期刊
CHEMICAL ENGINEERING SCIENCE
卷 270, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2023.118494
关键词
S-modified Cu and Pd catalysts; Electronic and geometric effects; Active site structure; Spatial scale
This study investigates the influences of S atom and nanoparticle size in the S-modified Cu and Pd nanoparticle catalysts on C2H2 semi-hydrogenation performance. It is found that Cu-S catalysts exhibit higher C2H4 selectivity but lower C2H4 formation rate compared to Pd-S catalysts. The S-modified M catalysts enhance C2H4 selectivity due to the geometric and electronic effects. The larger nanoparticle size of Cu(111)-S catalyst is more suitable for C2H2 semi-hydrogenation. Therefore, the catalytic performance of C2H2 semi-hydrogenation can be regulated by controlling the electronic and geometric effects of S-modified metal catalysts through tuning the nanoparticle size and spatial scale of active site induced by S atoms.
To reveal the influences of S atom and nanoparticle size in the S-modified Cu and Pd (Cu-S and Pd-S) nanoparticle catalysts on C2H2 semi-hydrogenation performance, the S-modified Mn (M = Cu and Pd, n = 13, 38, 55) catalysts and the periodic M(1 1 1) surface representing much larger size of nanoparticle were constructed to examine C2H2 semi-hydrogenation. The results showed that C2H4 selectivity over Cu-S catalysts is higher than that over Pd-S catalysts, while C2H4 formation rate is lower over Cu-S cat-alysts. Compared with the pure M catalysts, the S-modified M catalysts enhance C2H4 selectivity due to the geometric and electronic effects. The screened larger nanoparticle size of Cu(1 1 1)-S catalyst is more suitable for C2H2 semi-hydrogenation. Hence, the electronic and geometric effects of S-modified metal catalysts can be controlled by tuning the nanoparticle size and spatial scale of active site induced by S atoms, then, the catalytic performance of C2H2 semi-hydrogenation could be regulated.(c) 2023 Elsevier Ltd. All rights reserved.
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