4.7 Article

A pectocellulosic bioplastic from fruit processing waste: robust, biodegradable, and recyclable

期刊

CHEMICAL ENGINEERING JOURNAL
卷 463, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2023.142452

关键词

?Top-down? strategy; Pectocellulosic bioplastics; Biodegradable; Recyclable; Antioxidant Activity

向作者/读者索取更多资源

Recyclable and biodegradable bioplastics made from biomass resources, specifically citrus peels, have been developed using a novel top-down strategy. The bioplastics show excellent mechanical properties, easy recycling, and rapid biodegradation due to the lamellae structure formed by cross-linked pectin and cellulose micro/nanofibers. The pectocellulosic bioplastics also exhibit water stability, water vapor barrier properties, and antioxidant activity, making them potential substitutes for petrochemical-derived plastics in active food packaging.
Recyclable and biodegradable bioplastics made from biomass resources are urgently needed to combat the massive amount plastic packaging waste generated by the food sector. Herein, a novel top-down strategy is demonstrated for obtaining high-performance pectocellulosic bioplastics from fruit processing waste, specifically citrus peels rich in pectin and cellulose. The pectin, cellulose and lignin in citrus peels were separated, then the pectin and cellulose components recombined to form a pectin-cellulose film-forming slurry for casting into films. After the cast films had dried, they were then immersed in a CaCl2 solution to crosslink the pectin chains. The obtained pectocellulosic bioplastic films possessed a dense lamellae structure due to inter/intra-molecular entanglement between the cross-liked pectin and cellulose micro/nanofibers, offering excellent mechanical properties, easy recycling and rapid biodegradation. Additionally, this pectocellulosic bioplastic exhibited excellent water stability, water vapor barrier properties, and antioxidant activity. Importantly, the same protocol was applicable for the manufacture of bioplastics from other pectin-and cellulose-rich biomass raw materials (such as watermelon rind, pineapple rind and cantaloupe rind). From both an ecological and economic view-point, this biomass-derived bioplastics synthesized in this work offer potential as substitutes for petrochemical-derived plastics in many fields, especially active food packaging.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据