4.8 Article

Facile Insertion of Rh and Ir into a Boron-Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 7, 页码 2086-2089

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AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b11706

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资金

  1. National Science Foundation [CHE-0944634, CHE-1300299]
  2. Welch Foundation [A-1717]
  3. Fundamental Research Funds for the Central Universities of China [AUGA5710013115]
  4. Division Of Chemistry
  5. Direct For Mathematical & Physical Scien [1300299] Funding Source: National Science Foundation

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The unexpectedly facile insertion of Rh or Ir into a B-Ph bond (reversible for Rh) converts a borane/bis(phosphine) precursor into a boryl/bis-(phosphine) PBP pincer ligand. Interconversions between the boryl/borane/borate central functionality are demonstrated in reactions with dihydrogen.

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