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Article
Chemistry, Physical
Yangzheng Hou et al.
Summary: This study presents a new structure for zinc-iodine batteries (ZIBs) that addresses the issues of low electron conductivity, shuttle effect, and highly soluble iodine species. By employing a double fixation strategy and specific materials, the ZIBs demonstrate excellent electrochemical performance.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Leiqian Zhang et al.
Summary: By constructing a sulfonate-rich ion-exchange layer (SC-PSS) to modulate the transport and reaction of polyiodide and Zn2+, the corrosion and dendritic growth issues on the anode of zinc-iodine batteries can be addressed. The resulting batteries exhibit proper performance over 6000 cycles with high-capacity retention (90.2%) and reversibility (99.89%). The SC-PSS layer blocks polyiodide permeation through electrostatic repulsion and restricts undesirable 2D diffusion of Zn2+ by facilitating desolvation and chemisorption.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Wei Zong et al.
Summary: The study successfully constructed an expanded 2D rhenium selenide intercalated by nitrogen-doped carbon hybrid with a strong-coupled interface and weak van der Waals forces, improving conductivity and accelerating reaction kinetics. Results showed that the hybrid capacitor has enhanced rate capability and long-term cyclability, as well as favorable sodium storage kinetics, making it applicable in a wide temperature range.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Dun Lin et al.
Summary: Aqueous rechargeable zinc-iodine batteries (ZIBs) are considered as promising candidates for grid-scale electrochemical energy storage due to their safety, high theoretical capacity, and energy density. However, challenges such as self-discharge, sluggish kinetics, low energy density, and unstable Zn metal anodes need to be addressed. This article reviews the electrochemistry of ZIBs, discusses the fundamental questions, and highlights the key strategies and recent accomplishments in overcoming these challenges.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jingxu Zheng et al.
Summary: Control of crystallography in metal electrodeposit films is crucial for long battery lifetimes, with the ARB process demonstrating significant improvements in crystallographic uniformity and plating/stripping performance. This concept can potentially be applied to various metal chemistries to develop highly reversible thin metal anodes, highlighting opportunities for future battery advancements.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yiju Li et al.
Summary: A new design concept for a Janus separator, enabled by interfacial engineering strategy, is proposed to improve the performance of lithium-sulfur batteries. By utilizing different materials and methods at the anode/separator and separator/cathode interfaces, the battery's cycling performance and capacity have been successfully improved.
ADVANCED MATERIALS
(2022)
Article
Engineering, Environmental
Yujie Zhang et al.
Summary: In this study, a high-performance rechargeable magnesium battery was developed using low-cost povidone iodine as the cathode material. The povidone iodine cathode demonstrated high reversible magnesium storage capacity, outstanding rate capability, and remarkable cycling durability. The chemical interaction of iodine with the host material effectively improved battery performance and eliminated the shuttle effect.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Chemistry, Multidisciplinary
Jin Cao et al.
Summary: This paper reviews the strategies of regulating Zn2+ solvation shells in electrolytes based on electrolyte engineering for dendrite-free and side reaction-suppressed aqueous zinc-ion batteries. Fruitful achievements have been made by controlling Zn2+ solvation shells through high-concentration electrolytes, deep eutectic solvents, ionic liquids, functional additives, etc.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Lin Hong et al.
Summary: The formation of Zn4SO4(OH)6middot5H2O byproducts is closely related to the direct contact between the Zn electrode and SO42-/H2O. A cation-exchange membrane of PFSA coated on the Zn surface can regulate the Zn plating/stripping behavior, resulting in a highly reversible process with corrosion-free and dendrite-free behavior.
Article
Chemistry, Multidisciplinary
Yongchang Liang et al.
Summary: This study developed a unique dual-interface engineering strategy to design an efficient ion transport modulator separator for Zn metal batteries. By decorating BaTiO3 (BTO) on glass fiber, the modified separator can capture and accelerate ion transport, and distribute it homogenously, resulting in highly reversible Zn plating/stripping in the anode and improved battery performance.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yiwen Su et al.
Summary: In this study, a scalable Ti3C2Tx MXene-decorated Janus separator was designed and prepared, demonstrating superior performance in achieving dendrite-free zinc anodes. The separator exhibited abundant surface polar groups, good electrolyte wettability, and high ionic conductivity, which facilitated homogeneous current distribution and promoted zinc nucleation kinetics.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Shao-Jian Zhang et al.
Summary: This study proposes a structure confinement strategy using starch to suppress polyiodide shuttling in Zn-I-2 batteries, resulting in a highly reversible and long-cycling Zn-I-2 battery with high Coulombic efficiency. The starch effectively inhibits Zn corrosion triggered by polyiodide, providing a cheap yet effective strategy for high-cyclability Zn-I-2 batteries.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Junwei Xu et al.
Summary: ZPC, a porous carbon material derived from ZIF-8, shows efficient iodine loading and fast electron transmission ability, which mitigates the shuttle effect of iodine species. In experiments, the ZPC/I-2 cathode exhibits high reversible capacity and long-term stability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Zhanpeng Huang et al.
Summary: Interfacial engineering using a metal-organic framework cation reservoir as a zincophile interphase offers a solution to manipulate zinc-ion flux, suppress side reactions, and improve the performance of zinc metal anodes.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Multidisciplinary
Zhengang Li et al.
Summary: The research team developed a membrane material using zeolite molecular sieve to effectively control the diffusion of soluble iodide in zinc iodide batteries. The membrane improved the Coulombic efficiency and reversibility of the battery, while also restraining self-discharge and zinc corrosion. Furthermore, the battery showed excellent cycling stability.
Article
Chemistry, Multidisciplinary
Leiqian Zhang et al.
Summary: In this study, a quaternization engineering approach was used to improve the cycling durability of aqueous rechargeable zinc-iodine batteries. By precisely controlling the polyiodide using a commercial acrylic fiber skeleton, a high-rate and ultra-stable polymer-based zinc-iodine battery was developed. The quaternization strategy significantly eliminated the polyiodide shuttle issue and allowed for unique solution-based iodine chemistry in the battery.
Article
Chemistry, Physical
Chang Li et al.
Summary: This study introduces a novel additive that effectively solves the issues in aqueous zinc-metal batteries, leading to excellent cycling performance and efficient zinc deposition.
Article
Chemistry, Multidisciplinary
Miaomiao Liu et al.
Summary: This study demonstrates the enhancement of physicochemical confinement effect and electrocatalytic redox conversion of iodine in zinc-iodine batteries by embedding a single iron atom in porous carbon with a metal-nitrogen-carbon bridging structure, which is crucial for fabricating high-performing batteries.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Xiaotan Zhang et al.
Summary: A Janus separator was constructed using spin-coating technique, which can continuously regulate the growth of zinc and achieve a locked crystallographic orientation of zinc(002) texture to intercept dendrites. The separator also has the capability to repel SO42- and anchor H+ while allowing effective transport of Zn2+. This work demonstrates the importance of continuous regulation for achieving crystallographic homogeneity of the Zn anode in metal batteries.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Zhengqiang Hu et al.
Summary: This study proposes the use of cerium chloride (CeCl3) as an additive in aqueous Zn batteries to inhibit dendrite growth and enhance electrolyte stability, resulting in improved cycling stability and efficiency of the batteries.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Applied
Ying Zhang et al.
Summary: This study presents a flexible, thin, and lightweight poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) nanopaper as an anion-cation regulation synergistic interlayer for aqueous zinc-iodine (Zn-I2) batteries. The PEDOT:PSS interlayer with a 3D nanofibrous network and uniformly distributed mesopores effectively suppresses polyiodide shuttling and promotes dendrite-free zinc plating/stripping at high current densities and high areal capacities. The Zn-I2 batteries demonstrate high capacity and ultralong lifespan even at high current densities. This work highlights the potential of multifunctional interlayers for innovation in Zn-I2 battery configurations by synergistic regulation of cations and anions at the electrodes/electrolyte interface.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Chemistry, Physical
Tingting Liu et al.
Summary: This study demonstrates that catalyzing the iodine conversion with nitrogen-doped porous carbons can effectively suppress the formation and crossover of triiodide, leading to improved energy density and cycle life of zinc-iodine batteries. The electrocatalytic activities are found to be sensitive to the type of N heteroatoms, and graphitic N-enriched host enhances the conversion efficiency and lowers the energy barrier for triiodide/iodide conversion.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Jingkang Ma et al.
Summary: Rechargeable metal-iodine batteries have been attracting attention for their high-rate performance, remarkable energy density, and low cost, but the slow electro-chemical kinetics of iodine have hindered practical implementation. Various strategies have been explored to accelerate the redox kinetics of iodine for developing advanced metal-iodine batteries.
MATERIALS TODAY ENERGY
(2022)
Article
Chemistry, Multidisciplinary
Jie Xu et al.
Summary: In this study, an all-climate lithium-sulfur (Li-S) battery is proposed using an ether-based electrolyte and a modified separator with a porous sub-nano aromatic framework (SAF-3). The SAF-3 effectively blocks polysulfides shuttling at high temperatures and enhances polysulfides conversion at low temperatures. The modified cells exhibit good performance in a wide temperature range (-40 to 60 degrees C) and retain 90% capacity after 100 cycles under high-sulfur loading and lean electrolyte conditions at room temperature.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Wei Yang et al.
Summary: In this research, a cation-initiated self-assembly process of Ti3C2Tx MXene nanosheets onto glass fiber membranes is proposed to form Janus separators that can mitigate the shuttle effect of I-/I3- ions in iodine-based redox ECs. The resulting Janus separators exhibit tailored nanochannels for ion sieving, which can effectively block the diffusion of I-3(-) ions while allowing the pass of other electrolyte ions. Experimental results show that the self-discharge caused by the shuttle effect can be greatly reduced in redox ECs using this Janus separator, resulting in higher voltage and energy retentions compared to cells using glass fiber membrane separators.
ENERGY STORAGE MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Qiang Guo et al.
Summary: Rechargeable aqueous zinc-iodine batteries are promising for next-generation energy storage systems due to their low cost and high safety. However, the shuttle effect of highly soluble I-3(-) in these batteries limits their cycling stability. In this study, we developed a mesoporous carbon and I-2 composite cathode material for zinc-iodine batteries, which effectively eliminated the polyiodide shuttle effect and significantly improved the cycling stability. The developed battery showed excellent performance and retained 80.6% capacity after 39,000 cycles. This work provides a solution for the assembly of high-performance I-2-based materials in aqueous energy technologies.
ACS MATERIALS LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Minhyung Kwon et al.
Summary: This study successfully constructs a stable zinc metal anode by identifying the growth mechanism of densely packed micrometer-sized Zn particles on Cu foil, which contributes to improving the performance of aqueous Zn-ion batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Electrochemistry
Siying Liu et al.
Summary: The addition of I-3(-) species to the electrolyte can improve the performance of Zn anodes and ZIBs, prolonging the cycling lifetime of electrodes and suppressing detrimental processes. However, the I-3(-) additive seems failed in evolving into a dense interfacial protective layer.
BATTERIES & SUPERCAPS
(2022)
Review
Chemistry, Multidisciplinary
Jizhen Ma et al.
Summary: This article discusses the potential and challenges of combining halogens with metal anodes in a single cell to develop novel rechargeable batteries, emphasizing the importance of understanding the fundamental reactions of iodine/polyiodide for designing high-performance cathodes. Special focus is placed on the basic principles of iodine redox chemistry and its correlation with structure-function relationships.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Nanoscience & Nanotechnology
Qinping Jian et al.
Summary: Constructing an ultrathin SPEEK solid-electrolyte interphase on the surface of zinc metal anode effectively suppresses side reactions and dendrite growth, leading to improved performance and stability of aqueous batteries.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Yang Yang et al.
Summary: The study successfully developed a Zn@ZnF2 electrode with a multi-functional protective layer by designing a 3D interconnected ZnF2 matrix on the surface of Zn foil. This electrode exhibits stable zinc deposition kinetics and good plating/stripping reversibility, showing potential for practical application in various battery systems.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Haobo Dong et al.
Summary: The latest progress in polymer electrolytes for flexible ZIBs, particularly hydrogel electrolytes, is summarized in the article, along with discussions on relevant challenges, device configurations, and life cycle analysis. It is noted that most current polymer electrolytes emphasize electrochemical performance, with little consideration for mechanical behavior and interactions with electrode materials. Strategies to combine softness and strength, as well as the introduction of a ranking index to evaluate both electrochemical and mechanical properties, are discussed.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Physical
Yiyang Liu et al.
Summary: This work reviews the development and advantages of various types of aqueous Zn-based EES devices since 1799, discussing the electrochemical charge storage mechanisms, key components, challenges, and future directions of AZDs.
Article
Chemistry, Multidisciplinary
Dun Lin et al.
Summary: By utilizing a double-layered cathode structure, the undesired shuttling of triiodide ions has been successfully suppressed, resulting in outstanding Coulombic efficiency and voltage efficiency for ZIBs. These findings offer new insights for the design and fabrication of ZIBs and other batteries based on conversion reactions.
Article
Chemistry, Multidisciplinary
Chun-Lei Song et al.
Summary: This study presents a Janus separator prepared with anionic metal-organic framework and single-atom zinc catalyst, which effectively inhibits the dendrite growth and shuttle effect of Li-S batteries. The results show stable cyclic performance and outstanding protection capability, making it suitable for various types of Li-S or Li-Se batteries.
Review
Materials Science, Multidisciplinary
Zhibin Pei et al.
Summary: Zn-iodine redox flow batteries are a promising next-generation energy storage system due to their high energy density, low cost, and superior safety, although challenges such as low I-2 utilization and shuttle effect of iodine species exist. Functional strategies including electrode design and electrolyte optimization have been developed to improve the adsorption capability and utilization efficiency of the iodine species towards practical applications. Further discussion and research are needed to address the remaining challenges and advance the future perspectives of Zn-iodine redox flow batteries.
MATERIALS RESEARCH BULLETIN
(2021)
Article
Chemistry, Physical
David J. Arnot et al.
Summary: Zinc has the potential for widespread use as an environmentally friendly and cost-effective anode material, with a self-assembled Nafion-coated Celgard 3501 (NC-Celgard) separator shown to enable unprecedented cycle life of a Zn anode in alkaline electrolyte. The highly selective diffusion properties of the Nafion coating prevent shorting by dendrites and inhibit redistribution of the active material.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Jin Cao et al.
Summary: A functional separator composed of cellulose nanofibers and graphene oxide is developed for dendrite-free and stable zinc ion batteries. This separator promotes uniform zinc deposition and significantly enhances the performance of zinc anodes in various types of batteries.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Chaojie Chen et al.
Summary: The study focuses on improving the cycling stability and capacity of zinc-iodine batteries using hierarchical porous carbon encapsulated iodine and ZnI2 additive in the electrolyte, achieving high performance in high-efficiency zinc-iodine batteries. Through ex-situ investigation, the working mechanism of the device was revealed.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Chemistry, Physical
Yong Zhang et al.
Summary: By studying a mixed zinc bis(trifluoromethane sulfonyl)imide and LiTFSI WIS electrolyte, it was found that in highly concentrated WIS electrolyte, zinc cations are mainly solvated by water molecules while TFSI anions are excluded. This ion solvation structure is fundamentally different from previous understandings, highlighting the need for further research to fully comprehend the unusual stability and reversibility of zinc-WIS electrolyte-based batteries.
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Yunpei Zhu et al.
Summary: High-concentration aqueous Zn2+ electrolyte using a supporting Na salt is efficient in addressing performance degradation issues in Zn-ion batteries without sacrificing power densities, cycling stability, and safety. A unique interphase formed on the Zn anode enables reversible and uniform Zn plating, while a cathode of sodium vanadate shows improved performance in a Zn-sodium vanadate battery with concentrated bi-cation electrolyte. This work offers new insights into electrolyte engineering for achieving high-performance aqueous batteries.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Physical
Jing Yang et al.
Summary: In this study, a polymer-polyiodide complex cathode was developed to enhance the iodide capacity of zinc-iodine flow batteries. By utilizing polyvinylpyrrolidone (PVP) and KI, the formation of the polyiodide complex significantly increased the solubility of the I-2 film, resulting in a superior discharge capacity and stable energy efficiency over 600 cycles.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2018)
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ADVANCED ENERGY MATERIALS
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ACS ENERGY LETTERS
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