期刊
CEMENT AND CONCRETE RESEARCH
卷 78, 期 -, 页码 179-189出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.cemconres.2015.07.005
关键词
Magnesium phosphate cement (MPC); Hydration temperature; Hydration products; Strength; Setting time
资金
- National Natural Science Foundation of China [51461135003, 51272283]
- Chongqing Science and Technology Commission - China [cstc2012jjB50009]
This paper investigates the effect of early hydration temperatures on hydration products and strength development of magnesium phosphate cement (MPC). MPC paste specimens with borate contents of 3%, 6%, 9% and 12% are prepared and cured in different air temperatures and in the adiabatic condition. The internal hydration temperatures are measured by pre-embedded temperature probes. MPC samples with different hydration temperatures are also obtained by using thin slice samples. The hydration products in MPC samples with different hydration temperatures are analyzed by X-ray diffractometer (XRD) and scanning electron microscope (SEM) and the strength development is also measured. The results show that NH4MgPO4 center dot 6H(2)O is the major hydration product and beneficial to strength development of MPC at hydration temperature below 70 degrees C. NH4MgPO4 center dot H2O is another major product, which significantly decreases the strength, when the temperature is higher than a critical temperature between 70 degrees C and 75 degrees C. NH4MgPO4 center dot H2O can directly form in the MPC paste, and comes from the decomposition of NH4MgPO4 center dot 6H(2)O when the temperature is above 75 degrees C. With temperature elevation and duration extension, NH4MgPO4 center dot 6H(2)O decomposes rapidly, and even entirely when the temperature is above 100 degrees C. The borate content has no effect on the types of major hydration products and the critical temperature. (C) 2015 Elsevier Ltd. All rights reserved.
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