期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 139, 期 2, 页码 607-610出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b11813
关键词
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资金
- National Natural Science Foundation of China [21390403]
- Thousand Talents Plan for Young Professionals
A pyridine-catalyzed transition-metal-free borylation reaction of haloarenes has been developed based on the selective cross-coupling of an aryl radical and a pyridine-stabilized boryl radical. Arylboronates were produced from haloarenes under mild conditions. This borylation reaction features a broad substrate scope, operational simplicity, and gram-scale synthetic ability.
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