期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 30, 页码 9401-9404出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b05723
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资金
- MIT Tata Center for Technology and Design
- National Science Foundation [DMR-1452612]
- Sloan Foundation
- Research Corporation for Science Advancement
- 3M
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1452612] Funding Source: National Science Foundation
A series of new mesoporous metal-organic frameworks (MOFs) made from extended bisbenzene-triazolate linkers exhibit coordinatively unsaturated metal sites that are responsible for high and reversible uptake of ammonia. Isostructural Mn, Co, and Ni materials adsorb 15.47, 12.00, and 12.02 mmol of NH3/g, respectively, at STP. Importantly, these near-record capacities are reversible for at least three cycles. These results demonstrate that azolate MOFs are sufficiently thermally and chemically stable to find uses in recyclable sorption, storage, and potentially separation of chemically challenging and/or corrosive gases, especially when designed to exhibit a high density of open metal sites.
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