Influence of mineral additives and environmental conditions on the self-healing capabilities of cementitious materials

The effects of the addition of minerals of various compositions (i.e., silica-based materials, chemical expansive agents, swelling minerals and crystalline components) on the self-healing performances of cementitious materials were investigated. The self-healing capabilities were assessed by performing water permeability tests, quantifying the widths of the surface cracks and studying the water absorption of mortars that were pre-cracked by either splitting or compression. The results showed that the cracks that appeared early on healed more efficiently when they were cured in still rather than flowing water. High pHs and high temperatures accelerate crack healing. The healing efficiency can be further improved by utilizing a combination of minerals rather than a single mineral. A self-healing mechanism was discussed by combining these results with micro-observations. The precipitation of calcium carbonate, which is aided by higher pH values and higher calcium ion contents, was found to be the main contributor to the healing of surface cracks. (C) 2014 Elsevier Ltd. All rights reserved.