期刊
CHEMICAL ENGINEERING JOURNAL
卷 461, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2023.141974
关键词
Electrochromic energy storage; D-A conjugated polymers; Molecular structure; Electropolymerized; Triphenylamine; High performance
This study designs and synthesizes three novel triphenylamine-based organic monomers to obtain three polymer films with different color switching abilities by electrochemical polymerization. The polymer pPh-4TPA shows a large optical contrast of 80.5% and a high coloration efficiency of 277.21 cm2.C-1 in the visible region, as well as high specific capacitance, high capacity, and excellent rate performance. The assembled asymmetric electrochromic energy storage devices based on pPh-4TPA polymer films exhibit the highest energy and power densities among pure organic electrochromic pseudocapacitors reported, along with reversible color changes during charging and discharging.
Multifunctional intelligent electrochromic energy storage with real-time monitoring of energy storage level by color change has become the extremely attractive researches for the development of electrochemical energy storage systems. Herein, three novel triphenylamine-based organic monomers with star-shaped donor-acceptor structure are designed and synthesized to successfully obtain the corresponding three polymer films with different and rich color switching by electrochemical polymerization via the coupling between peripheral tri-phenylamine groups. Based on these three polymer films as the electrodes, a fast switching electrochromic property with a large optical contrast of 80.5 % in the visible region and a high coloration efficiency of 277.21 cm2.C- 1, which are one of the best results among TPA-based electrochromic materials, is achieved for the polymer pPh-4TPA with the pyrazino[2,3-g]quinoxaline acceptor core. Meanwhile, pPh-4TPA also shows high specific capacitance of up to 423F.g(-1) (475F.cm(-3)), high capacity of 115.3 mAh.g(-1) and unparalleled rate performance. The assembled asymmetric electrochromic energy storage devices based on pPh-4TPA polymer films exhibited maximum energy density of 105.12 Wh.kg(-1) (107 mWh.cm(-3)) and power density of 45 kW.kg(-1) (45.9 W.cm(-3)), which are both the highest energy and power densities among the pure organic electrochromic pseudocapacitors ever reported, simultaneously accompanied by reversible color changes in appearance during charging and discharging process.
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