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Article
Energy & Fuels
Minghao Chen et al.
Summary: The study investigated a combination pretreatment method using hot water and lactic acid to treat reed straw, which demonstrated increased digestibility of lignocellulose and glucose yield. The results highlighted the potential application of this pretreatment technology in the biorefinery industry.
Article
Agricultural Engineering
Zhengyu Tang et al.
BIORESOURCE TECHNOLOGY
(2023)
Article
Agricultural Engineering
Shunli Zhang et al.
Summary: Via combination catalysis with deep eutectic solvent lactic acid:betaine and HMFOMUT cell, an eco-friendly one-pot chemoenzymatic strategy was developed to convert bread waste into 2,5-furandimethanol, achieving high yields. This method has great potential to reduce operating costs and valorize waste food bioresource into value-added furan.
BIORESOURCE TECHNOLOGY
(2023)
Article
Agricultural Engineering
Qing Li et al.
Summary: This study develops an efficient one-pot process for the chemoenzymatic transformation of biobased substrate to 2,5-diformylfuran using deep eutectic solvent (DES) Betaine:Lactic acid ([BA][LA]) catalyst and oxidase biocatalyst. The yields of HMF were 32.8% (15 min) and 91.6% (90 min) at 150 degrees C, using waste bread and D-fructose as feedstocks in [BA][LA]-H2O. The prepared HMF could be biologically oxidized to 2,5-diformylfuran by Escherichia coli pRSFDuet-GOase, achieving a productivity of 0.631 g 2,5-diformylfuran/(g fructose) and 0.323 g 2,5-diformylfuran/(g bread) after 6 h.
BIORESOURCE TECHNOLOGY
(2023)
Article
Biochemistry & Molecular Biology
Maojin Cui et al.
Summary: This study investigates the effect of additives on enzymatic hydrolysis of lignocellulose biomass and finds that the addition of Triton X-100 and Bovine serum albumin can improve the efficiency of enzymatic hydrolysis, particularly Triton X-100. Kinetic studies show that extracted cellulose has a higher initial enzymatic hydrolysis rate.
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY
(2023)
Article
Agricultural Engineering
Laxmi Sharma et al.
Summary: Optimizing alkaline pretreatment and saccharification conditions can enhance saccharification yield of jute biomass. The highest delignification and saccharification were achieved with specific NaOH concentrations, temperature, and enzyme concentrations.
BIORESOURCE TECHNOLOGY
(2023)
Article
Engineering, Environmental
Mengjia Wu et al.
Summary: Researchers applied a novel aqueous solution NaOH/ChCl:TH/water to pretreat sugarcane bagasse at room temperature for a short time, aiming to improve its saccharification efficiency and convert it into adipic acid. The results showed that this pretreatment method was effective in enhancing saccharification efficiency and achieving a high yield of adipic acid.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Agricultural Engineering
Yuting Liu et al.
Summary: In this work, furfural was converted to furoic acid using biological macromolecules and chemical biological catalysts. A heterogeneous catalyst Sn-FS-RH was prepared using fish scale and rice husk as carriers. Different biomasses were transformed into furfural and the highest yield was obtained from corn cob-derived xylose. The by-products formed in the transformation of lignocellulose to furfural had an inhibitory effect on the formation of furoic acid. Escherichia coli HMFOMUT cells could fully transform furfural into furoic acid. This two-step chemoenzymatic strategy was an efficient and sustainable way to convert biomacromolecules into bio-furans.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Agricultural Engineering
Jiawei Shen et al.
Summary: In this study, a sustainable method for converting waste lignocellulosic biomass into furfural was successfully established. A biobased heterogeneous catalyst Sn-CFCRS was prepared using pretreated crab shells as a support. The catalytic performances of Sn-CFCRS were evaluated using deep eutectic solvent DES ChCl:MA. This sustainable process showed high potential for biomass valorization into furfural using a biobased catalyst in a benign reaction medium.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Agricultural Engineering
Qizhen Yang et al.
Summary: Hydrothermal pretreatment is an effective method to improve the saccharification of lignocellulose. In this study, an efficient hydrothermal pretreatment of sunflower straw was conducted, resulting in the removal of 58.8% xylan and 33.5% lignin at a treatment temperature of 180 degrees C for 120 min and a solid-to-liquid ratio of 1:15. Various characterizations confirmed that hydrothermal pretreatment altered the surface structure and increased the accessibility to cellulase. The enzymatic saccharification of the treated sunflower straw achieved a high yield of reducing sugar and glucose and also produced xylo-oligosaccharide in the filtrate.
BIORESOURCE TECHNOLOGY
(2023)
Article
Agricultural Engineering
Daozhu Xu et al.
Summary: Adipic acid is an important organic dibasic acid used in the manufacturing of plastics, lubricants, resins, fibers, etc. Using lignocellulose as feedstock for producing adipic acid can reduce production cost and improve bioresource utilization.
BIORESOURCE TECHNOLOGY
(2023)
Article
Agricultural Engineering
Qi Li et al.
Summary: A biotransformation process was developed to convert vanillin into vanillylamine using whole-cell catalysis, achieving high yields and eco-friendliness. The use of surfactants and deep eutectic solvents further enhanced the conversion efficiency. This process has potential for valorization of lignin-derived compounds.
BIORESOURCE TECHNOLOGY
(2023)
Article
Agricultural Engineering
Zhengyu Tang et al.
Summary: Sunflower straw, an abundant and often overlooked agricultural waste, has the potential for environmental protection and high-value utilization. By using hydrothermal pretreatment and tartaric acid, the resistance of straw can be effectively reduced and the recovery of reducing sugar can be increased. The tartaric acid-assisted hydrothermal pretreatment method improves the properties of the straw and enhances saccharide recovery.
BIORESOURCE TECHNOLOGY
(2023)
Article
Biochemistry & Molecular Biology
Jingjian Zha et al.
Summary: The strategy of efficiently utilizing lignocellulosic biomass to produce furfural using biomass-based heterogeneous catalyst in a green reaction media has gained much attention. The results showed that under specific conditions, the catalyst based on chestnut shell can efficiently catalyze biomass to furfural with high stability. The catalytic mechanism was elucidated, and it was found that green solvent and sodium chloride played a promoting role in the catalytic reaction.
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY
(2022)
Article
Agricultural Engineering
Shunli Zhang et al.
Summary: This study confirmed the feasibility of converting D-fructose to BHMF through one-pot chemoenzymatic conversion, achieving high yields. Pseudomonas Putida S12 was shown to efficiently catalyze the transformation of D-fructose-valorized 5-HMF into BHMF in a benign reaction system.
BIORESOURCE TECHNOLOGY
(2022)
Article
Agricultural Engineering
Lei Gong et al.
Summary: In this study, sunflower stalk was used as a raw material and catalyst for furfural production, and efficient conversion of xylose-rich hydrolysate into furfural was achieved using the carbonaceous solid acid catalyst SO42-/SnO2-SSXR in an aqueous deep eutectic solvent/organic solvent medium. The study revealed that under optimal conditions, a furfural yield of 82.6% was obtained, and the catalyst and solvent exhibited good recyclability for furfural production. This research demonstrates the high potential for sustainable application of furfural production.
BIORESOURCE TECHNOLOGY
(2022)
Article
Agricultural Engineering
Dong Yang et al.
Summary: The study developed a green strategy for synthesizing furoic acid from bulrushes using deep eutectic solvent and organic acid. The results showed that this method efficiently converted bulrushes into furfural and furoic acid, demonstrating the feasibility of producing high-value furan-based chemicals from renewable sources.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Agricultural Engineering
Lihe Zhang et al.
Summary: A series of acidic FDES were prepared for lignocellulose pretreatment, resulting in solid product with high cellulose content and high quality lignin, as well as liquid product containing hemicellulose. The enzymatic hydrolysis of solid product achieved a conversion rate of 84.5%. The enzymatic hydrolysate was successfully used for ethanol fermentation and the pretreatment solution was utilized for microbial lipid production. This study developed a biomass pretreatment process that fully utilized cellulose, hemicellulose, lignin, and the pretreatment solvent.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Agricultural Engineering
Hongzhen Luo et al.
Summary: In this study, the effects of glycerol organosolv pretreatment (GOP) on the main chemical composition of corn stover were investigated. It was found that the L-cysteine-assisted GOP process could enhance the yields of glucose and xylose. The study also elucidated the intrinsic mechanisms of the proposed pretreatment and conducted a techno-economic analysis.
BIORESOURCE TECHNOLOGY
(2022)
Article
Agricultural Engineering
Lei Pan et al.
Summary: This study developed a sustainable approach for the conversion of biomass into furfuryl alcohol through chemoenzymatic conversion and the use of a deep eutectic solvent. The study also demonstrated the efficient biosynthesis of furfuryl alcohol through co-expression of enzymes in E. coli. Overall, this research provides a novel strategy for catalyzing biomass into furfuryl alcohol.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Agricultural Engineering
A. Varilla-Mazaba et al.
Summary: This study optimized the delignification of sugarcane bagasse using deep eutectic solvents (DES) and found that increasing temperature and reaction time improves lignin removal. The results demonstrated that DES is an efficient and useful method for lignin removal from lignocellulosic biomass, with the added benefit of converting cellulose into fermentable sugars.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Engineering, Chemical
Bo Fan et al.
Summary: In this study, a pretreatment method using a mixture of NaOH and deep eutectic solvent (DES) was applied to waste tomato stalk (TS). The effects of pretreatment conditions on enzymatic saccharification were investigated, and it was found that a combination of dilute NaOH and DES pretreatment effectively improved the saccharification yield of TS.
Article
Agricultural Engineering
Mengjia Wu et al.
Summary: The study found that the hydrogen bond donor (HBD) in ChCl-based deep eutectic solvent (DES) had a significant impact on the removal of lignin and xylan during the pretreatment of sorghum straw. By sequentially pretreating with dilute sodium hydroxide and soaking in ChCl:LAC, the enzymatic saccharification efficiency of SS was significantly improved.
BIORESOURCE TECHNOLOGY
(2021)
Article
Agricultural Engineering
Li Ji et al.
Summary: Utilizing SO42-/SnO2-CS as catalyst, successful catalyzation of CS into furfural in a deep eutectic solvent-water system has been achieved, showing promising potential to enhance furfural synthesis yield in the future.
BIORESOURCE TECHNOLOGY
(2021)
Review
Agricultural Engineering
Wei Wang et al.
Summary: Biomass recalcitrance poses a significant challenge for biomass utilization, leading to the development of deep eutectic solvents (DES) as a promising solvent for biomass pretreatment. Current research focuses on the fractionation and saccharification enhancement of lignocellulosic biomass using DES.
BIORESOURCE TECHNOLOGY
(2021)
Article
Agricultural Engineering
Maolin Dong et al.
Summary: This study introduces benzenesulfonic acid as a green hydrotrope for efficient lignocellulose conversion, resulting in high-value building materials and lignin nanoparticles. The method not only removes lignin effectively, but also improves enzymatic hydrolysis efficiency and reduces entangled lignocellulosic nanofibrils, presenting a promising and simple technology for lignocellulose separation and utilization under mild conditions.
BIORESOURCE TECHNOLOGY
(2021)
Article
Agricultural Engineering
Yan Su et al.
Summary: The promising pretreatment using a biomass-derived deep eutectic solvent (DES) with choline chloride effectively removed lignin and xylan while preserving cellulose, resulting in a glucose yield of 75.8% under optimal conditions. The recovered lignin showed potential as a polyphenolic antioxidant due to its molecular weight, low polydispersity, and abundance of phenolic OH groups. Overall, this work demonstrated a biorefinery technology for the effective fractionation and valorization of lignocellulosic biomass.
BIORESOURCE TECHNOLOGY
(2021)
Article
Engineering, Chemical
Hyung-Eun An et al.
Summary: This study focused on using Sicyos angulatus as a raw material for bioethanol production. After pretreatment with NaOH, the glucan content and enzymatic digestibility of S. angulatus were significantly improved. The hydrolysates from S. angulatus were then used for bioethanol fermentation with Saccharomyces cerevisiae K35, resulting in a substantial increase in ethanol production compared to the control group.
Review
Agricultural Engineering
Akshay R. Mankar et al.
Summary: Depleting fossil reserves and increasing energy needs have raised the demand for alternative and clean energy sources. Utilizing lignocellulosic biomass for pretreatment has provided the impetus for developing economic and eco-friendly large scale biorefinery applications. New pretreatment approaches, such as milling, extrusion, microwave, ammonia fibre explosion, and eutectic solvents, are being explored for sustainable technologies in modern biorefineries.
BIORESOURCE TECHNOLOGY
(2021)
Article
Agricultural Engineering
Wei Tang et al.
Summary: Pretreatment with FeCl3 and AlCl3 can significantly increase enzymatic hydrolysis efficiency of waste wheat straw, mainly by increasing xylan removal. Additionally, metallic chlorides pretreatment can also reduce the surface charge, hydrophobicity, and protein adsorption capacity of lignin from waste wheat straw.
BIORESOURCE TECHNOLOGY
(2021)
Article
Agricultural Engineering
Md Anwar Hossain et al.
Summary: Deep eutectic solvent treatment shows great potential in overcoming lignocellulose resistance for biofuels and bioproducts production. Research focused on four solvents, with Choline chloride-glycerol pretreatment showing good results in retaining glucan from rice straw and fractionating lignin. However, some challenges remain with solvent deposition on solids limiting cellulose accessibility to enzymes.
INDUSTRIAL CROPS AND PRODUCTS
(2021)
Article
Chemistry, Multidisciplinary
Jiacheng Ni et al.
Summary: This study successfully converted corncob into furfurylamine using a chemoenzymatic approach, demonstrating an environmentally friendly production method that combines chemical and biological processes.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Biotechnology & Applied Microbiology
Jiacheng Ni et al.
Summary: In this study, a heterogeneous tin-based sulfonated graphite (Sn-GP) catalyst was prepared using graphite as the carrier. By utilizing organic acids with different pKa values as assistants, a linear equation was established for furfural synthesis. Co-catalysis of CC with maleic acid and Sn-GP yielded the highest furfural yield, showcasing an efficient valorization of renewable biomass.
BIORESOURCES AND BIOPROCESSING
(2021)
Article
Chemistry, Multidisciplinary
Huiyang Bian et al.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2020)
Article
Materials Science, Paper & Wood
Mun Chun Ho et al.
Article
Energy & Fuels
Emir Zafer Hosgun et al.
Article
Biochemistry & Molecular Biology
Stefano Cianchetta et al.
APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY
(2017)
Article
Agricultural Engineering
Carla Ines Soares Rodrigues et al.
INDUSTRIAL CROPS AND PRODUCTS
(2016)
Article
Chemistry, Multidisciplinary
Zea Strassberger et al.
Article
Chemistry, Multidisciplinary
Siddheshwar Dnyandev Kshirsagar et al.
Article
Environmental Sciences
Dhirendra Nath Barman et al.
ENVIRONMENTAL TECHNOLOGY
(2014)
Article
Agricultural Engineering
Kyeong Eop Kang et al.
BIORESOURCE TECHNOLOGY
(2013)
Article
Biotechnology & Applied Microbiology
Md Azizul Haque et al.
JOURNAL OF MICROBIOLOGY AND BIOTECHNOLOGY
(2012)
Article
Plant Sciences
Heather Kirk et al.
AMERICAN JOURNAL OF BOTANY
(2011)