4.6 Article

Insights into pathways and solvent effects of fructose dehydration to 5-hydroxymethylfurfural in acetone-water solvent

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CHEMICAL ENGINEERING SCIENCE
卷 267, 期 -, 页码 -

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2022.118352

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Biomass conversion; 5-hydroxymethylfurfural; Reaction pathways; Solvent effects

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In this study, the effects of acetone-water solvent on HMF production were investigated using experimental and theoretical methods. It was found that water increases substrate concentration and accelerates reaction rate through intermolecular hydrogen transfer, while acetone increases the population of high-reactive fructofuranose isomers, thus improving HMF yield. Therefore, water and acetone play a synergistic role in HMF preparation.
Preparation of 5-hydroxymethylfurfural (HMF) from fructose is a typical liquid-phase biomass conver-sion reaction, strongly affected by solvent media and acid catalysts, including fructose reactivity and HMF selectivity. Most works on solvent selection were conducted experimentally, however, lack of the-oretical guidance. Herein, we applied experimental and theoretical techniques to investigate solvent effects of acetone-water solvent on HMF production. Factors including product distribution, key interme-diate and byproduct identification, reaction pathways, and solvation simulation of solutes were system-atically evaluated. The results indicate that water ensures high substrate concentration and assists intermolecular hydrogen transfer to accelerate reaction rate. Various HMF degradation reactions are introduced in the presence of water, however, are significantly inhibited by acetone. Moreover, acetone increases the population of high-reactive fructofuranose isomers, thus improving HMF yield. Therefore, water and acetone play a synergistic role in HMF preparation. Also, our findings provide theoretical insights for solvent selection and methodology for studying solvent effects. (c) 2022 Published by Elsevier Ltd.

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