期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 6, 页码 1780-1783出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b12366
关键词
-
资金
- American Chemical Society Petroleum Research Fund [55281-DNI-3]
- Schlumberger Faculty for Future Fellowship
- DOE Office of Science by Argonne National Laboratory [DE-AC02-06CH11357]
A porous metal-organic framework Zr6O4(OH)(4)(L-PdX)(3) (1-X) has been constructed from Pd diphosphinite pincer complexes ([L-PdX](4-) = [(2,6-(OPAr2)(2)C6H3)PdX](4-), Ar = p-C6H4CO2-, X = Cl, I). Reaction of 1-X with PhI(O2CCF3)(2) facilitates I-/CF3CO2- ligand exchange to generate 1-TFA and I-2 as a soluble byproduct. 1-TFA is an active and recyclable catalyst for transfer hydrogenation of benzaldehydes using formic acid as a hydrogen source. In contrast, the homogeneous analogue Bu-t(L-PdTFA) is an ineffective catalyst owing to decomposition under the catalytic conditions, highlighting the beneficial effects of immobilization.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据