期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 31, 页码 9759-9762出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b04613
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资金
- National Institute of General Medical Sciences of the National Institutes of Health [R01GM113883]
Molecular imprinting within cross-linked micelles using 4-vinylphenylboronate derivatives of carbohydrates provided water-soluble nanoparticle receptors selective for the carbohydrate templates. Complete differentiation of D-aldohexoses could be achieved by these receptors if a single inversion of hydroxyl occurred at C2 or C4 of the sugar or if two or more inversions took place. Glycosides with a hydrophobic aglycan displayed stronger binding due to increased hydrophobic interactions.
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