Bimetallic (AuAg, AuPd and AgPd) nanoparticles supported on cellulose-based hydrogel for reusable catalysis

Biopolymer-derived hydrogels with low-cost and sustainable features have been considered as fascinating sup-ported materials for metal nanoparticles. Cellulose, as the most abundant biopolymer, is a renewable raw ma-terial to prepare biopolymer-derived hydrogels for catalysis. Here, a cellulose-based hydrogel is designed to load bimetallic (AuAg, AuPd and AgPd) nanoparticles. 4-Nitrophenol reduction and Suzuki-Miyaura coupling re-actions are selected to evaluate and compare the catalytic performance of the resulting bimetallic nanoparticle-loaded cellulose-based composite hydrogels. The bimetallic nanocomposite hydrogels are easy to be recycled over 10 times during the catalytic experiments and possess good applicability and generality for various sub-strates. The catalytic activity of bimetallic nanocomposite hydrogels was compared with recent literatures. In addition, the possible catalytic mechanism is also proposed. This work is expected to give a new insight for designing and preparing bimetallic nanoparticle-based cellulose hydrogels and proves its applicability and prospect in the catalytic field.

Automated summary

A cellulose-based hydrogel is developed to load bimetallic nanoparticles for catalytic reactions. The resulting bimetallic nanocomposite hydrogels exhibit excellent recyclability and applicability for various substrates, showing promising prospects in the catalytic field.