期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 6, 页码 1832-1835出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b13211
关键词
-
资金
- NIH [NIGMS R01 GM093213, R01 GM062871]
- Shanghai Institute of Organic Chemistry
An asymmetric decarboxylative C-sp(3)-C-sp(2) cross-coupling has been achieved via the synergistic merger of photoredox and nickel catalysis. This mild, operationally simple protocol transforms a wide variety of naturally abundant alpha-amino acids and readily available aryl halides into valuable chiral benzylic amines in high enantiomeric excess, thereby producing motifs found in pharmacologically active agents.
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