Oxidation of a-C-H bonds in alkyl aromatics with O2 catalyzed by highly dispersed cobalt(II) coordinated in confined reaction channel of porphyrin-based POFs with simultaneously enhanced conversion and selectivity

Article Energy & Fuels

Cumene autooxidation to cumene hydroperoxide based on a gas-liquid microdispersion strategy

Yuheng Lu et al.

Summary: Microfluidics was used to enhance non-catalytic cumene oxidation process, leading to improved conversion and selectivity with shortened reaction time.

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION (2022)

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Article Engineering, Environmental

MnO2 nanoparticles supported on CNTs for cumene oxidation: Synergistic effect and kinetic modelling

Yuchan Deng et al.

Summary: The synergistic effects between carbon materials and metal oxides play a significant role in the selective oxidation of hydrocarbons. In this study, MnO2/CNTs catalysts were prepared and used in the cumene oxidation reaction, showing high conversion and selectivity. The interaction between MnO2 nanoparticles and CNTs was found to facilitate the decomposition of cumene hydroperoxide, leading to enhanced activity and tunable selectivity of products.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Staged oxidation of hydrocarbons with simultaneously enhanced conversion and selectivity employing O2 as oxygen source catalyzed by 2D metalloporphyrin-based MOFs possessing bimetallic active centers

Hai-Min Shen et al.

Summary: This study achieved efficient and selective oxidation of hydrocarbons with oxygen using 2D metal-organic frameworks with bimetallic active centers. The catalytic performance was significantly improved, and the staged oxidation paths and catalytic mechanism were systematically explored. This work provides valuable reference for selective and efficient oxidative functionalization of hydrocarbons and other important chemical transformations.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Chemical

Relay catalysis of hydrocarbon oxidation using O2 in the confining domain of 3D metalloporphyrin-based metal-organic frameworks with bimetallic catalytic centers

Hai -Min Shen et al.

Summary: In this study, 3D MOFs with bimetallic centers were used to achieve efficient and selective oxidation of hydrocarbons. The performance of the catalyst was significantly improved, leading to increased conversion and selectivity towards partial oxidation products. The use of confining domains and relay catalysis sites in the MOFs played a crucial role in enhancing the oxidation process.

CHEMICAL ENGINEERING SCIENCE (2022)

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Article Chemistry, Applied

High dimensionally structured W-V oxides as highly effective catalysts for selective oxidation of toluene

Toru Murayama et al.

Summary: The high dimensionally structured W-V-O catalysts (HDS-WVO) synthesized by hydrothermal method showed excellent catalytic performance for the selective oxidation of toluene to benzoic acid. The Cs+ ion exchange significantly decreased the catalytic activity of HDS-WVO, indicating that toluene oxidation takes place at the heptagonal channel site.

CATALYSIS TODAY (2021)

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Article Chemistry, Applied

Bimetallic oxide nanoparticles confined in ZIF-67-derived carbon for highly selective oxidation of saturated C-H bond in alkyl arenes

Cheng Huang et al.

Summary: A series of ZIF-derived porous carbon catalysts encapsulated with bimetallic oxide nanoparticles were prepared and showed outstanding performance in the selective oxidation of C-H bonds in alkyl arenes, due to their unique structure promoting mass transfer and molecular oxygen activation, resulting in high conversion and selectivity. This work also provides a novel strategy for the controllable synthesis of MOFs-derived carbon catalysts for enhanced performance in heterogeneous catalysis.

APPLIED ORGANOMETALLIC CHEMISTRY (2021)

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Article Chemistry, Physical

Efficient aerobic oxidation of ethylbenzene accelerated by cu species in hydrotalcite

Xuan Dai et al.

Summary: The CuMgAl hydrotalcite is developed as an efficient catalyst for the aerobic oxidation of ethylbenzene to acetophenone in the presence of NHPI. The reaction is first-order over CuMgAl-LDH, and the catalyst accelerates both the conversion of ethylbenzene and the transformation of the alcohol intermediate to ketone. The positive effect of the catalyst's surface basicity on the reaction has been observed.

CATALYSIS COMMUNICATIONS (2021)

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Article Chemistry, Physical

New Understanding of Selective Aerobic Oxidation of Ethylbenzene Catalyzed by Nitrogen-doped Carbon Nanotubes

Yongzhao Su et al.

Summary: In this study, nitrogen doped carbon nanotubes were used as catalysts for the oxidation of ethylbenzene. Surprisingly, the catalytic performance was suppressed, contrary to expectations based on previous studies. Mechanistic investigations revealed that nitrogen doping inhibited radical propagation, and the addition of TBHP helped to promote it.

CHEMCATCHEM (2021)

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Article Chemistry, Physical

Efficient oxidation of cycloalkanes with simultaneously increased conversion and selectivity using O2 catalyzed by metalloporphyrins and boosted by Zn(AcO)2: A practical strategy to inhibit the formation of aliphatic diacids

Hai-Min Shen et al.

Summary: The study investigated the direct sources of aliphatic acids in cycloalkanes oxidation and adopted a strategy to suppress their formation. By enhancing the transformation of oxidation intermediates and delaying the emergence of cycloalkanones, the conversion of cycloalkanes and selectivity towards specific products were simultaneously increased.

APPLIED CATALYSIS A-GENERAL (2021)

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Article Chemistry, Physical

Efficient catalytic oxidation of primary benzylic C-H bonds with molecular oxygen catalyzed by cobalt porphyrins and N-hydroxyphthalimide (NHPI) in supercritical carbon dioxide

Wei-Jie Hu et al.

Summary: An efficient protocol for the oxidation of primary benzylic C-H bonds using cobalt porphyrin and NHPI in scCO2 was established in this study, showing good tolerance towards different substrates and proposing a mechanism involving free radicals and high-valence cobalt species.

CATALYSIS COMMUNICATIONS (2021)

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Article Materials Science, Multidisciplinary

Synthesis and characterization of highly dispersed cobaltous silicate as a catalyst for selective oxidation of toluene to benzaldehyde

Sihao Xu et al.

Summary: Heterogenization of CoOx/SiO2 catalysts is crucial for their separation, recovery and reuse. The catalysts showed outstanding textural and structural properties in the selective oxidation of toluene to benzaldehyde, with high conversion rates and selectivity. The reaction proceeded via a free radical mode, and the catalysts exhibited stable reusability, indicating promising industrial application prospects.

MATERIALS CHEMISTRY AND PHYSICS (2021)

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Article Chemistry, Physical

Microporous cobaltporphyrin covalent polymer mediated Co3O4@PNC nanocomposites for efficient catalytic C-H bond activation

Mingyang Tan et al.

Summary: The Cobalt porphyrin conjugated porous polymer (Co/PCP) was obtained by hybrid polymerization, carbonized at 400 degrees C to form Co3O4@PNC-400 catalyst, which exhibited high catalytic activity for C-H oxidation reactions with significant synergistic effect between Co3O4 and nitrogen-carbon framework.

APPLIED CATALYSIS A-GENERAL (2021)

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Article Chemistry, Physical

A tetra-cationic tetrapyridinoporphyrazinato Iron(II) grafted onto sulfonated SBA-15 as a novel heterogeneous catalyst for the aerobic oxidation of C(sp3)-H bonds in alkanes

Saeedeh Zahedi et al.

Summary: Researchers have successfully synthesized a catalyst of iron (II) tetramethylated tetrapyridinoporphyrazine grafted onto sulfonated SBA-15, which showed efficient C-H oxidation reaction capability in water and good reusability for at least 5 cycles.

APPLIED SURFACE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Oxidase Mimetic Activity of a Metalloporphyrin-Containing Porous Organic Polymer and Its Applications for Colorimetric Detection of Both Ascorbic Acid and Glutathione

Ding Guo et al.

Summary: The selective detection of ascorbic acid (AA) and glutathione (GSH) was achieved by preparing a metalloporphyrin-containing porous organic framework (Co-POP), which showed high oxidase-like activity. The colorimetric assay established with Co-POP allowed for sensitive detection of AA and GSH with low detection limits, showing great potential for biocatalysis and biosensing applications.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Physical

Fe assisted Co-containing hydrotalcites catalyst for the efficient aerobic oxidation of ethylbenzene to acetophenone

Weiyou Zhou et al.

Summary: Different cations in Co-containing hydrotalcites have significant effects on catalytic performance, with Co2Fe-LDH exhibiting the highest activity. The synergistic effect between Co and Fe species enhances the catalytic oxidation, leading to high selectivity and conversion rates in the aerobic oxidation of ethylbenzene to acetophenone. The proposed mechanisms suggest that electron transfer between Co and Fe species plays a crucial role in the reaction.

APPLIED CATALYSIS A-GENERAL (2021)

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Article Engineering, Chemical

Selective Aerobic Oxidation of Toluene in the Presence of Co2+ and Task-Specific Organic Salts, Including Ionic Liquids

Dawid Lisicki et al.

Summary: This research demonstrated that systems composed of transition-metal compounds and organic bromide salts catalyze the oxidation of toluene and its derivatives with high selectivities and reaction rates. It was also found that organic salts containing nitrogen atoms have an inhibitory effect on the corrosion caused by Br- ions in the reaction system, showing the potential for replacing industrial-scale inorganic bromides with organic bromide salts for corrosion inhibition.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Room Temperature Aerobic Peroxidation of Organic Substrates Catalyzed by Cobalt(III) Alkylperoxo Complexes

Yunzhou Chen et al.

Summary: The study introduces a new series of cobalt complexes that function as efficient catalysts for aerobic peroxidation of hydrocarbons at room temperature, offering a potential solution to the challenge of room temperature aerobic oxidation of hydrocarbons.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Covalent anchoring of N-hydroxyphthalimide on silica via robust imide bonds as a reusable catalyst for the selective aerobic oxidation of ethylbenzene to acetophenone

Guojun Shi et al.

Summary: The study demonstrates that the immobilized NHPI catalyst on SiO2 can efficiently catalyze the aerobic oxidation of ethylbenzene and shows good reusability. This research provides a new approach to convert organic compounds with benzylic C-H bonds into oxygenated value-added products.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Physical

Confinement of Au3+-rich clusters by using Silicalite-1 for selective solvent-free oxidation of toluene

He Huang et al.

Summary: Selective oxidation of primary carbon-hydrogen bonds in toluene to form benzaldehyde was successfully achieved using a novel catalyst design. The synergistic catalysis between Au-0 and Au3+ species in the catalyst played a crucial role in the oxidation and desorption of benzaldehyde.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Solvent-Free Aerobic Oxidation of Ethylbenzene Promoted by NHPI/Co(II) Catalytic System: The Key Role of Ionic Liquids

Gabriela Dobras et al.

CHEMCATCHEM (2020)

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Article Chemistry, Physical

Hydrophobic Modification of Microenvironment of Highly Dispersed Co3O4 Nanoparticles for the Catalytic Selective Oxidation of Ethylbenzene

Li Zhao et al.

CHEMCATCHEM (2020)

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Article Chemistry, Multidisciplinary

A Supported Bismuth Halide Perovskite Photocatalyst for Selective Aliphatic and Aromatic C-H Bond Activation

Yitao Dai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Physical

Synthesis of three-dimensional nitrogen doped meso/macroporous carbon beads for heterogeneous catalytic solvent-free oxidation of ethylbenzene

Zhe Wang et al.

CARBON (2020)

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Article Chemistry, Multidisciplinary

Non-Heme-Type Ruthenium Catalyzed Chemo- and Site-Selective C-H Oxidation

Daiki Doiuchi et al.

CHEMISTRY-AN ASIAN JOURNAL (2020)

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Article Chemistry, Organic

Selective Oxidation of Benzylic C-H Bonds Catalyzed by Cu(II)/{PMo12}

Peihe Li et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

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Review Multidisciplinary Sciences

Designing for a green chemistry future

Julie B. Zimmerman et al.

SCIENCE (2020)

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Article Chemistry, Physical

Visible-Light-Driven Selective Oxidation of Toluene into Benzaldehyde over Nitrogen-Modified Nb2O5 Nanomeshes

Kaiyi Su et al.

ACS CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Porous Organic Frameworks Featured by Distinct Confining Fields for the Selective Hydrogenation of Biomass-Derived Ketones

Yajie Yang et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Physical

Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C-H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with N-Hydroxyphthalimide

Hai-Min Shen et al.

CATALYSIS LETTERS (2020)

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Article Chemistry, Inorganic & Nuclear

Cobalt(II) Bipyrazolate Metal-Organic Frameworks as Heterogeneous Catalysts in Cumene Aerobic Oxidation: A Tag-Dependent Selectivity

Anna Nowacka et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

AgNPs Immobilized over Functionalized 2D Hexagonal SBA-15 for Catalytic C-H Oxidation of Hydrocarbons with Molecular Oxygen under Solvent-Free Conditions

Rima Biswas et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

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Article Chemistry, Multidisciplinary

Sustainable Oxidation of Cyclohexane and Toluene in the Presence of Affordable Catalysts: Impact of the Tandem of Promoter/Oxidant on Process Efficiency

Alexander Pokutsa et al.

ACS OMEGA (2020)

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Article Chemistry, Physical

Efficient and selective oxidation of tertiary benzylic C-H bonds with O2 catalyzed by metalloporphyrins under mild and solvent-free conditions

Hai-Min Shen et al.

APPLIED CATALYSIS A-GENERAL (2020)

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Article Chemistry, Physical

Highly enantioselective undirected catalytic hydroxylation of benzylic CH2 groups with H2O2

Roman Ottenbacher et al.

JOURNAL OF CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Catalytic oxidation of cycloalkanes by porphyrin cobalt(II) through efficient utilization of oxidation intermediates

Hai M. Shen et al.

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES (2020)

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Article Chemistry, Physical

An Enantioconvergent Benzylic Hydroxylation Using a Chiral Aryl Iodide in a Dual Activation Mode

Ayham H. Abazid et al.

ACS CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Intrinsic Activity of Metal Centers in Metal-Nitrogen-Carbon Single-Atom Catalysts for Hydrogen Peroxide Synthesis

Chang Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Mechanism of Ni-Catalyzed Oxidations of Unactivated C(sp3)-H Bonds

Yehao Qiu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Catalytic oxidation of alcohols and alkyl benzenes to carbonyls using Fe3O4@SiO2@(TEMPO)-co-(Chlorophyll-CoIII) as a bi-functional, self-co-oxidant nanocatalyst

Boshra Mahmoudi et al.

GREEN CHEMISTRY (2020)

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Article Chemistry, Physical

A series of highly stable porphyrinic metal-organic frameworks based on iron-oxo chain clusters: design, synthesis and biomimetic catalysis

Gang Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

Selective oxygenation of unactivated C-H bonds by dioxygen via the autocatalytic formation of oxoiron(v) species

Bittu Chandra et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Physical

Trace amounts of Cu(OAc)2 boost the efficiency of cumene oxidation catalyzed by carbon nanotubes washed with HCl

Jie Deng et al.

CATALYSIS SCIENCE & TECHNOLOGY (2020)

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Article Chemistry, Multidisciplinary

Light and oxygen-enabled sodium trifluoromethanesulfinate-mediated selective oxidation of C-H bonds

Xianjin Zhu et al.

GREEN CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Acetylacetone as an oxygen activator to improve efficiency for aerobic oxidation of toluene and its derivatives by using cobaltmeso-tetraphenylporphyrin

Xian-Tai Zhou et al.

NEW JOURNAL OF CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Template-free synthesis of graphene-like carbons as efficient carbocatalysts for selective oxidation of alkanes

Xiang Hu et al.

GREEN CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Designed Synthesis of a 2D Porphyrin-Based sp2 Carbon-Conjugated Covalent Organic Framework for Heterogeneous Photocatalysis

Rufan Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Engineering, Chemical

Highly Dispersed Manganese Based Mn/N-C/Al2O3 Catalyst for Selective Oxidation of the C-H Bond of Ethylbenzene

Wan-Fei Xu et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

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Article Chemistry, Multidisciplinary

Selective Aerobic Oxidation of Cumene to Cumene Hydroperoxide over Mono- and Bimetallic Trimesate Metal-Organic Frameworks Prepared by a Facile Green Aqueous Synthesis

Anna Nowacka et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Chemistry, Physical

Green oxidation of cyclohexane catalyzed by recyclable magnetic transition-metal silica coated nanoparticles

Nuno M. R. Martins et al.

CATALYSIS COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Electron Transfer Control of Reductase versus Monooxygenase: Catalytic C-H Bond Hydroxylation and Alkene Epoxidation by Molecular Oxygen

Manjistha Mukherjee et al.

ACS CENTRAL SCIENCE (2019)

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Article Chemistry, Physical

Hydrotalcite-derived Co-MgAlO mixed metal oxides as efficient and stable catalyst for the solvent-free selective oxidation of cyclohexane with molecular oxygen

Peng Liu et al.

MOLECULAR CATALYSIS (2019)

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Article Chemistry, Inorganic & Nuclear

Catalytic and stoichiometric C-H oxidation of benzylalcohols and hydrocarbons mediated by nonheme oxoiron(IV) complex with chiral tetrapyridyl ligand

Dora Lakk-Bogath et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2019)

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Article Materials Science, Multidisciplinary

The influence of encapsulated cobalt content within N-doped bamboo-like carbon nanotubes catalysts for arylalkanes oxidation

Xiaocan Wang et al.

MATERIALS CHEMISTRY AND PHYSICS (2019)

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Article Engineering, Chemical

Selective Oxidation of Cumene to the Equivalent Amount of Dimethylbenzyl Alcohol and Cumene Hydroperoxide

Man Yang et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

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Article Chemistry, Multidisciplinary

Solvent-Free Melting-Assisted Pyrolysis Strategy Applied on the Co/N Codoped Porous Carbon Catalyst

Lushuang Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Chemistry, Multidisciplinary

A Sustainable Approach for the Synthesis of Catalytically Active Peroxidase-Mimic ZnS Catalysts

Camilla M. Cova et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Materials Science, Biomaterials

A hollow microshuttle-shaped capsule covalent organic framework for protein adsorption

Zhixiang Lu et al.

JOURNAL OF MATERIALS CHEMISTRY B (2019)

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Article Chemistry, Physical

Exfoliation of amorphous phthalocyanine conjugated polymers into ultrathin nanosheets for highly efficient oxygen reduction

Wenping Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

Enhancing catalytic aerobic oxidation performance of cyclohexane via size regulation of mixed-valence {V16} cluster-based metal-organic frameworks

Shuang Wang et al.

NEW JOURNAL OF CHEMISTRY (2019)

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Article Chemistry, Physical

Synergistic effect between Cu-Cr bimetallic oxides supported on g-C3N4 for the selective oxidation of toluene to benzaldehyde

Cai Xu et al.

CATALYSIS SCIENCE & TECHNOLOGY (2019)

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Article Chemistry, Physical

Aerobic selective oxidation of methylaromatics to benzoic acids over Co@N/Co-CNTs with high loading CoN4 species

Bingfeng Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

Aerobic oxidation of the C-H bond under ambient conditions using highly dispersed Co over highly porous N-doped carbon

Renfeng Nie et al.

GREEN CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

A Cooperative Effect in a Novel Bimetallic Mo-V Nanocomplex Catalyzed Selective Aerobic C-H Oxidation

Hasan Tavallaei et al.

ACS OMEGA (2019)

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Article Chemistry, Physical

Aerobic oxidation of alkylaromatic hydrocarbons to hydroperoxides catalysed by N-hydroxyimides in ionic liquids as solvents

Gabriela Dobras et al.

APPLIED CATALYSIS A-GENERAL (2018)

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Article Chemistry, Physical

Montmorillonite-assisted synthesis of cobalt-nitrogen-doped carbon nanosheets for high-performance selective oxidation of alkyl aromatics

Shanshan Jie et al.

APPLIED SURFACE SCIENCE (2018)

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Article Engineering, Chemical

Catalyst-free and solvent-free oxidation of cycloalkanes (C5-C8) with molecular oxygen: Determination of autoxidation temperature and product distribution

Haimin Shen et al.

CHINESE JOURNAL OF CHEMICAL ENGINEERING (2018)

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Article Chemistry, Organic

Highly Efficient Catalytic Oxidation of Inert C(sp3)-H Bonds by the Synergistic Effect of Copper Nanoparticles/N-Doped Graphene

Wei Sun et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Arylruthenium(III) Porphyrin-Catalyzed C-H Oxidation and Epoxidation at Room Temperature and [Ru-v(Por)(O)(Ph)] Intermediate by Spectroscopic Analysis and Density Functional Theory Calculations

Ka-Pan Shing et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Oxidation of p-toluic acid to terephthalic acid via a bromine-free process using nano manganese and manganese-copper mixed oxides

Mohamed A. Betiha et al.

NEW JOURNAL OF CHEMISTRY (2018)

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Synthesis, characterization, and reactivity of a chiral Fe(iv)-oxo complex bearing an l-proline-derived aminopyridine ligand

Junyi Du et al.

NEW JOURNAL OF CHEMISTRY (2018)

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Efficient and Selective Uptake of TcO4- by a Cationic Metal-Organic Framework Material with Open Ag+ Sites

Daopeng Sheng et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2017)

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The E factor 25 years on: the rise of green chemistry and sustainability

Roger A. Sheldon

GREEN CHEMISTRY (2017)

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3D Porphyrin-Based Covalent Organic Frameworks

Guiqing Lin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Multidisciplinary

Identifying the Recognition Site for Selective Trapping of 99TcO4- in a Hydrolytically Stable and Radiation Resistant Cationic Metal-Organic Framework

Lin Zhu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Physical

Co-SBA-15-Immobilized NDHPI as a New Composite Catalyst for Toluene Aerobic Oxidation

Xingxing Li et al.

CATALYSIS LETTERS (2017)

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Article Engineering, Environmental

Manganese-containing hollow TS-1: Description of the catalytic sites and surface properties for solvent -free oxidation of ethylbenzene

Mengqiao Liu et al.

CHEMICAL ENGINEERING JOURNAL (2017)

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Article Chemistry, Physical

A New Method for Immobilization of NDHPI on SBA-15 Carrier Used as Catalyst for Selective Oxidation of Toluene

Meng Zhou et al.

CATALYSIS LETTERS (2016)

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Article Chemistry, Physical

Synthesis of acetophenone from aerobic catalytic oxidation of ethylbenzene over Ti-Zr-Co alloy catalyst: Influence of annealing conditions

Tong Liu et al.

APPLIED CATALYSIS A-GENERAL (2016)

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Article Chemistry, Multidisciplinary

Metalation of a Mesoporous Three-Dimensional Covalent Organic Framework

Luke A. Baldwin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Physical

In situ-created Mn(III) complexes active for liquid-phase oxidation of alkylaromatics to aromatic ketones with molecular oxygen

Yasutaka Kuwahara et al.

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A 2D porous porphyrin-based covalent organic framework for sulfur storage in lithium sulfur batteries

Huaping Liao et al.

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Article Engineering, Environmental

Silylated MgAl LDHs intercalated with MnO2 nanowires: Highly efficient catalysts for the solvent-free aerobic oxidation of ethylbenzene

Wenmiao Lv et al.

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Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation

Jinqiao Dong et al.

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Construction of Ultrastable Porphyrin Zr Metal-Organic Frameworks through Linker Elimination

Dawei Feng et al.

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Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts

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Oxidation of a-C-H bonds in alkyl aromatics with O2 catalyzed by highly dispersed cobalt(II) coordinated in confined reaction channel of porphyrin-based POFs with simultaneously enhanced conversion and selectivity

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