Sodium-alginate-laden MXene and MOF systems and their composite hydrogel beads for batch and fixed-bed adsorption of naproxen with electrochemical regeneration

Sodium alginate (SA)-laden two-dimensional (2D) Ti3C2Tx MXene (MX) and MIL-101(Fe) (a type of metal--organic framework (MOF)) composites were prepared and used for the removal of naproxen (NPX), following the adsorption and electrochemical regeneration processes. The fixed-bed adsorption column studies were also conducted to study the process of removal of NPX by hydrogels. The number of interactions via which the MX-embedded SA (MX@SA) could adsorb NPX was higher than the number of pathways associated with NPX adsorption on the MIL-101(Fe)-embedded SA (MIL-101(Fe)@SA), and the MX and MIL-101(Fe) composite embedded SA (MX/MIL-101(Fe)@SA). The optimum parameters for the electrochemical regeneration process were determined: charge passed and current density values were 169.3 C g-1 and 10 mA cm-2, respectively, for MX@SA, and the charge passed and current density values were 16.7 C g-1 and 5 mA cm-2, respectively, for both MIL-101(Fe)@SA and MX/MIL-101(Fe)@SA. These parameters enabled excellent regeneration, consistent over multiple adsorption and electrochemical regeneration cycles. The mechanism for the regeneration of the ma-terials was proposed that the regeneration of MX@SA and MIL-101(Fe)@SA involved the indirect electro-oxidation process in the presence of OH radicals, and the regeneration of MX/MIL-101(Fe)@SA involved the indirect oxidation process in the presence of active chlorine species.

Automated summary

Sodium alginate (SA)-laden two-dimensional Ti3C2Tx MXene and MIL-101(Fe) composite materials were used for the removal of naproxen (NPX) through adsorption and electrochemical regeneration processes. The MX-embedded SA (MX@SA) showed higher NPX adsorption capacity compared to MIL-101(Fe)-embedded SA (MIL-101(Fe)@SA) and MX/MIL-101(Fe) composite embedded SA (MX/MIL-101(Fe)@SA). Optimum parameters for electrochemical regeneration were determined, enabling excellent regeneration over multiple cycles. The regeneration mechanisms involved indirect electro-oxidation and indirect oxidation processes.