Enhanced photoelectrochemical activity of bi-functional photocatalytic fuel cell by a superior heterostructure SnO2/BiOBr/MoS2 photoanode

A dual-photoelectrode PFC system was constructed using an excellent SnO2/BiOBr/MoS2 as a photoanode and copper oxide/copper as a photocathode for the first time. The appropriate interfacial contact and outstanding photoelectrochemical activity of the photoanode can be attributed to SnO2 hole-blocking layer. It is not only employed as a conductive scaffold for BiOBr/MoS2 but also provided less tendency for charge transport loss. In addition, the by-product Bi2S3 acts as a sensitizer due to its broad absorption spectrum (similar to 800 nm) to increase light harvesting. The resulting SnO2/BiOBr/MoS2 photoanode yields the highest photocurrent density at all bias voltages and achieves 4.0 mA cm(-2), which is around eight times higher in comparison with bare BiOBr while it is twice as much as that of the BiOBr/MoS2 photoanode without SnO2 hole reflection layer. This study demonstrates that recombination is significantly inhibited by adding methylene blue (MB) as the hole scavenger, resulting in a high power output efficiency in the dual-photoelectrode PFC system. An ultrahigh power density of 0.045 mW cm(-2) and improved photodegradation efficiency to reach similar to 91 % after 180 min. The excellent power density can therefore be assumed that the enriched strong oxidizing photoexcited holes were used to participate in directly decomposing MB.

Automated summary

A dual-photoelectrode PFC system was constructed using an SnO2/BiOBr/MoS2 photoanode and copper oxide/copper photocathode, achieving a high power density of 0.045 mW cm(-2) and an improved photodegradation efficiency of approximately 91%. The SnO2 hole-blocking layer in the photoanode contributed to the appropriate interfacial contact and outstanding photoelectrochemical activity, while the by-product Bi2S3 acted as a sensitizer to increase light harvesting. The addition of methylene blue as a hole scavenger significantly inhibited recombination and resulted in a high power output efficiency in the PFC system.