期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 27, 页码 8400-8403出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b05273
关键词
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资金
- JSPS (KAKENHI) [JP26220804, JP16K14057]
- Grants-in-Aid for Scientific Research [26220804, 16K14057, 15J00026] Funding Source: KAKEN
Electrochemical oxidation of toluene derivatives in the presence of a sulfilimine gave benzylaminosulfonium ions as stabilized benzyl cation pools, which reacted with subsequently added aromatic nucleophiles to give the corresponding cross-coupling products. The transformation serves as a powerful metal- and chemical-oxidant-free method for benzylic C-H/aromatic C-H cross-coupling. The method has been successfully applied to synthesis of TP27, an inhibitor of PTPase.
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