期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202306133
关键词
Active Sites; Heterogeneous Catalysis; Methane Conversion; Solid-State NMR; Zeolites
By using 1D Mo-95 NMR and 2D H-1-Mo-95 heteronuclear correlation solid-state NMR spectroscopy, the active ensembles in the confined channels of Mo/ZSM-5 zeolite during the MDA reaction were observed. Two kinds of MoOxCy species were identified, with MoOxCy-II showing higher activity for methane activation and benzene formation.
Methane dehydroaromatization (MDA) over Mo-modified zeolite is a potential catalytic route for converting natural gas into valuable aromatics. However, the active species in this reaction are highly complex, involving diverse Mo species, acidic sites of zeolite, and organic molecules. Herein, we apply 1D Mo-95 NMR and 2D H-1-Mo-95 heteronuclear correlation solid-state NMR spectroscopy to directly observe the active ensembles in the confined channels of Mo/ZSM-5 zeolite during the MDA reaction. We monitor the evolution of the spatial correlations of Mo species with the Bronsted acid sites and organic products (olefins and aromatics) in the zeolite channels. We identified two kinds of MoOxCy species, with the more carbidic one (MoOxCy-II) exhibiting higher activity for methane activation and benzene formation. The strong spatial interactions between the active Mo species and the organic species in the Mo/ZSM-5 pores are related to the MDA activity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据