivates defects on the surface. The optimized devices with the passivated layers achieve higher power conversion efficiency (PCE) and improved stability compared to the pristine devices.

CERAMICS INTERNATIONAL (2022)

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Article Materials Science, Multidisciplinary

Photoluminescence Enhancement of NIR-II Emissive Ag2S Quantum Dots via Chloride-Mediated Growth and Passivation

Liang-Jun Pan et al.

Summary: This study demonstrates a novel strategy to prepare Ag2S quantum dots with high photoluminescence quantum yield (PLQY) through chloride-mediated growth and passivation. By partially exchanging ligands and passivating with chloride ions, the surface trap states in Ag2S QDs are effectively reduced, leading to a significant enhancement of photoluminescence intensity.

ADVANCED OPTICAL MATERIALS (2022)

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Review Chemistry, Physical

Rational Design of Metal Halide Perovskite Nanocrystals for Photocatalytic CO2 Reduction: Recent Advances, Challenges, and Prospects

Jin Wang et al.

Summary: This review focuses on the application of metal halide perovskite nanocrystals (MHP NCs) in the field of photocatalysis. It highlights the key issues in developing MHP photocatalysts, such as severe charge recombination and low stability, and provides design principles and modification strategies to address these issues. An outlook on future challenges and prospects is also presented.

ACS ENERGY LETTERS (2022)

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Article Energy & Fuels

Band Alignment Engineering of Semiconductor Nanocrystal Heterostructures Toward Emerging Applications

Long Liu et al.

Summary: This article provides an overview of the potential applications of heterostructure nanocrystals in various fields, including lighting devices, lasers, photocatalysis, and biological applications. By tuning the band alignment, the properties of these nanocrystals can be modified.

SOLAR RRL (2022)

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Article Chemistry, Multidisciplinary

Enriched-Bromine Surface State for Stable Sky-Blue Spectrum Perovskite QLEDs With an EQE of 14.6%

Hanwen Zhu et al.

Summary: Enriched-bromine surface state is achieved through anion exchange with PbBr2 stock solution in Cd-doped perovskite quantum dots, leading to improved efficiency and stability of perovskite QLEDs.

ADVANCED MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Co-doping of tellurium with bismuth enhances stability and photoluminescence quantum yield of Cs2AgInCl6 double perovskite nanocrystals

Shixun Wang et al.

Summary: Co-doping of double perovskites with Bi3+ and Te4+ ions improves their stability and enhances photoluminescence quantum yield. The introduction of Te4+ ions promotes the radiative recombination of self-trapped excitons in Cs2AgInCl6 nanocrystals. Excess use of the TeO2 precursor leads to the generation of residual TeO2, Te2O3Cl2, R2TeO, which improves coordination with surface oleic acid ligands. The co-doped Cs2AgInCl6 nanocrystals with 1% Bi and 8% Te exhibit a high photoluminescence quantum yield of 34% and excellent stability, retaining over 70% of their original emission intensity after storage for more than 1 month.

NANOSCALE (2022)

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Review Chemistry, Physical

Recent advances in anisotropic two-dimensional materials and device applications

Jinlai Zhao et al.

Summary: Anisotropic 2D materials possess unique properties and have garnered extensive attention for their wide range of applications. Recent advances have led to the fabrication of new devices based on these materials, demonstrating significant potential for further development.

NANO RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Quantum-Rod On-Chip LEDs for Display Backlights with Efficacy of 149 lm W-1: A Step toward 200 lm W-1

Chengbin Kang et al.

Summary: Efficient white light-emitting diodes (LEDs) with an efficacy of 200 lm W-1 are much desired for lighting and displays. Current phosphor-based LEDs in use for display applications offer poor color saturation, leading to intensive efforts to replace phosphor with quantum-dot-based downconverters to improve efficiency and stability. In this study, gradient alloyed CdSe/ZnxCd1-xS/ZnS and CdSe/CdS/ZnS core/shell/shell quantum rods (QRs) downconverters show high efficacy LEDs and wide color gamut.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Efficient Infrared Solar Cells Employing Quantum Dot Solids with Strong Inter-Dot Coupling and Efficient Passivation

Sisi Liu et al.

Summary: By epitaxially coating a thin PbS shell over the PbSe QDs and in situ halide passivation, a strategy to decouple the restrictive relation between V-OC and J(SC) in QD IR photovoltaics is developed. This approach allows for excellent trap-state control and outstanding performance under filtered solar illumination, providing a new route to overcome the trade-off between V-OC and J(SC) limited by the photoactive layer with a given bandgap.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Physical

Colloidal Manganese-Doped ZnS Nanoplatelets and Their Optical Properties

Liwei Dai et al.

Summary: This study presents the successful direct doping of Mn2+ ions into ZnS nanoplatelets using a nucleation-doping strategy, resulting in Mn luminescence in ZnS:Mn NPLs. Energy transfer from ZnS NPLs to Mn2+ ions was observed, and the impact of Mn concentration on optical properties was systematically investigated. Tunable Mn emission and enhanced PL quantum yield in ZnS:Mn NPLs were achieved by passivating surface trap states. The synthetic strategy introduced here opens up new possibilities for further doped systems of two-dimensional NPLs.

CHEMISTRY OF MATERIALS (2021)

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Article Chemistry, Physical

Seeded Growth Combined with Cation Exchange for the Synthesis of Anisotropic Cu2-xS/ZnS, Cu2-xS, and CuInS2 Nanorods

Chenghui Xia et al.

Summary: Colloidal copper(I) sulfide nanocrystals have unique optoelectronic properties, making them potential seeds for the synthesis of heteronanocrystals. By using a multistep synthesis strategy, Cu2-xS/ZnS Janus-type heteronanorods were successfully obtained with sharp heterointerfaces. This work demonstrates the rational synthesis of multicomponent heteronanorods by combining postsynthetic heteroepitaxial seeded growth and nanoscale cation exchange.

CHEMISTRY OF MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Quantum Photoinitiators: Toward Emerging Photocuring Applications

Nir Waiskopf et al.

Summary: Semiconductor nanocrystals, as promising photocatalysts, have diverse properties that depend on multiple parameters, such as composition, dimensions, architecture, surface coating, and environmental conditions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

Wavelength-selectivity polarization dependence of optical absorption and photoresponse in SnS nanosheets

Yu Cui et al.

Summary: The research focused on the optical and optoelectronic characteristics of SnS nanosheets with strong anisotropic crystal structure, showing high performance in photodetection at 450 nm and distinctive polarization sensitivity at 862 nm. The nanosheets exhibit potential for future applications in polarized photodetectors for specific wavelengths.

NANO RESEARCH (2021)

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Article Nanoscience & Nanotechnology

High-Performance Ultrapure Green CdSe/CdS Core/Crown Nanoplatelet Light-Emitting Diodes by Suppressing Nonradiative Energy Transfer

Zuoliang Wen et al.

Summary: This study developed an ultrapure green emitting nanocrystal LED based on four-monolayer CdSe/CdS core/crown NPLs, successfully suppressing nonradiative energy transfer by applying nonstacked nanoplates and achieving pure green emission with low turn-on voltage, high maximum luminance, and peak external quantum efficiency.

ADVANCED ELECTRONIC MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Synthesis and applications of anisotropic nanoparticles with precisely defined dimensions

Amanda K. Pearce et al.

Summary: Shape and size are crucial factors in determining material properties, and the introduction of shape anisotropy at the nanoscale is a potent way to access new properties and functionalities. Recent advancements have allowed for precise control over the morphology and dimensions of anisotropic nanoparticles, leading to the development of materials with unique properties.

NATURE REVIEWS CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Toward Bright Mid-Infrared Emitters: Thick-Shell n-Type HgSe/CdS Nanocrystals

Ananth Kamath et al.

Summary: A new method was developed to grow thick, conformal CdS shells that preserve the optical properties of 5 nm HgSe cores, with the doping of the core/shell particles quantitatively tuned through a simple postsynthetic Cd treatment. The CdS shell greatly increases the intraband emission intensity and raises important questions about the fundamental limits to achievable slow intraband relaxation in quantum dots.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

In Situ Epitaxial Growth of Centimeter-Sized Lead-Free (BA)2CsAgBiBr7/Cs2AgBiBr6 Heterocrystals for Self-Driven X-ray Detection

Xinyuan Zhang et al.

Summary: This study presents the successful creation of lead-free halide perovskite heterocrystals with built-in electric potential and high crystalline quality. These heterocrystals can operate in a self-driven mode in X-ray detectors, exhibiting superior sensitivity and operational stability.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

Contrasting Ligand-Exchange Behavior of Wurtzite and Zinc-Blende Cadmium Telluride Nanoplatelets

Haochen Sun et al.

Summary: The ligand-exchange chemistries of wurtzite (WZ) and zinc-blende (ZB) CdTe nanoplatelets exhibit contrasting behaviors, which are consistent with their facet structures. WZ nanoplatelets prefer nonpolar facets and neutral ligation, while ZB nanoplatelets prefer polar, cationic facets and anionic ligation.

CHEMISTRY OF MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Colloidal Alloyed Quantum Dots with Enhanced Photoluminescence Quantum Yield in the NIR-II Window

Hongchao Yang et al.

Summary: Alloyed AgAuSe quantum dots exhibit high PLQY and long lifetime in the NIR-II window, showing great potential for applications in bioimaging, LEDs, and photovoltaic devices.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Synthesis of Lead-Free Cs2AgBiX6 (X = CI, Br, I) Double Perovskite Nanoplatelets and Their Application in CO2 Photocatalytic Reduction

Zhenyang Liu et al.

Summary: This study successfully synthesized two-dimensional nanoplatelets of Cs2AgBiX6 (X = Cl, Br, I) through a newly developed synthetic procedure, demonstrating the morphology control achievable in lead-free double perovskite materials and the better performance in photocatalytic CO2 reduction of Cs2AgBiBr6 nanoplatelets.

NANO LETTERS (2021)

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Article Chemistry, Physical

Ultrathin lead-free double perovskite cesium silver bismuth bromide nanosheets

Jianmei Huang et al.

Summary: In this study, lead-free 2D halide double perovskite nanosheets were successfully synthesized, demonstrating excellent optoelectronic properties and providing guidance for the controllable synthesis of multi-component compounds.

NANO RESEARCH (2021)

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Article Engineering, Biomedical

Bistratal Au@Bi2S3 nanobones for excellent NIR-triggered/multimodal imaging-guided synergistic therapy for liver cancer

Ruizhuo Ouyang et al.

Summary: The novel Au@Bi2S3 core shell nanobones (NBs) with Au nanorods as cores showed excellent photothermal conversion efficiency, remarkable photoacoustic imaging, and high computed tomography performance, making them a promising nanotheranostic agent for imaging. The poly(N-vinylpyrrolidone)-modified Au@Bi2S3 NBs loaded with the anticancer drug doxorubicin achieved a satisfactory pH sensitive release profile, demonstrating great potential in chemotherapy. Both in vitro and in vivo investigations confirmed the Au@Bi2S3-PVP NBs as an effective agent for cancer therapy, with low toxicity, good biocompatibility, high drug loading ability, precise tumor targeting, and efficient ablation of cancer cells.

BIOACTIVE MATERIALS (2021)

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Article Chemistry, Physical

High efficiency photoelectrochemical hydrogen generation using eco-friendly Cu doped Zn-In-Se colloidal quantum dots

Bing Luo et al.

Summary: This study demonstrates the efficient hydrogen production by utilizing eco-friendly Cu-doped Zn-In-Se colloidal quantum dots in PEC cells, achieving unprecedented saturated photocurrent density under sunlight illumination. The optimized Cu dopant and Zn:In ratio significantly enhance light absorption, carrier injection rates/lifetime and the spatial separation of electron-hole pairs, showing promise for high efficiency and environmentally friendly solar-driven applications.

NANO ENERGY (2021)

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Article Chemistry, Physical

Phase-Dependent Shell Growth and Optical Properties of ZnSe/ZnS Core/Shell Nanorods

Jiajia Ning et al.

Summary: The most efficient way to improve the stability and optical properties of nanocrystals is to grow shell around their cores. Different growth modes of the ZnS shell on ZnSe nanorods were observed depending on the crystal structure of the ZnSe core, leading to differences in photoluminescence quantum yield.

CHEMISTRY OF MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Extending the Near-Infrared Emission Range of Indium Phosphide Quantum Dots for Multiplexed In Vivo Imaging

Alexander M. Saeboe et al.

Summary: This report showcases the reddest emitting indium phosphide quantum dots to date, demonstrating tunable near-infrared photoluminescence and PL multiplexing in the first optical tissue window while avoiding toxic constituents. By utilizing an inverted QD heterostructure, the synthesis overcomes the growth bottleneck and extends the emission peak of the nanoparticles into the deeper optical tissue window.

NANO LETTERS (2021)

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Article Nanoscience & Nanotechnology

Highly versatile near-infrared emitters based on an atomically defined HgS interlayer embedded into a CdSe/CdS quantum dot

Vladimir Sayevich et al.

Summary: This study presents high-quality near-infrared emitters based on CdSe/CdS heterostructures, which are converted from normally visible emitters to highly efficient near-infrared fluorophores by incorporating an HgS interlayer. The structures synthesized in this study exhibit highly efficient photoluminescence with atomic-level precision in defining the thickness of the HgS interlayer, resulting in 'quantized' jumps of the photoluminescence spectrum. Furthermore, the emission from these colloidal quantum dots is virtually blinking free and shows nearly perfect single-photon purity, making them promising for various applications.

NATURE NANOTECHNOLOGY (2021)

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Article Genetics & Heredity

Comparing Transcriptome Profiles of Saccharomyces Cerevisiae Cells Exposed to Cadmium Selenide/Zinc Sulfide and Indium Phosphide/Zinc Sulfide

Cullen Horstmann et al.

Summary: The global gene expression data of baker's yeast exposed to sub-lethal doses of quantum dots revealed changes in gene expression profiles, with CdSe/ZnS and InP/ZnS quantum dots altering genes related to various metabolic processes and cellular organization. The assessment of toxicity through cell viability assays and ROS detection assays indicated modest cytotoxic effects on yeast exposed to both types of quantum dots, with different effects on ROS levels observed between the two types.

GENES (2021)

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Article Nanoscience & Nanotechnology

Tin(II) Acetylacetonate as a New Type of Tin Compensator Additive for Tin-Based Perovskite Solar Cells

Feidan Gu et al.

Summary: Introducing a new tin compensator Sn (acac) (2) to improve the performance of tin-based perovskite solar cells and increase the maximum power conversion efficiency. In addition to compensating tin, the organic ligand acac (-) can also promote the crystallization process of perovskites.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Synthesis and Formation Mechanism of Colloidal Janus-Type Cu2-xS/CuInS2 Heteronanorods via Seeded Injection

Chenghui Xia et al.

Summary: Colloidal heteronanocrystals offer the synergistic combination of properties of different materials, such as spatial separation of photogenerated charge carriers to improve the efficiency of photocatalysts and photovoltaic devices. The synthesis of Cu2-xS/CuInS2 Janus-type heteronanorods through a two-step process allows for the rational design of heteronanocrystals with targeted architectures. By exploiting the size and faceting of premade Cu2-xS seed nanocrystals, the growth of the CuInS2 segment is directed, showcasing the potential for controlled synthesis in the formation of heteronanocrystals.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

State of the Art and Prospects for Halide Perovskite Nanocrystals

Amrita Dey et al.

Summary: Metal-halide perovskites have emerged as promising materials with exciting properties and great potential for applications in fields like photovoltaics and optoelectronics. Researchers have made significant progress in the synthesis, properties, and shape-controlled synthesis of perovskite nanocrystals.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

Synthesis and Bioapplications of Ag2S Quantum Dots with Near-Infrared Fluorescence

Caiping Ding et al.

Summary: NIR Ag2S QDs, known for their excellent NIR fluorescence properties and biocompatibility, have emerged as a promising tool for biosensing, bioimaging, and theranostics applications.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Versatile Synthesis of Hollow Metal Sulfides via Reverse Cation Exchange Reactions for Photocatalytic CO2 Reduction

Ruijin Zeng et al.

Summary: A novel growth strategy for fabricating hollow multinary metal sulfide using a Cu2-xS nanocube template-assisted and reverse cation exchange-mediated method was explored. Experimental and theoretical calculations demonstrated that the obtained hollow metal sulfide semiconductors significantly improve the separation and migration of photogenerated electron-hole pairs, leading to outstanding photocatalytic performance.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Synthesis of Wurtzite In and Ga Phosphide Quantum Dots Through Cation Exchange Reactions

Xinyao Shan et al.

Summary: This study successfully synthesized monodisperse wurtzite InP quantum dots through cation exchange reaction and demonstrated the feasibility of using this method to synthesize other III-V wurtzite QDs. Additionally, the growth of a gradient ZnSeS shell on wurtzite InP QDs resulted in fluorescent QDs with controllable emission wavelengths.

CHEMISTRY OF MATERIALS (2021)

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Review Physics, Applied

CuInSe2 and related I-III-VI2 chalcopyrite compounds for photovoltaic application

Takahiro Wada

Summary: CuInSe2 and other I-III-VI2 chalcopyrite compounds are important for solar cell applications, but their crystal and electronic structures are complex, making it difficult to fabricate high-efficiency solar cells.

JAPANESE JOURNAL OF APPLIED PHYSICS (2021)

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Review Multidisciplinary Sciences

Semiconductor quantum dots: Technological progress and future challenges

F. Pelayo Garcia de Arquer et al.

Summary: This article explores the distinctive behavior of electrons in quantum-confined semiconductor nanostructures and their impact on material properties, specifically focusing on the potential applications of zero-dimensional semiconductor quantum dots in optics and materials science.

SCIENCE (2021)

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Article Materials Science, Multidisciplinary

An ultrathin and dual band metamaterial perfect absorber based on ZnSe for the polarization-independent in terahertz range

Yadgar Abdulkarim et al.

Summary: A new ultra-thin and dual band metamaterials perfect absorber (MPA) design was proposed in this work, operating in the frequency range from 15 to 35 THz with high absorptivity. The proposed design is insensitive to incident angles and polarization angles, suitable for applications in stealth technology and imaging.

RESULTS IN PHYSICS (2021)

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Review Chemistry, Physical

All-inorganic perovskite quantum dots as light-harvesting, interfacial, and light-converting layers toward solar cells

Leimeng Xu et al.

Summary: Solution-processed colloidal lead halide perovskite quantum dots are considered promising candidates for next-generation photovoltaics due to their excellent optoelectronic properties and low-cost synthetic process. While remarkable breakthroughs have been made in bulk perovskite solar cells, all-inorganic perovskite quantum dot-based solar cells are still catching up. Various optimization means have been discussed to improve the performance of all-inorganic perovskite quantum dot-based solar cells.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Mechanochemically synthesized Pb-free halide perovskite-based Cs2AgBiBr6-Cu-RGO nanocomposite for photocatalytic CO2 reduction

Santosh Kumar et al.

Summary: The Pb-free Cs2AgBiBr6 double perovskite nanoplates and their heterostructure with Cu-loaded reduced graphene oxide exhibit significant photocatalytic activity and high quantum efficiency for gas-phase CO2 reduction. The enhanced performance compared to traditional Pb-based perovskites is attributed to improved charge separation, suppressed electron-hole recombination, and extended visible light absorption.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Nonepitaxial Gold-Tipped ZnSe Hybrid Nanorods for Efficient Photocatalytic Hydrogen Production

Wei Chen et al.

SMALL (2020)

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Review Chemistry, Physical

From Pb to Bi: A Promising Family of Pb-Free Optoelectronic Materials and Devices

Cuncun Wu et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Quantized Reaction Pathways for Solution Synthesis of Colloidal ZnSe Nanostructures: A Connection between Clusters, Nanowires, and Two-Dimensional Nanoplatelets

Patrick D. Cunningham et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Record High External Quantum Efficiency of 19.2% Achieved in Light-Emitting Diodes of Colloidal Quantum Wells Enabled by Hot-Injection Shell Growth

Baiquan Liu et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Rationally Designed Three-Layered Cu2S@Carbon@MoS2 Hierarchical Nanoboxes for Efficient Sodium Storage

Fang Yongjin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Synthesis of Anisotropic ZnSe Nanorods with Zinc Blende Crystal Structure

Jiajia Ning et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Dimensional Reduction of Cs2AgBiBr6: A 2D Hybrid Double Perovskite with Strong Polarization Sensitivity

Yaobin Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Agriculture, Multidisciplinary

Emerging Roles of microRNAs in Plant Heavy Metal Tolerance and Homeostasis

Yanfei Ding et al.

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2020)

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Article Energy & Fuels

Ligand-assisted cation-exchange engineering for high-efficiency colloidal Cs1-xFAxPbI3 quantum dot solar cells with reduced phase segregation

Mengmeng Hao et al.

NATURE ENERGY (2020)

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Temperature-Controlled Fragmentation and Ripening: Synthesis of ZnSe Nanorods with Variable Dimensions and Crystal Structure Starting from Ultrathin ZnSe Nanowires

Jiajia Ning et al.

CHEMISTRY OF MATERIALS (2020)

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Article Chemistry, Physical

Efficient Blue-Light-Emitting Cd-Free Colloidal Quantum Well and Its Application in Electroluminescent Devices

Sungwoo Kim et al.

CHEMISTRY OF MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Controlled Synthesis of Ag2Te@Ag2S Core-Shell Quantum Dots with Enhanced and Tunable Fluorescence in the Second Near-Infrared Window

Yejun Zhang et al.

SMALL (2020)

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Article Materials Science, Multidisciplinary

Piezo-phototronic effect enhanced polarization-sensitive photodetectors based on cation-mixed organic-inorganic perovskite nanowires

Laipan Zhu et al.

MATERIALS TODAY (2020)

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Review Chemistry, Multidisciplinary

A-Site Cation Engineering of Metal Halide Perovskites: Version 3.0 of Efficient Tin-Based Lead-Free Perovskite Solar Cells

Weiyin Gao et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Physical

Reversible Z-Type to L-Type Ligand Exchange on Zinc-Blende Cadmium Selenide Nanoplatelets

Haochen Sun et al.

CHEMISTRY OF MATERIALS (2020)

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Article Environmental Sciences

Transfer and bioaccumulation of mercury from soil in cowpea in gold mining sites

Jose Marrugo-Negrete et al.

CHEMOSPHERE (2020)

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Article Chemistry, Multidisciplinary

Low-Dimensional Semiconductors in Artificial Photosynthesis: An Outlook for the Interactions between Particles/Quasiparticles

Hui Wang et al.

ACS CENTRAL SCIENCE (2020)

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THIN SOLID FILMS (2015)

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Formamidinium tin-based perovskite with low E-g for photovoltaic applications

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Solution-Processable Ultrathin Size- and Shape-Controlled Colloidal Cu2-xS Nanosheets

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Influence of Shape on the Surface Plasmon Resonance of Tungsten Bronze Nanocrystals

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Photoluminescence of Band Gap States in AgInS2 Nanoparticles

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Synthesis of Ultrathin and Thickness-Controlled Cu2-xSe Nanosheets via Cation Exchange

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Hydrophobic Anticancer Drug Delivery by a 980 nm Laser-Driven Photothermal Vehicle for Efficient Synergistic Therapy of Cancer Cells In Vivo

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Enhancing the efficiency of SnS solar cells via band-offset engineering with a zinc oxysulfide buffer layer

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JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2013)

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Polarization Properties of Semiconductor Nanorod Heterostructures: From Single Particles to the Ensemble

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CHEMICAL REVIEWS (2012)

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Synthesis and Magnetic Properties of FePt@MnO Nano-heteroparticles

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CRYSTENGCOMM (2012)

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ENERGY & ENVIRONMENTAL SCIENCE (2012)

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Prediction of Methyl Mercury Uptake by Rice Plants (Oryza sativa L.) Using the Diffusive Gradient in Thin Films Technique

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Shape and property control of Mn doped ZnSe quantum dots: from branched to spherical

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Seed-catalyzed heteroepitaxial growth and nonlinear optical properties of zinc selenide nanowires

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Activation of plasmons and polarons in solar control cesium tungsten bronze and reduced tungsten oxide nanoparticles

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Highly Luminescent CuInS2/ZnS Core/Shell Nanocrystals: Cadmium-Free Quantum Dots for In Vivo Imaging

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

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Controlled synthesis of oriented single-crystal ZnO nanotube arrays on transparent conductive substrates

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APPLIED PHYSICS LETTERS (2008)

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CHEMISTRY-A EUROPEAN JOURNAL (2008)

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JOURNAL OF MATERIALS CHEMISTRY (2008)

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JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY (2008)

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Twin-related branching of solution-grown ZnSe nanowires

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Highly polarized photoluminescence and photodetection from single indium phosphide nanowires

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