期刊
CHEMICAL ENGINEERING JOURNAL
卷 465, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2023.142928
关键词
Lithium-rich cathode materials; Oxygen defect; Anionic redox; Energy band structure
In this study, uniform oxygen defects were injected into the surface region of Li1.2Ni0.13Co0.13Mn0.54O2 to improve its electrochemical performance, resulting in high initial coulombic efficiency, outstanding capacity retention, and low voltage decay.
Lithium-rich layered cathode materials are considered to be research focus of cathode candidates for next-generation lithium-ion batteries due to their high specific capacity and low cost. However, lattice deoxidation associated with elemental migration and internal local shrinkage usually results in deteriorated cyclic perfor-mance and notorious voltage attenuation, severely limiting its application. In this paper, we have successfully injected uniform oxygen defects into surface region of Li1.2Ni0.13Co0.13Mn0.54O2 primary particles under the high-pressure and weak carbonate environment. Various experimental investigations indicate that the injected robust oxygen defects can not only mitigate detrimental interfacial reactions but also suppress unfavorable lattice variation and particle breakage. More importantly, theoretical calculations unravel the critical roles of oxygen defects in regulating energy band structure for strengthened anionic reversibility. Owing to stabilization effects of unique oxygen defect engineering, the modified Li1.2Ni0.13Co0.13Mn0.54O2 cathode has harvested dramatically enhanced electrochemical performance including a high initial coulombic efficiency of 96.6%, an outstanding capacity retention of 91.96% (1C, 200 cycles) and suppressed voltage decay of only 1.62 mV per cycle. There-fore, this facile and effective defect engineering strategy could establish new guidance for promoting practical application of Li-rich Mn-based cathode material.
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