期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 9, 页码 2961-2964出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b00436
关键词
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资金
- NSFC of China [21525104, 91422301, 11474292, 21373220, 51502288, 51502290, 21571178]
- 863 Program of China [2015AA034203]
- NSF for Distinguished Young Scholars of Fujian Province [2016J0103]
- Chunmiao Project of Haixi Institute of Chinese Academy of Sciences [CMZX-2015-003]
- Youth Innovation Promotion of CAS [2016274]
A beryllium-free deep-ultraviolet (deep-UV) nonlinear optical (NLO) material K3Ba3Li2Al4B6O20F is developed mainly by the element substitution of Be for Al and Li from Sr2Be2B2O7 that was considered as one of the most promising deep-UV NLO materials. K3Ba3Li2Al4B6O20F preserves the structural merits of Sr2Be2B2O7 and thus exhibits no layering growth tendency and possesses the optical properties required for deep-UV NLO applications, including deep-UV transparency, phase-matchability, and sufficiently large second-harmonic generation (1.5 x KH2PO4). Furthermore, it overcomes the structural instability problem of Sr2Be2B2O7, which is confirmed by the obtainment of large single crystals and phonon dispersion calculations. These attributes make it very attractive for next-generation deep-UV NLO materials. The substitution of Be for Al and Li in beryllium borates provides a new opportunity to design beryllium free deep-UV NLO materials with good performance.
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