Upconversion properties of Er, Yb co-doped KBi(MoO4)2 nanomaterials for optical thermometry

Rare earth ions doped upconversion materials have an extensive range of utilizations because of their exceptional luminescence properties. Here, scheelite type Yb3+, Er3+ co-doped KBi(MoO4)2 nanomaterials were produced by means of a conventional co-precipitation method at room temperature with a typical crystallite size of 13 nm. 980 nm excitation aided in the investigation of the concentration and power-dependent upconversion emission. The optimum upconversion emission is obtained with Er and Yb concentrations of 0.035 and 0.125 mol%, respectively in KBi(MoO4)2 nanomaterials. The intensity ratio of upconversion emission bands based on 529 and 551 nm is investigated in the temperature range of 200-550 K and the theoretical function is used for fitting the exploratory information. The absolute sensitivity is found to be of maximum value of 0.0123 K-1, indicating that this double molybdate can be utilized as a potential probe for luminescence-based temperature sensing.

Automated summary

Rare earth ions doped upconversion materials with exceptional luminescence properties were synthesized through a conventional co-precipitation method. The optimized upconversion emission was achieved with Er and Yb concentrations of 0.035 and 0.125 mol%, respectively in KBi(MoO4)2 nanomaterials. The temperature-dependent intensity ratio of upconversion emission bands was investigated, and the maximum absolute sensitivity was found to be 0.0123 K-1, indicating the potential application of this double molybdate as a luminescence-based temperature probe.