Straightforward FeOOH nanografting of Al-based SrTiO3 perovskite material as core-shell nanoflower-like heteronanostructure with enhanced solar light-driven photodegradation capability

Extensive attention and considerable efforts have been made to construct efficient heterogeneous nano -particulate systems for surface chemical reactions to be active in solar light-driven photodegradation. This work addresses current deficiencies of the nanoparticles-focused systems intended for visible light photodegradation by developing a newly-formulated innovative chemically-engineered multi-component system that functions as a recyclabe, nontoxic, active and inexpensive catalyst for photodegradation of tetracyclne antibiotic. Here, we show a straightforward FeOOH nanografting of Al-based SrTiO3 perovskite material as core-shell nanoflower-like heteronanostructure with enhanced solar light-driven photodegradation capability over harmful antibi-otics. A persuasive surface formation mechanism is proposed based on systematic investigation of the assembly process. In-depth caracterization of structural, optical and morphological properties of the prepared samples was investigated using a series of complementary analytical techniques, such as XRD, FE-SEM, HR-TEM, synchrotron XPS, as well as hard and soft XAS in both total electron yield (TEY) and fluorescence yield (TFY). The oxygen -deficient nature of core and shell interface indicates its n-doping and the availability of free charges in core which can be either transferred to the shell or create localized absorption levels into the valence band. This study provides a real opportunity to rationally photocatalysts design with very promising performance in water treatment.

Automated summary

Efforts have been made to develop efficient heterogeneous nano-particle systems for solar light-driven photodegradation. In this study, a chemically-engineered multi-component system was formulated as a recyclable, nontoxic, active and inexpensive catalyst for the degradation of tetracycline antibiotic. The nanoflower-like heteronanostructure showed enhanced photodegradation capability by using FeOOH nanografting of Al-based SrTiO3 perovskite material.